UVΑ pre-irradiation to P25 titanium dioxide nanoparticles enhanced its toxicity towards freshwater algae Scenedesmus obliquus

Environmental Science and Pollution Research - There has recently been an increase in the usage of TiO2 nanoparticles (NPs). P25 TiO2 NPs, a mixture of anatase and rutile phase in 3:1 ratio, are...     

Bacterial response to dynamic metal concentrations in the surface sediments of a solar saltern (Goa, India)

The Ribandar solar saltern, situated adjacent to the Mandovi estuary is influenced by the barge transport of ferromanganese ore to the Mormugao harbour (Arabian Sea). The current study focuses on the distribution of metals and related heterotrophic bacterial populations in the surface sediments (0–10 cm) of the Ribandar salterns (Goa, India) during the salt-making (January to May) and non salt-making seasons (August and November). The concentrations of heavy metals in the sediments ranged from 17.2?±?2.8 to 26.3?±?6.7 % Fe; 0.6?±?0.2 to 0.9?±?0.2 % Mn; 27.6?±?7.3 to 51?±?8.3 ppm Ni; 28.4?±?8.9 to 35.2?±?10.6 ppm Co; 44?±?21.6 to 62.8?±?23.6 ppm Zn; 0.1?±?0.01 ppm Cd and 1.7?±?0.1 to 2.6?±?0.7 ppm Pb and were much higher than those reported at the same site in a previous study by Kerkar (2004). Hg concentrations were below detection limits. In general, computation of “geoaccumulation index” revealed the sediments as ‘uncontaminated to moderately contaminated’ with Fe, Mn, Ni, Co, Pb and Zn during the salt-making season. The abundance of metal-tolerant bacteria was comparatively restricted to the salt-making season and was higher than the non salt-making season. Fe-, Mn-, Ni-, Co- and Pb- (200 ppm) tolerant bacteria were retrieved and restricted to the surface sediments (0–5 cm), Cd and Fe being the two most regulatory elements governing bacterial populations in the non salt-making season. However, during the salt-making season, the concentration of Zn was found to be pivotal in regulating the counts of Fe-, Mn- and Ni-tolerant bacteria. In general, the strength of correlation of metals and microbes was higher in the non salt-making season as compared to the salt-making season. This would probably indicate metal-induced limitations in microbial populations in the non salt-making season and the absence of this effect during the salt-making season. In this study, we test the hypothesis that solar salterns behave as ecological sinks with a potential to transform native bacterial populations to metal-resistant strains, in relation to the dynamic changes in the surrounding metal concentrations.     

Potential use of biomass and coal-fine waste for making briquette for sustainable energy and environment

Environmental Science and Pollution Research - Biomass waste contributes 14% of the total global energy. And 15–20% of the coal-fine waste from coal mines are deposited in the rivers, ponds,...     

Safety of 0.5% hydrogen peroxide mist used in the disinfection gateway for COVID-19

Environmental Science and Pollution Research - Hydrogen peroxide (H2O2) is a reactive chemical used in a wide range of applications. Most importantly, it is used for sterilization process in health...     

Mercury remediation potential of a mercury resistant strain Sphingopyxis sp. SE2 isolated from contaminated soil

A mercury resistant bacterial strain SE2 was isolated from contaminated soil.The 16 s rRNA gene sequencing confirms the strain as Sphingopyxis belongs to the Sphingomonadaceae family of the α-Proteobacteria group.The isolate showed high resistance to mercury with estimated concentrations of Hg that caused 50%reduction in growth(EC_(50)) of 5.97 and 6.22 mg/L and minimum inhibitory concentrations(MICs) of 32.19 and 34.95 mg/L in minimal and rich media,respectively.The qualitative detection of volatilized mercury and the presence of mercuric reductase enzyme proved that the strain SE2 can potentially remediate mercury.ICP-QQQ-MS analysis of the remaining mercury in experimental broths indicated that a maximum of 44%mercury was volatilized within 6 hr by live SE2 culture.Furthermore a small quantity(23%) of mercury was accumulated in live cell pellets.While no volatilization was caused by dead cells,sorption of mercury was confirmed.The mercuric reductase gene merA was amplified and sequenced.Homology was observed among the amino acid sequences of mercuric reductase enzyme of different organisms from a-Proteobacteria and ascomycota groups,     

Histochemical studies on reproductive and nutritional cycles of the holothurian,Holothuria scabra

Histochemical observations were made of seasonal changes of protein, carbohydrates, lipids and nucleic acids in different tissues of Holothuria scabra. Accumulation of organic components in the gonads were observed with the advance of maturity. Protein and lipids were found to be important as storage materials for utilization during development. A sexcorrelated variation of nucleic acids was evident in the gonads. Intestinal protein and lipids were found to be utilized by the gonads during the reproductive cycle; carbohydrates seemed to be of lesser importance.     

