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Natarajan Velmurugan Grim Hwang Muthuswamy Sathishkumar Tae Kie Choi Kui-Jae Lee Byung-Taek Oh Yang-Soo Lee 《环境科学学报(英文版)》2010,22(7):1049-1056
A heavy metal contaminated soil sample collected from a mine in Chonnam Province of South Korea was found to be a source
of heavy metal adsorbing biosorbents. Chemical analyses showed high contents of lead (Pb) at 357 mg/kg and cyanide (CN) at 14.6
mg/kg in the soil. The experimental results showed that Penicillium sp. MRF-1 was the best lead resistant fungus among the four
individual metal tolerant fungal species isolated from the soil. Molecular characterization of Penicillium sp. MRF-1 was determined
using ITS regions sequences. E ects of pH, temperature and contact time on adsorption of Pb(II) by Penicillium sp. MRF-1 were
studied. Favorable conditions for maximum biosportion were found at pH 4 with 3 hr contact time. Biosorption of Pb(II) gradually
increased with increasing temperature. E cient performance of the biosorbent was described using Langmuir and Freundlich isotherms.
Adsorption kinetics was studied using pseudo first-order and pseudo second-order models. Biosorbent Penicillium sp. MRF-1 showed
the maximum desorption in alkali conditions. Consistent adsorption/desorption potential of the biosorbent in repetitive cycles validated
the e cacy of it in large scale. SEM studies given notes on surface modification of fungal biomass under metal stress and FT-IR results
showed the presence of amino groups in the surface structure of the biosorbent. In conclusion, the new biosorbent Penicillium sp.
MRF-1 may potentially be used as an inexpensive, easily cultivatable material for the removal of lead from aqueous solution. 相似文献
84.
Jong-Beom Seo Soo-Bin Jeon Je-Young Kim Gang-Woo Lee Jong-Hyeon Jung Kwang-Joong Oh 《环境科学学报(英文版)》2012,24(3):494-498
Aqueous ammonia (NH3) solution can be used as an alternative absorption for the control of CO2 emitted from flue gases due to its high absorption capacity, fast absorption rate and low corrosion problem. The emission of CO2 from iron and steel plants requires much attention, as they are higher than those emitted from power plants at a single point source. In the present work, low concentration ammonia liquor, 9 wt.%, was used with various additives to obtain the kinetic properties using the blast furnace gas model. Although a solution with a high ammonia concentration enables high CO2 absorption efficiency, ammonium ions are lost as ammonia vapor, resulting in reduced CO2 absorption due to the lower concentration of the ammonia absorbent. To decrease the vaporization of ammonia, ethylene glycol, glycerol and glycine, which contain more than one hydroxyl radical, were chosen. The experiments were conducted at 313 K similar to the CO2 absorption conditions for the blast furnace gas model. 相似文献
85.
There are different approaches to estimating the transverse dispersion coefficient in river mixing. Theoretical approaches have derived the dispersion coefficient from the concept of shear flow, which has dominant effects on the transverse mixing. Empirical approaches have developed an equation using the hydraulic and geometric data of rivers through dimensional analysis and regression techniques. These two equations interact closely with each other. For example, the complicated theoretical equation can be simplified by empirical approaches, and the functional relationships of the empirical equation can be derived from theoretical bases. In this study, a new empirical equation for the transverse dispersion coefficient has been developed based on the theoretical background in river bends. As a regression method, the least-square iterative method was used because the equation was a nonlinear model. The estimated dispersion coefficients derived by the new equation were compared with observed transverse dispersion coefficients acquired from natural rivers and coefficients calculated by the other existing empirical equations. From a comparison of the existing transverse dispersion equations and the proposed equation, it appears that the behavior of the existing formula in a relative sense is very much dependent on the flow condition and the river geometry. Moreover, the proposed equation does not vary widely according to variation of flow conditions. Also, it was revealed that the equation proposed in this study becomes an asymptotic curve as the curvature effect increases. 相似文献
86.
