全文获取类型
收费全文 | 217篇 |
免费 | 0篇 |
国内免费 | 2篇 |
专业分类
安全科学 | 2篇 |
废物处理 | 20篇 |
环保管理 | 2篇 |
综合类 | 9篇 |
基础理论 | 74篇 |
污染及防治 | 80篇 |
评价与监测 | 20篇 |
社会与环境 | 12篇 |
出版年
2023年 | 4篇 |
2022年 | 7篇 |
2021年 | 10篇 |
2020年 | 2篇 |
2019年 | 3篇 |
2018年 | 21篇 |
2017年 | 19篇 |
2016年 | 17篇 |
2015年 | 6篇 |
2014年 | 12篇 |
2013年 | 23篇 |
2012年 | 13篇 |
2011年 | 20篇 |
2010年 | 13篇 |
2009年 | 6篇 |
2008年 | 5篇 |
2007年 | 8篇 |
2006年 | 8篇 |
2005年 | 5篇 |
2004年 | 4篇 |
2003年 | 1篇 |
2002年 | 4篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1993年 | 1篇 |
排序方式: 共有219条查询结果,搜索用时 449 毫秒
131.
132.
José M. Baldasano María Gonçalves Albert Soret Pedro Jiménez-Guerrero 《Atmospheric environment (Oxford, England : 1994)》2010,44(25):2997-3006
Assessing the effects of air quality management strategies in urban areas is a major concern worldwide because of the large impacts on health caused by the exposure to air pollution. In this sense, this work analyses the changes in urban air quality due to the introduction of a maximum speed limit to 80 km h?1 on motorways in a large city by using a novel methodology combining traffic assimilation data and modelling systems implemented in a supercomputing facility. Albeit the methodology has been non-specifically developed and can be extrapolated to any large city or megacity, the case study of Barcelona is presented here. Hourly simulations take into account the entire year 2008 (when the 80 km h?1 limit has been introduced) vs. the traffic conditions for the year 2007. The data has been assimilated in an emission model, which considers hourly variable speeds and hourly traffic intensity in the affected area, taken from long-term measurement campaigns for the aforementioned years; it also permits to take into account the traffic congestion effect. Overall, the emissions are reduced up to 4%; however the local effects of this reduction achieve an important impact for the adjacent area to the roadways, reaching 11%. In this sense, the speed limitation effects assessed represent enhancements in air quality levels (5–7%) of primary pollutants over the area, directly improving the welfare of 1.35 million inhabitants (over 41% of the population of the Metropolitan Area) and affecting 3.29 million dwellers who are potentially benefited from this strategy for air quality management (reducing 0.6% the mortality rates in the area). 相似文献
133.
Juhee Kim Minhee Kim Seunghun Hyun Jeong-Gyu Kim Yong Sik Ok 《Journal of environmental science and health. Part. B》2013,48(1):22-29
The fate of the acidic organic solute from the soil-water-solvent system is not well-understood. In this study, the effect of the acidic functional group of organic solute in the sorption from cosolvent system was evaluated. The sorption of naphthalene (NAP) and 1-naphthoic acid (1-NAPA) by three kaolinitic soils and two model sorbents (kaolinite and humic acid) were measured as functions of the methanol volume fractions (f c ≤ 0.4) and ionic compositions (CaCl2 and KCl). The solubility of 1-NAPA was also measured in various ionic compositions. The sorption data were interpreted using the cosolvency-induced sorption model. The K m values (= the linear sorption coefficient) of NAP with kaolinitic soil for both ionic compositions was log linearly decreased with f c. However, the K m values of 1-NAPA with both ionic compositions remained relatively constant over the f c range. For the model sorbent, the K m values of 1-NAPA with kaolinite for the KCl system and with humic acid for both ionic compositions decreased with f c, while the sorption of 1-NAPA with kaolinite for the CaCl2 system was increased with f c. From the solubility data of 1-NAPA with f c, no significant difference was observed with the different ionic compositions, indicating an insignificant change in the aqueous activity of the liquid phase. In conclusion, the enhanced 1-NAPA sorption, greater than that predicted from the cosolvency-induced model, was due to an untraceable interaction between the carboxylate and hydrophilic soil domain in the methanol-water system. Therefore, in order to accurately predict the environmental fate of acidic pesticides and organic solutes, an effort to quantitatively incorporate the enhanced hydrophilic sorption into the current cosolvency-induced sorption model is required. 相似文献
134.
