A DYNAMIC SYSTEM MODEL FOR SIMULATING SEDIMENT DISCHARGE1

ABSTRACT: A dynamic sediment discharge model was developed and proposed for the simulation of watershed systems. It war developed from an expansion of splash and flow erosion relationships under steady state conditions. It was described as a general erosion model that can be reduced to forms comparable to many conceptual soil erosion and sediment yield models. The model incorporates eight parameters such as rainfall intensities, runoff rates, and previous sediment discharges. The model was tested with two small watersheds with simulation results which were very satisfactory compared to the data.     

CONSIDERATIONS IN CHOOSING THE APPROPRIATE MIX OF URBAN AND AGRICULTURAL NONPOINT POLLUTION CONTROL1

ABSTRACT: In developing strategies for nonpoint pollution control in designated 208 areas, one of the issues facing planners is the relative emphasis which should be placed upon urban versus agricultural non-point control. Five criteria which should be considered in designing an appropriate BMP strategy mix are discussed: 1) BMP cost effectiveness; 2) information and administrative cost; 3) flexibility, which relates to the cost of reversibility given substantial uncertainties; 4) associated effects, both direct and indirect; and 5) acceptability to local jurisdictions and groups. Whatever an evaluation on the basis of the first four criteria may suggest, acceptance of agricultural BMPs will be difficult to achieve, thus favoring urban oriented strategies, unless local revenue sources are developed to offer payments to farmers for BMP adoption.     

Background monitoring and long-range transport of atmospheric CFC-11 and CFC-12 at Kosan, Korea

The background concentrations of atmospheric CFC-11 and CFC-12were monitored to assess their impact on stratospheric ozone depletion and global warming from September 1995 to March 1999 at Kosan, Korea, located at eastern margin of the Asian Continent. The concentrations of atmospheric CFC-11 at Kosan have decreased slightly, at a rate of –2.5 pptv yr^-1, over the period in response to the Montreal Protocol. The CFC-12 mixing ratio at Kosan continues to increase in the atmosphere at a rate of 5.7 pptv yr^-1 despite international regulations, because of its extreme atmosphere persistence. Recent trends ofthese two chlorofluorocarbons at Kosan, Korea were concordant with those of the northern hemispheric background monitored unitat Mauna Loa, Hawaii. The maximum seasonal mean mixing ratios of CFC-11 and CFC-12 at Kosan, Korea, were 270±4 pptv inthe spring and 538±9 pptv in the winter, and the corresponding seasonal minima were 267±7 and 529±12 pptv. This occurred in the summer and was due to southeasterlywinds from the northwestern Pacific Ocean. By performing a three-day isentropic backward trajectory analysis, it was shownthat air masses at Kosan, and with the exception of summer, mainly originated from central and northern China. In particular, the mixing ratios of these two contaminant speciesare closely related with their air mass trajectories.     

Study on Size Distribution of Total Aerosol and Water-Soluble Ions During an Asian Dust Storm Event at Jeju Island, Korea

Soil dust particles transported from loess regions of the Asian continent, called Asian dust, highly influences the air quality of north-eastern Asia and the northern Pacific Ocean. In order to investigate the effects of these dust storms on the chemical composition of atmospheric aerosol particles with different size, measurements of size distributions of total aerosol and major ion species were carried out on Jeju Island, Korea during April 2001. Juju Island was chosen for the study because the levels of emissions of anthropogenic air pollutants are very low. A 5-stage cascade impactor was used to sample size-fractionated aerosol particles. Samples were analyzed for major water-soluble ions using Dionex DX-120 ion chromatograph. The average mass concentration of total aerosol was found to be 24.4 and 108.3 microg m(-3) for non-Asian dust and Asian dust periods, respectively. The total aerosol size distribution, measured during the non-Asian dust period, was bimodal, whereas the coarse particles dominated the size distribution of total aerosol during the Asian dust period. It was found that SO4(2-), NH4+ and K+ were mainly distributed in fine particles, while Cl-, NO3-, Na+, Mg2+ and Ca2+ were in coarse particles. Although SO4(2-) was mainly distributed in fine particles, during the Asian dust period, the concentrations in coarse particles were significantly increased. This indicates heterogeneous oxidation of SO2 on wet surfaces of basic soil dust particles. The NH4+ was found to exist as (NH4)2SO4 in fine particles, with a molar ratio of NH4+ to SO4(2-) of 2.37 and 1.52 for non-Asian dust and Asian dust periods, respectively. Taking into account the proximity of the sampling site to the sea, and the observed chloride depletion, coarse mode nitrate, during the non-Asian dust period, is assumed to originate from the reaction of nitric acid with sodium chloride on the surfaces of sea-salt particles although the chloride depletion was not shown to be large enough to prove this assumption. During the Asian dust period, however, chloride depletion was much smaller, indicating coarse nitrate particles were mainly produced by the reaction of nitric acid with surfaces of basic soil particles. Most chloride and sodium components were shown to originate from sea-salt particles. Asian dust aerosols, arriving at Jeju Island, contained considerable amounts of sea-salt particles as they passed over the Yellow Sea. Ca2+ was shown to be the most abundant species in Asian dust particles.     