Kim Duk-Min Kwon Oh-Hun Oh Youn Soo Lee Jin-Soo 《Environmental geochemistry and health》2021,43(10):4061-4074
Environmental Geochemistry and Health - Paddy fields near metalliferous mining area are sometimes contaminated by tailings or mine water. In the contaminated paddy fields around the abandoned... 相似文献
87.
The presence of polychlorinated dibenzo-p-dioxins and furan (PCDD/Fs) and brominated flame retardants (BFRs) in sludge generated at municipal wastewater treatment plants (MWTPs) and industrial wastewater treatment plants (IWTPs) was investigated. The concentrations of these pollutants were in the following ranges: 5.38-7947 ng kg−1 dw (0.02-49.9 ng WHO-TEQ kg−1 dw) for 17 PCDD/Fs, 17.5-66 761 μg kg−1 dw for 27 polybrominated diphenyl ethers (PBDEs), 1.55-29 604 μg kg−1 dw for hexabromocyclododecanes (HBCDs) (α-, β-, and γ-diastereomers), and 4.01-618 μg kg−1 dw for tetrabromobisphenol A (TBBPA). Generally, the levels of each compound in the sewage-sludge samples were higher than those in the industrial-sludge samples with some exceptions. The characteristic distribution profiles of target compounds were observed for different types of sludge and different sources of wastewater. High-chlorinated PCDD/Fs were dominant in all samples except those from the textile industry. The distribution of the BFRs in industrial-sludge samples varied, whereas that of the BFRs in sewage-sludge samples was consistent. The proportion of penta-BDEs in sewage sludge was higher than that in industrial sludge, even though BDE-209 was the most dominant congener in all the samples. For HBCDs, the distribution of diastereomers (α-, β-, and γ-HBCD) was similar across sludge samples that had the same source of wastewater and treatment processes. 相似文献
88.
Shin-ichi Sakai Hideto Yoshida Yasuhiro Hirai Misuzu Asari Hidetaka Takigami Shin Takahashi Keijirou Tomoda Maria Victoria Peeler Jakub Wejchert Thomas Schmid-Unterseh Aldo Ravazzi Douvan Roy Hathaway Lars D. Hylander Christian Fischer Gil Jong Oh Li Jinhui Ngo Kim Chi 《Journal of Material Cycles and Waste Management》2011,13(2):86-102
Reduce, reuse, and recycle (3R) policies form the basis of waste management and global warming countermeasures globally, so we conducted a comparative study of 3R and waste management policies in the European Union (EU), USA, Korea, Japan, China, and Vietnam. An international workshop for 3R and waste management policymakers was held in Kyoto, Japan, and a bibliographic survey was also conducted to collect data. 3R policies are clearly given priority in the hierarchy of waste management in every country studied. Thermal recovery, which includes power generation from waste heat and methane gas collected from organic waste, is also a priority; this is consistent with the increased use of countermeasures to reduce greenhouse gas (GHG) emissions. In the EU, waste management is characterized by practical and effective 3R policies through the development of realistic regulations and by the policymakers??desire to simplify management systems. The policy ideal in China, however, is the development of a circular economy that targets reductions in the amount and hazardousness of waste. Limits on the number of final disposal sites, strategies for procuring resources, and GHG emission countermeasures are closely linked with 3R policies, and further development of 3R policies in parallel with such issues is expected. 相似文献
89.
Natural disasters such as typhoon, flood, and heavy rainfall cause damage in South Korea every year during the summer season. After each rainy season, South Korea suffers not only from flood wastes but also from debris that pile up at dams and stagnate at the estuary of the river. Thus, it is very important to handle these types of wastes as quickly as possible to recover from flood damages and to prevent environmental contamination such as offensive odor and water contamination by the leachate from flood wastes. Other countries such as Japan or USA have established and implemented regulations and guidelines for flood waste. Note, however, that South Korea did not establish practical guidelines; hence, the urgency of establishing practical measures for flood waste. In this study, we suggested various ways of making environmentally sound guidelines including the method of reducing the amount of flood waste by environmentally sound treatment process for flood waste, and the method of setting up and operating the temporary storage site for purposes of efficient separation and treatment of flood waste. 相似文献
90.