Results from Three Field Tracer Experiments on the Neighbourhood Scale in the City of Birmingham UK

The physical processes governing flow and pollutantdispersion at the neighbourhood scale, a spatial scaleintermediate between the street scale and the city scale, is notwell understood. Furthermore, it is not clear whether a traditional approach using averaged characteristics such as theaerodynamic roughness length is sufficient to predict the concentration field at this scale. To investigate pollutant dispersion in a real urban area, three field experiments were designed within the UK-URGENT programme sponsored by NERC. Theexperiments were performed in the City of Birmingham using a finite duration release of inert, non-toxic and non-depositingtracers, vis. perfluoromethylcyclohexane (PMCH) and perfluoromethylcyclopentane (PMCP). Measurements were taken using air bag samplers placedin an arc at 3.5 km (first experiment) and 1 km (second andthird experiments) from the source; some trap samplers wereplaced outside the main arc in the outskirts of the city. Measurements were analysed in the laboratory using anovel gas-chromatography technique. Data so obtained werecompared with predictions from a simple steady-state modeland a time-dependent model. The concentration-time serieswere very asymmetrical with a sharp rise, a plateau followedby a relatively slow decrease and finally a long-livedplateau above (or possibly very slow decrease to) thebackground level.     

Designating Air Quality Management Areas (AQMAs) in the UK Implications for Securing UK Air Quality Objectives

Across the United Kingdom, the majority of local authoritieshave now completed their first phase of local air qualityreview and assessment work, as required under the AirQuality Strategy for England, Scotland, Wales and NorthernIreland (DETR, 2000a). Emerging from this first phasework is an anticipated suite of over 110 Air QualityManagement Areas (AQMAs). These areas are identifiedlocations where one or more of the national air qualityobjectives are predicted to exceed by specific target dates,and their spatial extent and shape is emerging as highlyvariable. Local authorities are guided to use a variety ofscientific tools to underpin the scientific assessments, anda consideration of uncertainty in both the tools used andsubsequent delineation of AQMAs is likely to affect theemerging management areas significantly. With subsidiarity underpinning the process of local air qualitymanagement (LAQM), local decision-making is anticipated toinfluence the outcome of the LAQM process in its entirety,with the declaration of AQMAs necessitating the preparationand implementation of air quality action plans. UKexperience of the effective management of local air quality,through the designation of AQMAs, demonstrates a valuableframework for other European countries developing mechanismsto manage air quality locally.     

Chemical Changes in Sediment Pore-Waters of an Acidic Mining Lake After Addition of Organic Substrate and Lime for Stimulating Lake Remediation

In the past five years, enclosures have beeninstalled in an acidic mining lake in Lusatia to investigate insitu remediation processes. They were treated with straw, withstraw and Carbokalk, or with Carbokalk alone, where Carbokalkis a by-product of the sugar industry (solid precipitate ofnon-sugars after lime clarification of extracted sugar beetjuice). Sediment samples were taken as cores to get informationabout the behaviour of organic and inorganic components insediment pore-water with depth. Vertical distributions of pH,soluble reactive phosphate, nitrate, ammonium, silica,aluminium, iron, manganese, calcium, magnesium, sodium,potassium, sulphate, and DOC were measured. The resultingprofiles, each consisting of 15 data points at differentdepths, were compared by cluster analysis. The similarities ofsediment cores from different treated enclosures relating toprofiles of chemical components were discussed. Increasedconcentrations of potassium and sulphate were found in pore-water after substrate treatment. The data imply dissolution ofpotassium iron sulphate hydroxide minerals (jarosite) after anincrease of pH caused by dissolution of lime and by sulphatereducing processes which were stimulated by organic substrateaddition.     

Trends in the Water Chemistry of High Altitude Lakes in Europe

Here we present the chemical trends of seven high altitude lakes, analysed within the AL:PE and MOLAR Projects of the EU (1999) and selected on the basis of the availability of complete and reliable data for the period 1984–1999. The lakes are representative of the Scandinavian Alps, the Cairngorm Mountains in Scotland, the Alps and the Pyrenees. Significant trends were identified for some indicators of acidification, for instance pH and alkalinity, but not all lakes reacted similarly to decreasing depositions of sulphate and base cations. Differences in lake response are discussed in relation to recent variations of atmospheric deposition chemistry and associated changes in climatic conditions. Beside individual variations of the studied lakes, depending, among other things, on altitude and morphology, catchment characteristics and climate trends play a major role for the reaction of high altitude lakes on changes in atmospheric depositions.     