Crestani M Menezes C Glusczak L dos Santos Miron D Spanevello R Silveira A Gonçalves FF Zanella R Loro VL 《Chemosphere》2007,67(11):2305-2311
The effects of the herbicide, clomazone, on acetylcholinesterase (AChE), catalase and TBARS formation in teleost fish (Rhamdia quelen) were studied. The fish were exposed to 0.5 or 1.0 mg L−1 of clomazone for 12, 24, 48, 96 and 192 h. After 192 h of exposure period, fish were transferred to clean water and kept in the same for 192 h to study the recovery response. Same parameters as that of exposure period were assayed after 96 and 192 h of recovery period. Specific AChE activity was reduced in the brain and muscle after treatments, reaching a maximum inhibition of 47% in the brain and 45% in the muscle after 12 h of exposure. Fish exposed to clomazone increased TBARS production in the liver for all exposure periods. The brain presented elevated TBARS levels after 12, 24 and 48 h, but after 96 and 192 h, these levels decreased. The decrease of TBARS levels persisted in brain tissue after 96 h of recovery and returned to the control value after 192 h in clean water. Catalase activity was reduced for all periods of exposure. Histological analysis showed vacuolation in the liver after herbicide exposure. Some of the alterations observed were completely restored after recovery period. 相似文献
135.
M.T. Pay M. Piot O. Jorba S. Gassó M. Gonçalves S. Basart D. Dabdub P. Jiménez-Guerrero J.M. Baldasano 《Atmospheric environment (Oxford, England : 1994)》2010,44(27):3322-3342
The CALIOPE-EU high-resolution air quality modeling system, namely WRF-ARW/HERMES-EMEP/CMAQ/BSC-DREAM8b, is developed and applied to Europe (12 km × 12 km, 1 h). The model performances are tested in terms of air quality levels and dynamics reproducibility on a yearly basis. The present work describes a quantitative evaluation of gas phase species (O3, NO2 and SO2) and particulate matter (PM2.5 and PM10) against ground-based measurements from the EMEP (European Monitoring and Evaluation Programme) network for the year 2004. The evaluation is based on statistics. Simulated O3 achieves satisfactory performances for both daily mean and daily maximum concentrations, especially in summer, with annual mean correlations of 0.66 and 0.69, respectively. Mean normalized errors are comprised within the recommendations proposed by the United States Environmental Protection Agency (US-EPA). The general trends and daily variations of primary pollutants (NO2 and SO2) are satisfactory. Daily mean concentrations of NO2 correlate well with observations (annual correlation r = 0.67) but tend to be underestimated. For SO2, mean concentrations are well simulated (mean bias = 0.5 μg m?3) with relatively high annual mean correlation (r = 0.60), although peaks are generally overestimated. The dynamics of PM2.5 and PM10 is well reproduced (0.49 < r < 0.62), but mean concentrations remain systematically underestimated. Deficiencies in particulate matter source characterization are discussed. Also, the spatially distributed statistics and the general patterns for each pollutant over Europe are examined. The model performances are compared with other European studies. While O3 statistics generally remain lower than those obtained by the other considered studies, statistics for NO2, SO2, PM2.5 and PM10 present higher scores than most models. 相似文献
136.
