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51.
Zinc adsorption equilibria were measured in soils differing in pH but with similar textures and total zinc concentrations, using adsorption isotherm and isotopic exchange techniques. The results suggested that the equilibrium between solution and exchangeable zinc was strongly pH dependent and the active zinc species in adsorption was single charged (e.g. Zn(OH)(+)). The size of the exchangeable zinc pool was not strongly pH dependent. Similar results were obtained when zinc was added to the soils, either as Zn(NO(3))(2) or in sewage sludge. 相似文献
52.
The Influence of Mycorrhiza on Uranium and Phosphorus Uptake by Barley Plants from a Field-contaminated Soil (7 pp) 总被引:3,自引:0,他引:3
Chen B Zhu YG Zhang X Jakobsen I 《Environmental science and pollution research international》2005,12(6):325-331
Background Recent studies indicated that arbuscular mycorrhizal fungi (AMF) play important roles in plant accumulation of uranium (U)
from contaminated environments, but the impacts of fertilization practices on functioning of the symbiotic associations, which
are crucial factors influencing plant nutrition and growth responses to mycorrhiza, have rarely been considered.
Materials and Methods In a greenhouse experiment, a bald root barley mutant (brb) together with the wild type (wt) were used to test the role of
root hairs and AMF in uranium (U) uptake by host plants from a U contaminated soil. Nil, 20 and 60 mg KH2PO4-P kg–1 soil were
included to investigate the influences of phosphorus (P) fertilization on plant growth and accumulation of U.
Results Dry matter yield of barley plants increased with increasing P additions and wt produced significantly higher dry weight than
brb. Mycorrhiza markedly improved dry matter yield of both genotypes grown at nil P, whereas only brb responded positively
to mycorrhiza at 20 mg P kg-1. At the highest P level, mycorrhiza resulted in growth depressions in both genotypes, except
for the roots of wt. In general, plant P concentrations increased markedly with increasing P additions and in response to
mycorrhiza.
Mycorrhiza and P additions had no significant effects on shoot U concentrations. However, root U concentrations in both genotypes
were significantly increased by mycorrhiza. On the other hand, shoot U contents increased with increasing P levels, while
20 mg P kg-1 stimulated, but 60 mg P kg-1 marginally affected the U accumulation in roots. Root length specific U uptake was
moderately enhanced both by root hairs and strongly enhanced by mycorrhiza. Moreover, non-inoculated plants generally had
higher shoot-root ratios of U content than the corresponding inoculated controls.
Conclusion Our study shows that AMF and root hairs improves not only P acquisition but also the root uptake of U, and mycorrhiza generally
decreases U translocation from plant root to shoot. Hence, mycorrhiza is of potential use in the phytostabilization of U contaminated
environments.
Perspectives The complex impacts of P on U accumulation by barley plants suggested that U behavior in mycorrhizosphere and translocation
along the soil-fungi-plant continuum as affected by fertilization practices deserve extensive studies for optimizing the function
of mycorrhizal associations for phytoremediation purposes. 相似文献
53.
Ahde El Imache Sylvie Dousset Ahmed Satrallah Abdelmalek Dahchour 《Journal of environmental science and health. Part. B》2013,48(3):161-167
The Gharb region in Morocco is an important agricultural zone where soils receive pesticide treatments and organic amendments to increase yields. The groundwater aquifer in the Gharb region is relatively shallow and thus vulnerable. The objective of this work was to study the influence of organic amendments on diuron, cyhalofop-butyl and procymidone leaching through undisturbed soil columns. Two soils were sampled from the Gharb region, a Dehs (sandy soil) and a R’mel (loamy clay soil). Following elution (124.5 mm), the amount of pesticide residues in the leachates of the sandy soil (0.06–0.21 %) was lower than in those of the loamy clay soil (0.20–0.36 %), which was probably due to preferential flow through the loamy clay soil. The amount of procymidone leached through the amended soil columns was greater than the control for the sandy soil only. The organic amendments did not significantly influence diuron and cyhalofop-butyl leaching in either of the soils. The application of organic amendments affected the amounts of dissolved organic matter (DOM) eluted and thus pesticide leaching as a function of soil-type. Nevertheless, in some case, the formation of pesticide-DOM complexes appeared to promote pesticide leaching, thus increasing groundwater contamination risks. 相似文献
54.