Observations of Dust-Storms in China, Mongolia and Associated Dust Falls in Korea in Spring 2003

A joint monitoring of dust-storms that occurred in East Asia from March until May 2003 has been carried. Our discussions include dust-storm observations in the source areas of China and Mongolia, and measurements with satellites and ground monitors in central Korea. Differences were found in the definition and measurement of dust-storms. Over the source area of Mongolia there were 6 dusty days in March, 18 days in April, and 10 dusty days in May. In Inner Mongolia of northern China there were 4 dust-storms with 14 dusty days observed over the three months. In central Korea, a sink area, there were 4 cases of weak dust-storm and 17 dusty days in the spring of 2003. The highest PM10 value was 607 μgm⁻³ and PM 2.3 was 149 μgm⁻³, respectively. These observations identify the growing need for further universal observation practices and dust-storm reporting in future. Observations indicated that snow covered the central part of the Gobi Desert, near the boundary of China and Mongolia, from December until mid-March. This is in contrast to other years when the Gobi was relatively wet, producing unfavourable conditions for the formation of intense dust-storms. In addition, the very strong winds associated with intense cyclones and anticyclones were not apparent and the systems shifted northward during the spring. As a result, the frequency and intensity of observed dust-storms in 2003 in this region were very low. This confirms that there is variability in the frequency of dust-storm formation due to the current process of desertification and climate change.     

Short-term influence of phosphate and nitrate on heavy metal accumulation by red alga Acrosorium uncinatum

Heavy metal accumulation (Cu, Zn, Ni, and Pb) in common marine macroalga, Acrosorium uncinatum under nutrient (phosphate and nitrate) enriched (experiment 1) and starved (experiment 2) conditions over a short exposure period (12 h) were examined in this study. Control was maintained in seawater contained nutrient solution without addition of metals and in seawater alone for experiment 1 and 2, respectively. Among the four metals studied, the accumulation of Zn, Ni, and Pb was considerably lower than Cu. The accumulation factor for all metals varies greatly in different nutrient concentrations, but it increases as the exposure of metal concentration decreases in both the experiments. The results of the present findings established that this macroalga is an accumulator of metals Cu, Zn, Ni, and Pb and have the potential to accumulate these metals even in a short time exposure period (12 h). Even though metal accumulation by A. uncinatum largely depends on the available concentration in the medium, nutrients like phosphate and nitrate can affect the accumulation significantly.     

Desiccation of contaminant barrier materials amended with aqueous carboxymethyl cellulose solution

The stabilization potential of negatively charged sodium carboxymethyl cellulose (CMC) solution was assessed through investigation of its retention on clays under environmental conditions that promote soil desiccation. Sodium montmorillonite and kaolinite, commonly used in clayey soils, were mixed with aqueous CMC solutions in concentrations ranging from 0 to 10 g/L. These samples were dried in a specially-designed desiccation chamber which was operated at a temperature of 25°C and relative humidity of 30%. The results show an inverse proportionality between liquid loss and CMC concentration. Liquid loss from clayey soil follows the first-order reaction with a rate constant in the range of 4.6–6.7 mg/h. CMC half-lives on sodium montmorillonite during desiccation ranged from 103 to 181 h for an aqueous concentration range of 0.5–10 g/L compared to 108 h for distilled water. For kaolinite, more liquid was retained at 10 g/L CMC concentration than at other concentrations, but liquid retention was generally insignificant. These conclusions are valid for a desiccation duration of 890 h, a time that is reasonably simulative of the duration of exposures of bare ground surfaces to weather elements. The experimental results are explained in terms of the role of CMC molecular interactions with clay minerals in controlling fluid flow to desiccating clay surfaces.     

Creating integrated business and environmental value within the context of China’s circular economy and ecological modernization

This paper investigates the challenges and opportunities of how firms and organizations can and will be able to strike a better balance between economic growth and environmental stewardship in the context of China’s emerging ‘circular economy’ policy paradigm and based on ecological modernization theoretic approaches.Based on three company case studies in the information technology and electronic industries in China, we identify and demonstrate how a blended business and environmental value can be created from adopting a sustainable supply chain management approach. The adoption of a sustainable supply chain management approach is rapidly becoming a key business challenge and opportunity in China and other large emerging economies around the world, where our greatest environmental management challenges currently reside and will continue to exist for many years to come. The value creation framework proposed in research focuses on evaluating three case study companies who appear in various stages of an electronic industry supply chain. Value creation within a supply chain can provide the impetus for organizations to adopt circular economy, sustainable supply chain practices, for competitive reasons.In addition, we describe how a value proposition can be evaluated at two levels of analysis, a more specific micro-level and a more general meso-level of analysis. The four major business value dimensions include cost reduction, revenue generation, resiliency, and legitimacy and image.The initial findings are that a variety of opportunities exist for electronic firms in emerging and developing countries, while results from this study provide an important scholarly foundation to develop and refine sustainable supply chain management practices in emerging and developing economies.