全文获取类型
收费全文 | 1572篇 |
免费 | 5篇 |
国内免费 | 7篇 |
专业分类
安全科学 | 10篇 |
废物处理 | 71篇 |
环保管理 | 80篇 |
综合类 | 522篇 |
基础理论 | 362篇 |
污染及防治 | 364篇 |
评价与监测 | 97篇 |
社会与环境 | 68篇 |
灾害及防治 | 10篇 |
出版年
2017年 | 15篇 |
2016年 | 20篇 |
2014年 | 21篇 |
2013年 | 69篇 |
2012年 | 22篇 |
2011年 | 45篇 |
2010年 | 44篇 |
2009年 | 48篇 |
2008年 | 66篇 |
2007年 | 51篇 |
2006年 | 46篇 |
2005年 | 45篇 |
2004年 | 41篇 |
2003年 | 37篇 |
2002年 | 48篇 |
2001年 | 59篇 |
2000年 | 54篇 |
1999年 | 34篇 |
1998年 | 20篇 |
1997年 | 30篇 |
1996年 | 28篇 |
1995年 | 30篇 |
1994年 | 28篇 |
1993年 | 26篇 |
1992年 | 19篇 |
1991年 | 36篇 |
1990年 | 50篇 |
1989年 | 23篇 |
1988年 | 27篇 |
1987年 | 20篇 |
1985年 | 21篇 |
1984年 | 21篇 |
1983年 | 16篇 |
1982年 | 30篇 |
1979年 | 18篇 |
1978年 | 13篇 |
1977年 | 15篇 |
1976年 | 13篇 |
1974年 | 17篇 |
1972年 | 17篇 |
1971年 | 12篇 |
1969年 | 11篇 |
1968年 | 12篇 |
1967年 | 23篇 |
1966年 | 19篇 |
1965年 | 13篇 |
1964年 | 12篇 |
1962年 | 13篇 |
1958年 | 14篇 |
1957年 | 12篇 |
排序方式: 共有1584条查询结果,搜索用时 31 毫秒
951.
Dong W Xie G Miller TR Franklin MP Oxenberg TP Bouwer EJ Ball WP Halden RU 《Environmental pollution (Barking, Essex : 1987)》2006,142(1):132-142
Directly adjacent to the Chesapeake Bay lies the Aberdeen Proving Ground, a U.S. Army facility where testing of armor-piercing ammunitions has resulted in the deposition of >70,000 kg of depleted uranium (DU) to local soils and sediments. Results of previous environmental monitoring suggested limited mobilization in the impact area and no transport of DU into the nation's largest estuary. To determine if physical and biological reactions constitute mechanisms involved in limiting contaminant transport, the sorption and biotransformation behavior of the radionuclide was studied using geochemical modeling and laboratory microcosms (500 ppb U(VI) initially). An immediate decline in dissolved U(VI) concentrations was observed under both sterile and non-sterile conditions due to rapid association of U(VI) with natural organic matter in the sediment. Reduction of U(VI) to U(IV) occurred only in non-sterile microcosms. In the non-sterile samples, intrinsic bioreduction of uranium involved bacteria of the order Clostridiales and was only moderately enhanced by the addition of acetate (41% vs. 56% in 121 days). Overall, this study demonstrates that the migration of depleted uranium from the APG site into the Chesapeake Bay may be limited by a combination of processes that include rapid sorption of U(VI) species to natural organic matter, followed by slow, intrinsic bioreduction to U(IV). 相似文献
952.
Comber SD Conrad AU Höss S Webb S Marshall S 《Environmental pollution (Barking, Essex : 1987)》2006,144(2):661-668
The toxicity of linear alkylbenzene sulphonates (LAS), to freshwater benthic organisms was assessed during exposure to spiked sediment. Lethal and sub-lethal end-points were monitored for two organisms (oligochaete Lumbriculus variegatus and nematode Caenorhabditis elegans). Results demonstrated relatively low toxicity (LOECs>100 mg/kg dry weight). No observed effect concentrations (NOECs) of 81 mg/kg dw (Lumbriculus) and 100 mg/kg dw (Caenorhabditis) were determined. For the oligochaete, no specific endpoint was particularly sensitive to LAS. For the nematode, egg production was the most sensitive endpoint. Significant degradation was measured over the 28-day duration of the Lumbriculus study, equating to a half-life of 20 days in sediment. 相似文献
953.
