全文获取类型
收费全文 | 1312篇 |
免费 | 95篇 |
国内免费 | 413篇 |
专业分类
安全科学 | 92篇 |
废物处理 | 92篇 |
环保管理 | 93篇 |
综合类 | 754篇 |
基础理论 | 207篇 |
环境理论 | 1篇 |
污染及防治 | 433篇 |
评价与监测 | 55篇 |
社会与环境 | 54篇 |
灾害及防治 | 39篇 |
出版年
2024年 | 1篇 |
2023年 | 27篇 |
2022年 | 96篇 |
2021年 | 81篇 |
2020年 | 65篇 |
2019年 | 42篇 |
2018年 | 46篇 |
2017年 | 77篇 |
2016年 | 63篇 |
2015年 | 75篇 |
2014年 | 122篇 |
2013年 | 154篇 |
2012年 | 122篇 |
2011年 | 118篇 |
2010年 | 102篇 |
2009年 | 73篇 |
2008年 | 88篇 |
2007年 | 63篇 |
2006年 | 58篇 |
2005年 | 34篇 |
2004年 | 31篇 |
2003年 | 32篇 |
2002年 | 32篇 |
2001年 | 30篇 |
2000年 | 33篇 |
1999年 | 29篇 |
1998年 | 21篇 |
1997年 | 22篇 |
1996年 | 17篇 |
1995年 | 16篇 |
1994年 | 13篇 |
1993年 | 17篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1973年 | 1篇 |
排序方式: 共有1820条查询结果,搜索用时 978 毫秒
781.
水相中CCl4和CHCl3的紫外光解机理 总被引:1,自引:0,他引:1
利用瞬态吸收光谱技术研究水体污染物CCl4 和CHCl3 在紫外光照条件下的转化和归宿 ,表明在 2 4 8nm激光作用下 ,CCl4 解离为CCl3 和Cl自由基 ;CHCl3 在此条件下不解离 ,但加入少量的苯后即发生明显解离 ,产生CHCl2 和Cl自由基 .在有氧条件下 ,光解产生的CCl3 和CHCl2 自由基均与O2 反应分别生成CCl3O2 和CHCl2 O2 ;在无氧条件下 ,CCl3 和CHCl2 则发生偶合反应分别生成C2 Cl6和C2 H2 Cl4 .本研究还得出了一些微观速率常数 . 相似文献
782.
783.
采用“混凝沉淀-微滤-组合反渗透”工艺对某煤化工企业的高盐废水进行浓缩处理,浓水通过蒸发结晶进行脱水,产水采用常规反渗透进行水回收。运行结果表明,经30 d运行,水回收率保持在85%以上,脱盐率稳定在95%以上,常规反渗透产水水质稳定,产水电导率、浊度、Cl-质量浓度和COD的平均值分别为12.5 μs/cm,0.1 NTU,7.8 mg/L,1.8 mg/L,满足《炼化企业节水减排考核指标与回用水质控制指标》(Q/SH0104-2007)中污水回用于循环冷却水的水质指标和设计产水水质要求,实现了废水的近“零排放”。 相似文献
784.
785.
786.
Pengfei Qin Xingren Pan Rutao Liu Changwei Hu Yuliang Dong 《Journal of environmental science and health. Part. B》2017,52(11):833-841
To evaluate the toxicity of two fluoroquinolones (FQs), ciprofloxacin (CPFX), and enrofloxacin (ENFX), at the protein level, their binding modes with bovine serum albumin (BSA) were characterized by multiple spectroscopic and molecular docking methods under simulated physiological conditions. On the basis of fluorescence spectra, we concluded that both FQs greatly quenched the fluorescence intensity of BSA, which was attributed to the formation of a moderately strong complex mainly through electrostatic interactions. Besides, CPFX posed more of an affinity threat than ENFX. The molecular docking methods further illustrated that both CPFX and ENFX could bind into the subdomain IIIA of BSA and interact with Arg 508 and Lys 437, the positively charged residues in protein. Furthermore, as shown by the synchronous fluorescence, UV-Visible absorption and circular dichroism data, both CPFX and ENFX could lead to the conformational and microenvironmental changes of BSA, which may affect its physiological function. 相似文献
787.
Yunyu Pan Gerwin F. Koopmans Luc T. C. Bonten Jing Song Yongming Luo Erwin J. M. Temminghoff Rob N. J. Comans 《Environmental geochemistry and health》2016,38(6):1355-1372
Alternating flooding and drainage conditions have a strong influence on redox chemistry and the solubility of trace metals in paddy soils. However, current knowledge of how the effects of water management on trace metal solubility are linked to trace metal uptake by rice plants over time is still limited. Here, a field-contaminated paddy soil was subjected to two flooding and drainage cycles in a pot experiment with two rice plant cultivars, exhibiting either high or low Cd accumulation characteristics. Flooding led to a strong vertical gradient in the redox potential (Eh). The pH and Mn, Fe, and dissolved organic carbon concentrations increased with decreasing Eh and vice versa. During flooding, trace metal solubility decreased markedly, probably due to sulfide mineral precipitation. Despite its low solubility, the Cd content in rice grains exceeded the food quality standards for both cultivars. Trace metal contents in different rice plant tissues (roots, stem, and leaves) increased at a constant rate during the first flooding and drainage cycle but decreased after reaching a maximum during the second cycle. As such, the high temporal variability in trace metal solubility was not reflected in trace metal uptake by rice plants over time. This might be due to the presence of aerobic conditions and a consequent higher trace metal solubility near the root surface, even during flooding. Trace metal solubility in the rhizosphere should be considered when linking water management to trace metal uptake by rice over time. 相似文献
788.
Pan Guo Ting Wang Yanli Liu Yan Xia Guiping Wang Zhenguo Shen Yahua Chen 《Environmental science and pollution research international》2014,21(1):631-640
A field investigation, field experiment, and hydroponic experiment were conducted to evaluate feasibility of using Oenothera glazioviana for phytostabilization of copper-contaminated soil. In semiarid mine tailings in Tongling, Anhui, China, O. glazioviana, a copper excluder, was a dominant species in the community, with a low bioaccumulation factor, the lowest copper translocation factor, and the lowest copper content in seed (8 mg kg?1). When O. glazioviana was planted in copper-polluted farmland soil in Nanjing, Jiangsu, China, its growth and development improved and the level of γ-linolenic acid in seeds reached 17.1 %, compared with 8.73 % in mine tailings. A hydroponic study showed that O. glazioviana had high tolerance to copper, low upward transportation capacity of copper, and a high γ-linolenic acid content. Therefore, it has great potential for the phytostabilization of copper-contaminated soils and a high commercial value without risk to human health. 相似文献
789.
Xuan Huang Jing Zheng Min Chen Yangyu Zhao Chunlei Zhang Lifu Liu Weiwei Xie Shuqiong Shi Yuan Wei Dongzhu Lei Chenming Xu Qichang Wu Xiaoling Guo Xiaomei Shi Yi Zhou Qiufang Liu Ya Gao Fuman Jiang Hongyun Zhang Fengxia Su Huijuan Ge Xuchao Li Xiaoyu Pan Shengpei Chen Fang Chen Qun Fang Hui Jiang Tze Kin Lau Wei Wang 《黑龙江环境通报》2014,34(4):335-340
790.