Measuring the biodegradability of nonylphenol ether carboxylates, octylphenol ether carboxylates, and nonylphenol

We examined the biodegradability of several metabolites of C8- and C9-alkylphenol ethoxylates, including nonylphenoxyacetic acid (NPEC1), nonylphenoxyethoxyacetic acid (NPEC2), octylphenoxyacetic acid (OPEC1), octylphenoxyethoxyacetic acid (OPEC2), and nonylphenol (NP). Using OECD method 301B (modified Sturm method), OPEC1 and OPEC2 are readily biodegradable: both compounds exceeded 60% of theoretical CO2 formation (ThCO2) by day 28, and required less than 10 days to go from 10% to 60% ThCO2. Also using method 301B, NPEC1 and NPEC2 exceeded 60% ThCO2 at day 28, but did not meet the 10 day window. Using OECD method 301F, the manometric respirometry method that measures oxygen consumption, approximately 62% of NP was biodegraded in 28 days, but required more than 10 days to go from 10% to 60% biodegradation. While the validity of the "10-day window" is currently being debated within OECD, the data show that the common metabolites of C8- and C9-APEs are rapidly degraded in the test systems used, which strongly suggests that they would not accumulate or persist in the environment.     

A study on the dilemmas of resource utilization and tourism in Africa

This paper explores,explains and discusses issues around the dilemma between local conservation of natural resources(often,endangered species and habitats)and tourism needs in Africa.Often and in constitutional terms,local people have a right to exploit and use resources endowed in their local area.However,tourists often are interested in viewing the vegetation and animal resources undisturbed.Inevitably,there is an undeclared animosity of values and interests between local communities and tourists and state agencies.As a result,the dilemma is thus of governance.The purpose of this paper is to demonstrate the governance dilemma of resource utilization and tourism in Africa in a bid to create an informed stewardship framework for sustainability.This is achieved by way of case studies and narratives from Africa.As such,this paper will be a review literature on how different communities perceive tourism and derive livelihoods from their immediate environment.It also explains how the external factors influence local needs and interests.A more sustainable and operational framework that reduces friction among stakeholders is suggested.     

Throughflow analysis: A stochastic approach

Ecological network analysis (ENA), predicated on systems theory and Leontiev input–output analysis, is a method widely used in ecology to reveal ecosystem properties. An important ecosystem property computed in ENA is throughflows, the amount of matter/energy leaving each compartment of the ecosystem. Throughflows are analyzed via a matrix representing their relationships to the driving input at the boundary. Network particle tracking (NPT) builds on ENA to offer a Lagrangian particle method that describes the activity of the ecosystem at the microscopic level. This paper introduces a Lagrangian throughflow analysis methodology using NPT and shows that the NPT throughflow matrix, , agrees with the conventional ENA throughflow matrix, , for ecosystems at steady-state with donor-controlled flows. The matrix is computed solely from the pathways (particles’ histories) generated by NPT simulations and its average over multiple runs of the algorithm with longer simulation time agrees with the Eulerian matrix (Law of Large Numbers). While the traditional NEA throughflow analysis is mostly used with steady-state ecosystem models, the Lagrangian throughflow analysis that we propose can be used with non-steady-state models and paves the way for the development of dynamic throughflow analysis.     

Effect of electronic waste on E. coli genomic integrity: a possible role for metal induced carcinogenesis

Electronic waste (e-waste) poses a major public health threat for developing countries’ populations. The hazards of e-waste are exacerbated by crude recycling methods. In this study, the presence of metals in e-waste samples obtained from Lagos, Nigeria, was assessed using atomic absorption spectrometry. The effect of e-waste on Escherichia coli (E. coli) PQ-37 genomic integrity was evaluated using the SOS chromotest. The means of metal concentrations in the evaluated samples were 16 (cadmium), 7.3 (nickel), 11 (chromium), 20 (lead), 3100 (iron), 90 (zinc), and 2000 (copper) μg_L^?1. Damage to E. coli deoxyribonucleic acid (DNA) increased proportionally to the metal concentrations. Significant amounts of DNA damaging agents from inadequately processed e-waste are present in the studied environment, which will have implications for adverse effects on public and ecological health. Existing policies against dumping of toxic materials in susceptible communities should be enforced.