Yu X Zhou P Zhou X Liu Y 《Environmental science and pollution research international》2005,12(4):221-226
Background Little is known about metabolism rates of environmental chemicals by vegetation. A good model compound to study the variation
of rates among plant species is cyanide. Vascular plants possess an enzyme system that detoxifies cyanide by converting it
to the amino acid asparagine. Knowledge of the kinetic parameters, the half-saturation constant (Km) and the maximum metabolic
capacity (vmax), is very useful for enzyme characterization and biochemical purposes. The goal of this study is to find the
enzyme kinetics (KM and vmax) during cyanide metabolism in the presence of Chinese vegetation, to provide quantitative data
for engineered phytoremediation, and to investigate the variation of metabolic rates of plants.
Methods Detached leaves (1.0 g fresh weight) from 12 species out of 9 families were kept in glass vessels with 100 mL of aqueous
solution spiked with potassium cyanide at 23°C for 28 h. Four different treatment concentrations of cyanide were used, ranging
from 0.44 to 7.69 mg CN/L. The disappearance of cyanide from the aqueous solution was analyzed spectrophotometrically. Realistic
values of the half-saturation constant (KM) and the maximum metabolic capacity (vmax) were estimated by a computer program
using non-linear regression treatments. As a comparison, Lineweaver-Burk plots were also used to estimate the kinetic parameters.
Results and Discussion The values obtained for KM and vmax varied with plant species. Using non-linear regression treatments, values of vmax and
KM were found in a range between 6.68 and 21.91 mg CN/kg/h and 0.90 to 3.15 mg CN/L, respectively. The highest vmax was by
Chinese elder (Sambucus chinensis), followed by upright hedge-parsley (Torilis japonica). The lowest vmax was demonstrated
by the hybrid willow (Salix matssudana x alba). However, the highest KM was found in the water lily (Nymphea teragona), followed
by the poplar (Populus deltoides Marsh). The lowest KM was demonstrated by corn (Zea mays L.). The values of vmax were normally
distributed with a mean of 13 mg CN/kg/h.
Conclusions Significant removal of cyanide from aqueous solution was observed in the presence of plant materials without phytotoxicity,
even at high doses of cyanide. This gives rise to the conclusion that the Chinese plant species used in this study are all
able to efficiently metabolize cyanide, although with different maximum metabolic capacities. A second conclusion is that
the variation of metabolism rates between species is small. All these plants had a similar KM, indicating the same enzyme
is active in all plants.
Recommendations and Outlook Detoxification of cyanide with trees seems to be a feasible option for cleaning soils and water contaminated with cyanide.
For phytoremediation projects, screening appropriate plant species adapted to local conditions should be seriously considered.
More chemicals should be investigated to find common principles of the metabolism of environmental chemicals by plants. 相似文献
55.
Atmospheric BTEX concentrations in the vicinity of the crude oil refinery of the Baltic region 总被引:1,自引:0,他引:1
Baltrėnas P Baltrėnaitė E Serevičienė V Pereira P 《Environmental monitoring and assessment》2011,182(1-4):115-127
Among chemical industries, petroleum refineries have been identified as large emitters of a wide variety of pollutants. Benzene, toluene, ethylbenzene, and xylene (BTEX) form an important group of aromatic volatile organic compounds (VOCs) because of their role in the troposphere chemistry and the risk posed to human health. A very large crude oil refinery of the Baltic States (200,000 bbl/day) is situated in the northern, rural part of Lithuania, 10 km from the town of Ma?eikiai (Lithuania). The objectives of this study were: (1) to determine of atmospheric levels of BTEX in the region rural and urban parts at the vicinity of the crude oil refinery; and (2) to investigate the effect of meteorological parameters (wind speed, wind direction, temperature, pressure, humidity) on the concentrations measured. The averaged concentration of benzene varied from 2.12 ppbv in the rural areas to 2.75 ppbv in the urban areas where the traffic was determined to be a dominant source of BTEX emissions. Our study showed that concentration of benzene, as strictly regulated air pollutant by EU Directive 2008/50/EC, did not exceed the limit of 5 ppbv in the region in the vicinity of the crude oil refinery during the investigated period. No significant change in air quality in the vicinity of the oil refinery was discovered, however, an impact of the industry on the background air quality was detected. The T/B ratio (0.50-0.81) that was much lower than 2.0, identified other sources of pollution than traffic. 相似文献
56.