Heavy metal immobilization in soil near abandoned mines using eggshell waste and rapeseed residue 总被引:3,自引:0,他引:3
Sang Soo Lee Jung Eun Lim Samy A. M. Abd El-Azeem Bongsu Choi Sang-Eun Oh Deok Hyun Moon Yong Sik Ok 《Environmental science and pollution research international》2013,20(3):1719-1726
Heavy metal contamination of agricultural soils has received great concern due to potential risk to human health. Cadmium and Pb are largely released from abandoned or closed mines in Korea, resulting in soil contamination. The objective of this study was to evaluate the effects of eggshell waste in combination with the conventional nitrogen, phosphorous, and potassium fertilizer (also known as NPK fertilizer) or the rapeseed residue on immobilization of Cd and Pb in the rice paddy soil. Cadmium and Pb extractabilities were tested using two methods of (1) the toxicity characteristics leaching procedure (TCLP) and (2) the 0.1 M HCl extraction. With 5 % eggshell addition, the values of soil pH were increased from 6.33 and 6.51 to 8.15 and 8.04 in combination with NPK fertilizer and rapeseed residue, respectively, compared to no eggshell addition. The increase in soil pH may contribute to heavy metal immobilization by altering heavy metals into more stable in soils. Concentrations of TCLP-extracted Cd and Pb were reduced by up to 67.9 and 93.2 % by addition of 5 % eggshell compared to control. For 0.1 M HCl extraction method, the concentration of 0.1 M HCl-Cd in soils treated with NPK fertilizer and rapeseed residue was significantly reduced by up to 34.01 and 46.1 %, respectively, with 5 % eggshell addition compared to control. A decrease in acid phosphatase activity and an increase in alkaline phosphatase activity at high soil pH were also observed. Combined application of eggshell waste and rapeseed residue can be cost-effective and beneficial way to remediate the soil contaminated with heavy metals. 相似文献
137.
Application of eggshell waste for the immobilization of cadmium and lead in a contaminated soil 总被引:2,自引:0,他引:2
Ok YS Lee SS Jeon WT Oh SE Usman AR Moon DH 《Environmental geochemistry and health》2011,33(Z1):31-39
Liming materials have been used to immobilize heavy metals in contaminated soils. However, no studies have evaluated the use of eggshell waste as a source of calcium carbonate (CaCO?) to immobilize both cadmium (Cd) and lead (Pb) in soils. This study was conducted to evaluate the effectiveness of eggshell waste on the immobilization of Cd and Pb and to determine the metal availability following various single extraction techniques. Incubation experiments were conducted by mixing 0-5% powdered eggshell waste and curing the soil (1,246 mg Pb kg?1 soil and 17 mg Cd kg?1 soil) for 30 days. Five extractants, 0.01 M calcium chloride (CaCl?), 1 M CaCl?, 0.1 M hydrochloric acid (HCl), 0.43 M acetic acid (CH?COOH), and 0.05 M ethylendiaminetetraacetic acid (EDTA), were used to determine the extractability of Cd and Pb following treatments with CaCO? and eggshell waste. Generally, the extractability of Cd and Pb in the soils decreased in response to treatments with CaCO? and eggshell waste, regardless of extractant. Using CaCl? extraction, the lowest Cd concentration was achieved upon both CaCO? and eggshell waste treatments, while the lowest Pb concentration was observed using HCl extraction. The highest amount of immobilized Cd and Pb was extracted by CH?COOH or EDTA in soils treated with CaCO? and eggshell waste, indicating that remobilization of Cd and Pb may occur under acidic conditions. Based on the findings obtained, eggshell waste can be used as an alternative to CaCO? for the immobilization of heavy metals in soils. 相似文献
138.
Igalavithana Avanthi Deshani Farooq Muhammad Kim Kye-Hoon Lee Young-Han Qayyum Muhammad Farooq Al-Wabel Mohammad I. Lee Sang Soo Ok Yong Sik 《Environmental geochemistry and health》2018,40(1):559-559
Environmental Geochemistry and Health - Unfortunately, in the original publication of the article, Prof. Yang Sik Ok’s affiliation was incorrectly published. The author’s affiliation is... 相似文献
139.
Vithanage Meththika Herath Indika Almaroai Yaser A. Rajapaksha Anushka Upamali Huang Longbin Sung Jwa-Kyung Lee Sang Soo Ok Yong Sik 《Environmental geochemistry and health》2018,40(1):565-565
Environmental Geochemistry and Health - Unfortunately, in the original publication of the article, Prof. Yong Sik Ok’s affiliation was incorrectly published. The author’s affiliation is... 相似文献
140.
Vithanage Meththika Seneviratne Mihiri Ahmad Mahtab Sarkar Binoy Ok Yong Sik 《Environmental geochemistry and health》2018,40(1):569-569
Environmental Geochemistry and Health - Unfortunately, in the original publication of the article, Prof. Yong Sik Ok’s affiliation was incorrectly published. The author’s affiliation is... 相似文献