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31.
Trace amounts of heavy metals have been analysed by electrochemical techniques in ecstasy tablets obtained from different police seizures in Spain. Lead, cadmium, copper and zinc were determined by differential-pulse anodic stripping voltammetry at a hanging mercury drop electrode, whereas nickel and cobalt were determined by adsorptive differential-pulse cathodic stripping voltammetry from their dimethylglyoxime complexes, M(DMG)2. The performance of the procedure was compared with electrothermal atomic absorption spectrometry. The procedure was applied to the determination of these elements in nine ecstasy samples, finding that Zn is the element present in the highest concentration, ranging from 0.3 to 200?mg?kg?1, Ni, Cu appear below 15?mg?kg?1 and Pb below 8?mg?kg?1, while Cd and Co levels were always lower than 0.51?mg?kg?1. 相似文献
32.
M. Dolores Basallote Araceli Rodríguez-Romero Manoela R. De Orte T. Ángel DelValls Inmaculada Riba 《Chemistry and Ecology》2018,34(1):1-21
Carbon capture and storage has become a new mitigation option to reduce anthropogenic CO2 emissions. The effects of the CO2-related acidification, associated with unpredictable leaks of CO2 during the operational phases were studied using the Paracentrotus lividus sea urchin-liquid-phase-assays (fertilisation and embryo-larval development tests). Besides to the direct effects of the CO2-associated pH decrease, the possible effects on marine sediment toxicity were studied by exposing the urchin larvae to elutriate of sediments with different metals concentration, which were subjected to various pH treatments. The resulted median toxic effect pH ranged from 6.33?±?0.02 and 6.91?±?0.01 for the egg fertilisation, and between 6.66?±?0.03 and 7.16?±?0.01 for the larval development assays. Concentrations of Co, Zn, As, Cu, and Fe were detected in the sediment elutriates. For all the sediment elutriates tested the amount of the dissolved Zn increased in parallel with the pH reductions. Correlated effects of acidification, biological response, and the presence of dissolved metals were observed in this work evidencing that the most important factor controlling the reduction of egg fertilisation and larval development success was the combined effects of the reduction of pH and the presence of the contaminants (mainly Zn, Co, and As). 相似文献
33.
Cheviron Nathalie Grondin Virginie Marrauld Christelle Poiroux Françoise Bertrand Isabelle Abadie Josiane Pandard Pascal Riah-Anglet Wassila Dubois Caroline Malý Stanislav Marques Catarina R. Asenjo Inmaculada Valverde Alonso Alejandro Díaz Domingo Marquina Mougin Christian 《Environmental science and pollution research international》2022,29(20):29348-29357
Environmental Science and Pollution Research - The evaluation of soil quality requires the use of robust methods to assess biologically based indicators. Among them, enzyme activities are used for... 相似文献
34.
An integrated assessment of sediment quality in the Guadiamar River after a mining spill was conducted. The concentration of different metals and other conventional parameters were measured in sediments located along the river. Four sediment toxicity tests (Hyalella azteca 28-day survival and growth test; Chironomus riparius 10-day survival and growth test; Hexagenia spp. 21-day survival and growth test; and Tubifex tubifex 28-day reproduction and survival test) were carried out to determine the effects associated with the accidental spill. The geochemical fractions of 6 metals (Fe, Mn, Zn, Cu, Pb, and Cd) were determined to establish the bioavailability of the metals. The relationship found in the concentrations of metals associated with the mobile fractions of the sediments in the sites studied is similar to the toxic mud from tailing pond and confirms that the toxic effects are associated with the metals Zn and Cd originating from the spill. 相似文献