Imperatives for attracting investment and technology in the Indian mining sector

In India, the mineral resource inventory and the production of a large number of important minerals have registered significant increases during the last few decades. Yet the country continues to be a net importer of many high value and scarce minerals and metals, like gold, diamond, and several base metals. Exploration and development of the resources of these minerals are technology- and capital-intensive. To bring technology and capital through foreign direct investment (FDI) into the Indian mineral sector, it is imperative to lay stress on: accurate resource estimation and categorization, as well as realistic projection of the true values; rationalization of legislative measures based on R&D studies and reorganization of the implementation machinery; conducive tax structure; notification of acts and rules applicable to offshore mineral resources; time-frames for granting licences and leases; encouragement to labor productivity by rationalizing labor laws; reforms in the monetary system to increase market competitiveness of Indian minerals; and judicial reforms. FDI in the Indian mineral sector is important to firm up the knowledge-base of mineral resources and their optimum exploitation.     

SOIL SALINITY PREDICTION USING ARTIFICIAL NEURAL NETWORKS1

ABSTRACT: This study explores the applicability of Artificial Neural Networks (ANNs) for predicting salt build‐up in the crop root zone. ANN models were developed with salinity data from field lysimeters subirrigated with brackish water. Different ANN architectures were explored by varying the number of processing elements (PEs) (from 1 to 30) for replicate data from a 0.4 m water table, 0.8 m water table, and both 0.4 and 0.8 m water table lysimeters. Different ANN models were developed by using individual replicate treatment values as well as the mean value for each treatment. For replicate data, the models with twenty, seven, and six PEs were found to be the best for the water tables at 0.4 m, 0.8 m and both water tables combined, respectively. The correlation coefficients between observed salinity and ANN predicted salinity of the test data with these models were 0.89, 0.91, and 0.89, respectively. The performance of the ANNs developed using mean salinity values of the replicates was found to be similar to those with replicate data. Not only was there agreement between observed and ANN predicted salinity values, the results clearly indicated the potential use of ANN models for predicting salt build‐up in soil profile at a specific site.     

Use of toxicity identification evaluation techniques to identify dredged material disposal options: A proposed approach

It is common to use the results of various solid-phase and aqueous-fraction toxicity tests as part of the decision-making process for selecting disposal options for dredged sediments. The mere presence of toxicity, however, does not provide a logical basis for selecting economical, environmentally protective disposal techniques. To achieve this, it is necessary to be able to identify specific compounds responsible for sediment toxicity. Toxicity identification evaluation (TIE) procedures, originally developed for complex effluents, represent a useful approach for identifying acutely toxic compounds in dredged materials. Herein we present a conceptual overview for TIE use in part of the decision-making framework for selecting dredged material disposal options; included are discussions concerning appropriate test fractions and species for TIE analyses, and specific TIE manipulations useful for ascertaining whether toxicity is due to any of a number of common sediment contaminants including ammonia, hydrogen sulfide, metals, or nonpolar organics.     

Book reviews

Environment Systems and Decisions -     

Acid rain in Asia

Acid rain has been an issue of great concern in North America and Europe during the past several decades. However, due to the passage of a number of recent regulations, most notably the Clean Air Act in the United States in 1990, there is an emerging perception that the problem in these Western nations is nearing solution. The situation in the developing world, particularly in Asia, is much bleaker. Given the policies of many Asian nations to achieve levels of development comparable with the industrialized world—which necessitate a significant expansion of energy consumption (most derived from indigenous coal reserves)—the potential for the formation of, and damage from, acid deposition in these developing countries is very high. This article delineates and assesses the emissions patterns, meteorology, physical geology, and biological and cultural resources present in various Asian nations. Based on this analysis and the risk factors to acidification, it is concluded that a number of areas in Asia are currently vulnerable to acid rain. These regions include Japan, North and South Korea, southern China, and the mountainous portions of Southeast Asia and southwestern India. Furthermore, with accelerated development (and its attendant increase in energy use and production of emissions of acid deposition precursors) in many nations of Asia, it is likely that other regions will also be affected by acidification in the near future. Based on the results of this overview, it is clear that acid deposition has significant potential to impact the Asian region. However, empirical evidence is urgently needed to confirm this and to provide early warning of increases in the magnitude and spread of acid deposition and its effects throughout this part of the world.