Mechanical performance of woodfibre–waste plastic composite materials

Plastic products used for packaging are often discarded after a single use resulting in an inexhaustible supply of waste polymeric materials. The stiffness and strength of polymeric materials have been known to improve with the addition of lignocellulosic fibres available in abundance in nature. Hence, composite materials containing natural fibres and waste plastics would result in the reduction of solid wastes and the use of cheap, renewable resources. Composite specimens, consisting of waste plastics obtained from a Kerbside collection (high density polyethylene (HDPE) waste, Janitorial waste, Kerbside waste I and Kerbside waste II) and Pinus radiata woodfibres (medium density fibres (MDF)), have been produced through melt blending and injection moulding. The effects of fibre content, matrix type and interfacial bonding on the tensile and flexural properties of these composite materials have been determined through extensive testing at various conditions. The mechanical properties of these composites at room temperature and humidity depend on the amount of woodfibres, the mechanical properties of the waste plastics used and the presence of a suitable coupling agent. The tensile strengths of MDF/waste plastic composites do not generally change with fibre content except for 40% MDF/HDPE waste and 40% MDF/Kerbside waste II (plus 1% Epolene™) composites, where the tensile strengths increase by about 25% compared to those of the corresponding waste plastics. Flexural strengths of MDF/waste plastic composites increase with the addition of medium density fibres with the exception of MDF/Kerbside waste I composites. The tensile and flexural moduli of MDF/waste plastic composites mostly increase with increasing fibre content.     

Growth and development of smooth bromegrass and tall fescue in TNT-contaminated soil

Plants can be used for effective and economical remediation of soil provided they are tolerant or resistant to contaminants. This study was conducted to determine effects of 2,4,6-trinitrotoluene (TNT) on growth and development of smooth bromegrass and tall fescue. Seeds of both species were grown in contaminated and non-contaminated soil mixed at ratios to obtain a range of concentrations and also in non-contaminated soil underlain by contaminated and non-contaminated soil mix. Germination, shoot and root dry weight, root length and area were measured. Germination and height of both species decreased with increasing TNT concentration. Shoot dry weight from tall fescue was 50% greater than smooth bromegrass at a given TNT concentration. Root length, area and dry weight of both species decreased with increasing TNT concentration. Root area and dry weight were greater for smooth bromegrass compared to tall fescue. This research indicates tall fescue and smooth bromegrass can germinate and grow in soils with concentrations less than 31 and 24 mg TNT l(-1), respectively.     

Annual and Seasonal Rainfall Trends in an Equatorial Tropical River Basin in Malaysian Borneo

Annual and seasonal rainfall trends in the Limbang River Basin (LRB), located in the equatorial tropics of Malaysian Borneo, have been characterised through Mann-Kendall and Spearman’s Rho non-parametric tests. Rainfall from 13 rain gauge stations in the LRB for the period 1948–2016 was examined in the present study. Basic statistical analysis of rainfall in the region indicates normal distribution, low missing percentage and homogenous characteristics of precipitation. Annual and seasonal rainfall in the LRB shows spatial variation while considering different rain gauge stations. In annual rainfall, eight stations showed a decreasing trend and five stations showed an increasing trend. Rain gauge stations which showed a statistically significant increase in annual rainfall were Limbang DID (2.77 and 2.85 mm/year) and Long Napir (3.65 and 3.77 mm/year). In recognising the two annual monsoon seasons in this area, a significant increase in rainfall was noticed in Long Napir (2.79 and 2.88 mm/year) during the Southwest monsoon (SWM) period. During the Northeast monsoon (NEM), along with Long Napir (3.90 and 3.95 mm/year), Limbang DID (2.86 and 3.02 mm/year), Pandaruan (1.82 and 1.87 mm/year) and Medamit Nanga (1.93 and 2.00 mm/year) also showed a significant increase in rainfall. At the same time, a distinct trend was noticed in rainfall amounts during the inter-monsoon (IM) periods. During the first inter-monsoon month (April), seven rain gauge stations showed an increasing trend in rainfall, whereas in the second inter-monsoon month (October), nine stations showed a decreasing rainfall trend. In April, Long Napir (1.86 and 1.95 mm/year) indicated a significant increasing trend, whereas in the month of October, the rain gauge station at Ukong showed a significant decreasing trend (− 2.45 and − 2.37 mm/year). Though minor spatial changes in trend characteristics were observed among the rain gauge stations, the LRB as a whole showed a consistent increasing (significant and non-significant) trend in annual and seasonal rainfall.