Th. Knacker und J. R?mbke 《Umweltwissenschaften und Schadstoff-Forschung》2008,20(4):301-302
Ohne Zusammenfassung 相似文献
57.
Ohne Zusammenfassung
Original erschienen in UWSF – Z Umweltchem ?kotox 20(2):133–144 (2008) DOI:
Herausgeber: Martin Pehnt und Eckard Helmers 相似文献
58.
The Distribution and Sources of Polycyclic Aromatic Hydrocarbons in Surface Sediments Along the Egyptian Mediterranean Coast 总被引:2,自引:0,他引:2
El Nemr A Said TO Khaled A El-Sikaily A Abd-Allah AM 《Environmental monitoring and assessment》2007,124(1-3):343-359
Coastal marine sediment samples were collected from 31 sampling stations along the Egyptian Mediterranean Sea coast. All sediment
samples were analyzed to determine aliphatic and polycyclic aromatic hydrocarbons (PAHs) as well as total organic carbon (TOC)
contents and grain size analysis. Total concentrations of 16 EPA-PAHs in the sediments were varied from 88 to 6338 ng g−1 with an average value of 154 ng g−1 (dry weight). However, the concentrations of total aliphatic were varied from 1.3 to 69.9 ng g−1 with an average value of 15.6 ng g−1 (dry weight). The highest contents of PAHs were found in the Eastern harbor (6338 ng g−1), Manzala (5206 ng g−1) and El-Jamil East (4895 ng g−1) locations. Good correlations observed between a certain numbers of PAH concentrations allowed to identify its origin. The
average total organic carbon (TOC) percent was varied from 0.91 to 4.54%. Higher concentration of total pyrolytic hydrocarbons
(∑COMB) than total fossil hydrocarbons (∑PHE) declared that atmospheric fall-out is the significant source of PAHs to marine
sediments of the Egyptian Mediterranean coast. The selected marked compounds, a principal component analysis (PCA) and special
PAHs compound ratios (phenanthrene/anthracene vs fluoranthene/pyrene; ∑COMB/∑EPA-PAHs) suggest the pyrogenic origins, especially
traffic exhausts, are the dominant sources of PAHs in most locations. Interferences of rather petrogenic and pyrolytic PAH
contaminations were noticed in the harbors due to petroleum products deliveries and fuel combustion emissions from the ships
staying alongside the quays. 相似文献
59.
This work examines the performance of a hydrous ferric oxide (HFO) reactive filtration (RF) process with coupled chemically enhanced secondary treatment (RECYCLE) for phosphorus removal from municipal wastewater (HFO-RF-RECYCLE). A 3-month, 0.95-ML/d (0.25-mgd) demonstration of HFO-RF-RECYCLE was performed at a municipal wastewater treatment plant equipped with oxidation ditches and secondary clarifiers. Influent to the plant averaged 6.0 mg/L phosphorus, with a tertiary effluent average of 0.011 mg/L phosphorus. Iron doses to the plant were low, at 5 mg/L. Inline recycling of HFO solution rejects to the plant influent resulted in a maximum 90.3%, dose-dependent reduction of phosphorus in the secondary effluent at 4.5 ML/d (1.2 mgd). Other results included reduction of total suspended solids and turbidity. A mass balance analysis was performed. We conclude that HFO-RF-RECYCLE may allow very low levels of phosphorus discharge from municipal wastewater treatment plants with a ferric-iron-based tertiary filtration process and residual recycling. 相似文献
60.
Asbj?rn Haaning Nielsen Jes Vollertsen Henriette Stokbro Jensen Heidi Ina Madsen Thorkild Hvitved-Jacobsen 《Water environment research》2008,80(1):16-25
The formation and fate of sulfide in a force main and a downstream-located gravity sewer were investigated in an extensive field study. Sulfide formation in the force main was significant. However, during 14 minutes of transport in the gravity sewer, the sulfide concentration decreased 30%, on average. An application of a conceptual sewer process model for simulating the formation and fate of sulfide was demonstrated. Overall, the model predicted that approximately 90% of the decrease of the sulfide concentration in the gravity sewer was the result of sulfide oxidation and that only a small fraction entered the sewer atmosphere, causing odor and corrosion. Even so, the model predicted concrete corrosion rates of up to 1.2 mm/y in the gravity sewer section. 相似文献