Sampling Considerations for Establishment of Baseline Loadings from Forested Watersheds for TMDL Application

Five methods for estimating maximum daily and annual nitrate (NO3) and suspended sediment loads using periodic sampling of varying intensities were compared to actual loads calculated from intensive stormflow and baseflow sampling from small, forested watersheds in north central West Virginia to determine if the less intensive sampling methods were accurate and could be utilized in TMDL development. There were no significant differences between the annual NO3 load estimates using non-intensive sampling methods and the actual NO3 loads. However, maximum daily NO3 loads were estimated less accurately than annual loads. The ability to estimate baseline NO3 loads fairly accurately with non-intensive concentration data is attributed to the small fluctuation in NO3 concentrations over flow and time, particularly during storms. By contrast, suspended sediment exports determined by any of the non-intensive methods varied significantly and widely from and compared poorly to the actual exports for both daily and annual methods. Weekly sampling better approximated actual annual exports, but there were no significant statistical differences among weekly, monthly, and quarterly estimates. Suspended sediment concentrations varied widely within and among storm events, so that accurate estimates of total annual or maximum daily loads could not be obtained from infrequent sampling.     

Consistency of ozone and nitrogen oxides standards at tropospherically relevant mixing ratios

The absolute accuracy and long-term precision of atmospheric measurements hinge on the quality of the instrumentation and calibration standards. To assess the consistency of the ozone (O3) and nitrogen oxides (NO(x)) standards maintained at the National Institute of Standards and Technology (NIST), these standards were compared through the gas-phase titration of O3 with nitric oxide (NO). NO and O3 were monitored using chemiluminescence and UV absorption, respectively. Nitrogen dioxide (NO2) was monitored directly by laser-induced fluorescence and indirectly by catalytic conversion to NO, followed by chemiluminescence. The observed equivalent loss of both NO and O3 and the formation of NO2 in these experiments was within 1% on average over the range of 40-200 nmol mol(-1) of NO in excess O3, indicating that these instruments, when calibrated with the NIST O3 and NO standards and the NO2 permeation calibration system, are consistent to within 1% at tropospherically relevant mixing ratios of O3. Experiments conducted at higher initial NO mixing ratios or in excess NO are not in as good agreement. The largest discrepancies are associated with the chemiluminescence measurements. These results indicate the presence of systematic biases under these specific conditions. Prospects for improving these experiments are discussed.     

Carbon and nitrogen isotopic composition of the fauna from the Broken Spur hydrothermal vent field

 The carbon and nitrogen isotopic composition of 18 faunistic groups collected during the 39th cruise of the R.V. “Akademik Mstislav Keldysh” in September 1996 at the Broken Spur vent field, MAR, was studied. The trophic structure of the Broken Spur vent community is considered. All age stages of the shrimp Rimicaris exoculata living 5 m below the main aggregations at black smokers show higher δ¹⁵N and more depleted δ¹³C values than the same stages inhabiting the black smokers themselves. The shrimps R. exoculata and Chorocaris chacei demonstrate ontogenetic changes in δ¹³C (the former also in δ¹⁵N), with smaller individuals showing higher δ¹⁵N and more depleted δ¹³C values than larger shrimps. Benthopelagic and benthic components of the vent community differ significantly in δ¹³C and δ¹⁵N, the benthic fauna being less dependent upon chemosynthetic production. Received: 30 March 1999 / Accepted: 28 September 1999     

An experimental examination of implicit stress theory

Implicit theories lead individuals to make assumptions about one trait based on their knowledge of another trait. This study experimentally examined Implicit Stress Theory under conditions of high and low performance information. The objective was to test for evidence of Implicit Stress Theory in ratings of effectiveness, commitment, and burnout. Results indicated moderate support for Implicit Stress Theory such that raters evaluated employee burnout and commitment as higher when the employee was perceived to be working under stressful conditions. Interestingly, the data suggested stronger support (based on the proportion of variance explained) for an Implicit Performance Theory such that information regarding good performance was associated with higher levels of commitment and less burnout than poor performance.     

An examination of beliefs about older workers: Do stereotypes still exist?

This study examined individuals' beliefs about older workers. Of particular interest was the relationship between those beliefs and individuals' (a) interactions with older workers, (b) supervisory status, and (c) demographic variables. Findings indicated that although older workers hold more positive beliefs about older workers than younger workers hold, even younger workers tended to have generally positive beliefs. Chronological age was found to moderate two relationships. First, the number of younger workers' interactions with older workers significantly, positively affected younger workers' beliefs about older workers. Second, an examination of the interaction between supervisory status and age found that older supervisors hold more negative beliefs about older workers than younger supervisors.     

Photocatalytic oxidation of NOx gases using TiO2: a surface spectroscopic approach

The bandgap of solid-state TiO2 (3.2 eV) enables it to be a useful photocatalyst in the ultraviolet (lambda < 380 nm) region of the spectrum. A clean TiO2 surface in the presence of sunlight therefore enables the removal of harmful NOx gases from the atmosphere by oxidation to nitrates. These properties, in addition to the whiteness, relative cheapness and non-toxicity, make TiO2 ideal for the many de-NOX catalysts that are currently being commercially exploited both in the UK and Japan for concrete paving materials in inner cities. There is need, however, for further academic understanding of the surface reactions involved. Hence, we have used surface specific techniques, including X-ray photoelectron spectroscopy and Raman spectroscopy, to investigate the NOx adsorbate reaction at the TiO2 substrate surface.     

A framework for profiling a lake's riparian area development potential

Some of the greatest challenges for managing residential development occur at the interface between the terrestrial and aquatic ecosystems--in a lake's riparian area. Land use planners need a framework they can use to identify development hotspots, areas were the next push for development will most likely occur. Lake riparian development profiles provide a framework for linking ecological and social factors important to development. In a test of this framework in northern Minnesota, researchers identified seven constructs influencing riparian area development: current general development, current housing development, and availability, accessibility, suitability, aesthetics, and proximity to services. Profiles display a lake's value for each construct relative to the range of values for all lakes in the county. Maps, developed using indicators for several constructs, allow us to identify how the factors interact and are dispersed across the landscape. These profiles help policy makers, planners, and managers identify lakes that are potential development hotspots so they can take timely steps to manage development or control the impacts of development.