池火灾热辐射下的最小安全距离

防火间距是石油化工企业平面设计中的一个重要参数 ,笔者旨在从流体力学角度研究池火灾发生情况下邻罐之间最小安全距离 ,从而给防火间距的制定提供依据。辐射是储罐区池火灾的主要传热方式 ,作者对池火灾形状以及介质辐射吸收性质进行了适当的简化 ,用CFD软件Fluent对丙烷液化烃储罐池火灾热辐射进行了数值模拟。模拟结果表明对于锰钢材料、内径为 1 2 4 1 0mm液化烃压力储罐 ,稳态池火灾情况下 ,相邻两储罐之间的最小安全距离为 1 5m。     

Increase in biodegradation of dimethyl phthalate by Closterium lunula using inorganic carbon

The effect and mechanism of inorganic carbon (IC) on the biodegradation of dimethyl phthalate (DMP) by a green microalga Closterium lunula was investigated. The growth of this microalga and the biodegradation of DMP were significantly enhanced when the initial IC was increased. An intermediate product of DMP biodegradation was identified as phthalic acid (PA) that was accumulated and caused a sharp decrease in pH of microalgal culture medium, which inhibited both the growth of microalga and the biodegradation of DMP. A suggested second-order kinetic equation of organic pollutant biodegradation by microalgae (-dC/dt = kNr) fitted well with the experimental data. The increase of IC caused a decline in biodegradation rate constant for organic carbon (k) and an increase in growth (N) by supplying a favorite carbon source and mitigating the decrease of pH. As the net effect, the overall biodegradation rate of DMP was promoted as IC increased, which was dominated by the increase of microalgal growth.     

"开放型"区域资源策略探析--以浙江省为例

本文从区域资源安全的内涵出发,以浙江省为研究对象,在分析了省域资源条件及供给现状的基础上,提出了构建“开放型”区域资源安全体系的总体思路。     

Microbial degradation of phthalic acid esters under anaerobic digestion of sludge

The microbial degradation by anaerobic sludge of three phthalates, priority pollutants, listed by both China National Environmental Monitoring Center and the U.S.EPA, namely, dimethyl (DMP), di-n-butyl (DBP) and di-n-octyl (DOP) phthalates was investigated. The experimental results indicated that the biodegradation rate and the biodegradability of three phthalates under anaerobic conditions appeared to be related to the length of the alkyl-side chains. More than 90% of DMP and DBP with the short alkyl-side chain phthalates can be degraded, whereas the DOP degradation appeared to be relatively slow under the same experimental conditions. The quantity of methane produced was measured and the results showed that both the ester groups and the phthalate ring were mineralized at a significant rate. The kinetics study demonstrated that the biodegradation of three phthalates conformed to the first-order model with respect to their concentrations.     

Carbon disulfide at a Chinese viscose factory external and internal exposure assessment

This article presents the results of carbon disulfide exposure measurements in a Chinese viscose rayon factory. The objectives of the study were to identify the external exposure levels at a large factory and to investigate the 2-thiothiazolidine-4-carboxylic acid (TTCA) concentrations in the urine of the subjects who were exposed to carbon disulfide in the working place atmosphere. The metabolism of carbon disulfide in the exposed subjects was also studied in order to demonstrate the best points in time for the internal exposure sampling. The measurement of the amount of personal exposure to carbon disulfide in the air of the workplace was performed by GC-FPD; the presence of TTCA in the workers urine was analyzed by use of a modified HPLC method. The kinetics of TTCA excretion was studied by analyses at different time-points both during and after exposure to carbon disulfide in the subjects. A total of 155 personal samples were obtained. The carbon disulfide concentration in the staple viscose hall was 13.72 +/- 1.12 mg m-3 in terms of the geometric mean +/- geometric standard deviation, and was 20.05 +/- 1.33 mg m-3 in the filament spinning hall. The TTCA values in the subjects who worked in the staple spinning hall were 1.18 +/- 0.43 mg g-1 creatinine and 1.07 +/- 0.38 mg g-1 creatinine for subjects working in the filament spinning hall. The best time for TTCA sampling is at the end of the working shift, the TTCA excretion was stable for a period of 4-12 h after exposure of the subjects to the carbon disulfide. It might be that the Chinese have different anthropometric characteristics; a sampling bias may therefore appear among different races.     

如何浅开谈展石环油境石应化企急工业作

根据石化企业环境应急工作面临的任务和国内外发展趋势,对企业的环境应急现状和存在问题进行了分析和评价,论述了开展环境应急工作的必要性和紧迫性,探讨了石化企业开展环境应急工作的指导思想和方法。     

全密闭电石炉尾气治理及综合利用

由于全密闭电石炉的尾气性质特殊，治理和综合利用存在一定的难度。本文总结了国内电石生产厂家的多种治理和利用方法，并根据国家产业政策的要求，提出了适合我国国情的电石炉烟气治理及综合利用方法。     

500 kV紧凑型输电线路走廊与电磁环境

通过介绍500 kV郓城～泰山紧凑型送电线路的设计,围绕输电线路走廊问题,对紧凑型线路和常规线路进行了比较,重点分析了紧凑型输电线路在提高输电能力的同时所具备的节约走廊占地和减轻电磁环境影响的技术特点.从环境保护角度来看,500 kV紧凑型输电线路是一项值得推广的技术.     

城市灾害对城市土地利用的影响

随着城市的不断扩张，对城市土地利用的需求量也在不断增加。地震、火灾、风灾、地质破坏是现代城市的主要灾害，城市灾害在一定程度上制约着土地利用的类型。充分运用GIS的空间分析功能，研究了城市灾害对城市土地利用的影响，所得结果可为城市土地利用规划提供辅助决策参考。