Mechanisms of competitive adsorption of Pb, Cu, and Cd on peat 总被引:15,自引:0,他引:15
Qin F Wen B Shan XQ Xie YN Liu T Zhang SZ Khan SU 《Environmental pollution (Barking, Essex : 1987)》2006,144(2):669-680
Combined use of batch equilibration adsorption and X-ray absorption spectroscopy (XAS) was employed to study the mechanisms of competitive adsorption of Pb, Cu, and Cd on Danish and Heilongjiang peat in single- and multi-solute systems. The adsorption capacity and initial adsorption rate on the same peat in single-solute systems followed the order Pb>Cu>Cd. Both the adsorbed amount of each metal (q'm) and its initial adsorption rate were decreased in multi-solute systems. It was observed that the adsorbed amounts of metals at low-energy adsorption sites (qm,1) decreased pronouncedly compared to those at high-energy adsorption sites (qm,2), indicating that the competitive adsorption of Pb, Cu and Cd occurred mainly at the low-energy adsorption sites. XAS study revealed that both Pb and Cu were coordinated in peat predominantly to carboxylic moieties without excluding the hydroxyl groups, thereby providing an insight into the mechanism of competitive adsorption of Pb and Cu on peat. 相似文献
954.
Determining gaseous emission factors and driver's particle exposures during traffic congestion by vehicle-following measurement techniques 总被引:3,自引:0,他引:3
Vehicle gaseous emissions (NO, CO, CO2, and hydrocarbon [HC]) and driver's particle exposures (particulate matter < 1 microm [PM1], < 2.5 microm [PM2.5], and < 10 microm [PM10]) were measured using a mobile laboratory to follow a wide variety of vehicles during very heavy traffic congestion in Macao, Special Administrative Region, People's Republic of China, an urban area having one of the highest population densities in the world. The measurements were taken with high time resolution so that fluctuations in the emissions can be seen readily during vehicle acceleration, cruising, deceleration, and idling. The tests were conducted in close proximity to the vehicles, with the inlet of a five-gas analyzer mounted on the front bumper of the mobile laboratory, and the distance between the vehicles was usually within several meters. To measure the driver's particle exposures, the inlets of the particle analyzers were mounted at the height of the driver's breathing position in the mobile laboratory, with the driver's window open. A total of 178 and 113 vehicles were followed individually to determine the gaseous emission factor and the driver's particle exposures, respectively, for motorcycle, passenger car, taxi, truck, and bus. The gaseous emission factors were used to model the roadside air quality, and good correlations between the modeled and monitored CO, NO2, and nitrogen oxide (NO(x)) verified the reliability of the experiments. Compared with petrol passenger cars and petrol trucks, diesel taxies and diesel trucks emitted less CO but more NO(x). The impact of urban canyons is shown to cause a significant increase in the PM1 peak. The background concentrations contributed a significant amount of the driver's particle exposures. 相似文献
955.
Availability of reliable emission measurements of concentrated volatile organic compounds (VOCs) bear great significance in facilitating the selection of a feasible emission abatement technique. There are numerous methods, which can be used to measure VOC emissions, however, there is no single method that would allow sampling of the whole range of volatile organics. In addition, research efforts are usually directed to the development of measuring VOCs in diluted concentrations. Therefore, there is a need for a novel measurement method, which can give reliable results while entailing simple operations and low costs. This paper represents a development effort of finding a reliable measurement procedure. A methodology is proposed and used to measure solvent emissions from coating processes. 相似文献
956.
We evaluated the suitability of single and multiple cell type cultures as model systems to characterise cellular kinetics of highly lipophilic compounds with potential ecotoxicological impact. Confluent mono-layers of human skin fibroblasts, rat astrocytoma C6 cells, non-differentiated and differentiated mouse 3T3 cells were kept in culture medium supplemented with 10% foetal calf serum. For competitive uptake experiments up to four different cell types, grown on glass sectors, were exposed for 3 h to 14C-labelled model compounds, dissolved either in organic solvents or incorporated into unilamellar lecithin liposomes. Bromo-, or chloro-benzenes, decabromodiphenylether (DBP), and dichlorodiphenyl ethylene (DDE) were tested in rather high concentration of 20 μM. Cellular toxicity was low. Compound levels were related to protein, DNA, and triglyceride contents. Cellular uptake was fast and dependent on physico-chemical properties of the compounds (lipophilicity, molecular size), formulation, and cell type. Mono-halogenated benzenes showed low and similar uptake levels (= low accumulation compounds). DBP and DDE showed much higher cellular accumulations (= high accumulation compounds) except for DBP in 3T3 cells. Uptake from liposomal formulations was mostly higher than if compounds were dissolved in organic solvents. The extent of uptake correlated with the cellular content of triglycerides, except for DBP. Uptake competition between different cell types was studied in a sectorial multi-cell culture model. For low accumulation compounds negligible differences were found among C6 cells and fibroblasts. Uptake of DDE was slightly and that of DBP highly increased in fibroblasts. Well-defined cell culture systems, especially the sectorial model, are appropriate to screen for bioaccumulation and cytotoxicity of (unknown) chemical entities in vitro. 相似文献
957.
Satya Narayan H. M. Dani U. K. Misra 《Journal of environmental science and health. Part. B》2013,48(2):259-272
Abstract The effect of intracheally administered DDT (5 mg/100 g body weight) or endosulfan (1 mg/100 g body weight) for three cosecutive days have been studied on lipid metabolism of rat lung subcellular fractions. Both the insecticides did not affect the lung weight and the protein contents of microsomes, lamellar bodies and surfactant but significantly increased the phospholipid contents of microsomal and surfactant system. Most of the neutral lipid components of lung subcellular fractions were also increased by DDT or endosulfan treatments, except that of surfactant triglycerides which were decreased by DDT treatment. DDT or endosulfan both increased the incorporation of radioactive [methyl‐3H]choline into microsomal phosphatidylcholine (PC) and surfactant dipalmitoylphosphatidylcholine (DPPC) without affecting the incorporation of radioactive [methyl‐14C]methionine, showing the increased synthesis of PC via CDPcholine pathway. The results presented in this communication showed that DDT and endosulfan, the two different chloroinsecticides have similar effects on microsomal lipid metabolism but produce different biochemical manifestations on the secretion of surfactant phospholipids. 相似文献
958.
Antonella Soro Manfred Ayasse Marion U. Zobel Robert J. Paxton 《Behavioral ecology and sociobiology》2011,65(4):641-653
The ability to discriminate degrees of relatedness may be expected to evolve if it allows unreciprocated altruism to be preferentially
directed towards kin (Hamilton in J Theor Biol 7:1–16, 1964). We explored the possibility of kin recognition in the primitively eusocial halictid bee Lasioglossum malachurum by investigating the reliability of worker odour cues that can be perceived by workers to act as indicators of either nest
membership or kinship. Cuticular and Dufour’s gland compounds varied significantly among colonies of L. malachurum, providing the potential for nestmate discrimination. A significant, though weak, negative correlation between chemical distance
and genetic relatedness (r = −0.055, p < 0.001) suggests a genetic component to variation in cuticular bouquet, but odour cues were not informative enough to discriminate
between different degrees of relatedness within nests. This pattern of variation was similar for Dufour’s gland bouquets.
The presence of unrelated individuals within nests that are not chemically different from their nestmates suggests that the
discrimination system of L. malachurum is prone to acceptance errors. Compounds produced by colony members are likely combined to generate a gestalt colony chemical
signature such that all nestmates have a similar smell. The correlation between odour cues and nest membership was greater
for perceived compounds than for non-perceived compounds, suggesting that variability in perceived compounds is a result of
positive selection for nestmate recognition despite potentially stabilising selection to reduce variability in odour differences
and thereby to reduce costs derived from excessive intracolony nepotistic behaviour. 相似文献
959.
Honey U. K. Pillai K. A. Jayaraj M. Rafeeq K. J. Jayalakshmi C. Revichandran 《Environmental monitoring and assessment》2011,176(1-4):239-250
The study addresses the distribution and diversity of mesozooplankton near the active volcano-Barren Island (Andaman Sea) in the context of persistent volcanic signature and warm air pool existing for the last few months. Sampling was done from the stations along the west and east side of the volcano up to a depth of 1,000 m during the inter monsoon (April) of 2006. Existence of feeble warm air pool was noticed around the Island (Atm. Temp. 29°C). Sea surface temperature recorded as 29.9°C on the west and 29.6°C on the east side stations. High mesozooplankton biomass was observed in the study area than the earlier reports. High density and biomass observed in the surface layer decreased significantly to the deeper depths. Lack of correlation was observed between mesozooplankton biomass and density with chl. a. Twenty-three mesozooplankton taxa were observed with copepoda as the dominant taxa followed by chaetognatha. The relative abundance of chaetognatha considerably affected the copepod population density in the surface layer. A noticeable feature was the presence of cumaceans, a hyperbenthic fauna in the surface, mixed layer and thermocline layer on the western side station where the volcano discharges in to the sea. The dominant order of copepoda, the calanoida was represented by 52 species belonging to 17 families. The order poecilostomatoida also had a significant contribution. Copepods exhibited a clear difference in their distribution pattern in different depth layers. The families Calanidae and Pontellidae showed a clear dominance in the surface whereas small-sized copepods belonging to the families Clausocalanidae and Paracalanidae were observed as the predominant community in the mixed layer and thermocline layer depth. Families Metridinidae, Augaptilidae and Aetideidae were observed as dominant in deeper layers. 相似文献
960.
A new approach to investigate the interactions between sediment transport and ecotoxicological processes during flood events 总被引:1,自引:0,他引:1
Holger Schüttrumpf Markus Brinkmann Catrina Cofalla Roy M Frings Sabine U Gerbersdorf Markus Hecker Sebastian Hudjetz Ulrike Kammann Gottfried Lennartz Sebastian Roger Andreas Schäffer Henner Hollert 《Environmental Sciences Europe》2011,23(1):1-5