Laboratory appraisal of organic carbon changes in mixtures made with different inorganic wastes

Mixtures of organic and inorganic wastes were incubated to examine the changes in organic C (OC) contents. An anaerobic sludge and a CaO-treated aerobic sludge, with OC concentrations of 235 and 129 g kg^?1, were used. The inorganic wastes used – referred to as “conditioners” – were shot blasting scrap, fettling, Linz-Donawitz slag, foundry sand (FS), and fly ash from wood bark combustion (FA). The total OC (TOC) and ${\text{KMnO}}_4^{?}$ oxidized OC were determined. DTA-TGA profiles and FTIR spectra were also obtained. Mixtures made with the FS contained significantly lower (P < 0.05) amounts of TOC (45 g kg^?1) than the rest of mixtures, which was attributed to the non-existence of reactive surfaces in the conditioner and the increased aeration induced by this material. Those made with FA contained significantly higher (P < 0.05) amounts of TOC (170 g kg^?1), which was attributed to: (i) the addition of an extra source of C – black carbon (BC) – in the FA, and (ii) the inhibition of mineralization from the compounds present in this conditioner (e.g., amorphous aluminosilicates, BC). The results highlight the importance of the characteristics of the conditioners on the fate of the OM originating from the sludges.     

Nitrate and phosphate leaching in a Phaeozem soil treated with biosolids,composted biosolids and inorganic fertilizers

The use of organic wastes in agriculture may increase the production of crops by incorporating organic matter and nutrients into the soil, and by improving its physical characteristics; however, this use may cause environmental problems such as the leaching of certain ions. The objective of this study was to establish possible nitrogen and phosphorus leaching under real field conditions in Phaeozem soils. The experimental work was performed in a corn (Zea mays L.) field where three plots were conditioned with inorganic fertilizer, three plots with 4.5 Mg ha^?1 of biosolids on dry basis, and three plots with the same amount of composted biosolids. The quality of biosolids and composted biosolids complied with the Mexican Official Standards. Soil water samples were collected with suction cups during two agricultural cycles and were analysed. Soil samples were also taken and analysed.The N–NO₃ concentrations in soil water fluctuated between 0.9 and 98 mg L^?1 in the composted biosolid treatment, between 0.7 and 64 mg L^?1 in the biosolid treatment, and between 1 and 61 mg L^?1 in the inorganic fertilizer treatment. The maximum concentration of N–NO₂ and N–NH₃ in soil water was 1.02 and 2.65 mg L^?1, respectively. The greatest percentage of nitrogen leached is produced when inorganic fertilizer is used (37.4% and 24.0% N leached in the first and second years, respectively), followed by composted biosolids (17.1% and 13.5% N leached in the first and second years, respectively) and last by biosolids (11% for both years). This difference could be related to the form in which nitrogen is present in the fertilizers, while commercial fertilizer is as inorganic nitrogen, organic wastes are basically presented as organic nitrogen. The maximum ${\text{PO}}_4^{3-}$ concentration in soil water was 1.9 mg L^?1 in the composted biosolid treatment, 1.7 mg L^?1 in the biosolid treatment and 0.9 mg L^?1 in the inorganic fertilizer treatment. The estimated percentage of leached phosphorus was less than 1% for all treatments. The minimum leaching that occurred seemed to be due to a sorption–precipitation process.     

Evaluation of antibiotic mobility in soil associated with swine-slurry soil amendment under cropping conditions

Interest in identifying pools of antibacterial-resistance genes has grown over the last decade, with veterinary antibiotics (VAs) receiving particular attention. In this paper, a mesoscale study aimed at evaluating the vertical transport of common VAs—namely, fluoroquinolones, tetracyclines, sulfonamides, and lincosamides in agricultural soil subjected to drip irrigation—was performed under greenhouse conditions. Accordingly, leachates of cropped and uncropped soil, amended with swine-slurry leading to 19–38 μg kg^?1 (dry mass) antibiotics in the soil, were analyzed over the course of the productive cycle of a lettuce (42 days) with three sampling campaigns (N?=?24). High lincomycin (LCM) concentrations (30–39 μg L^?1) were detected in the leachates collected from the swine-slurry-amended soil. The highest LCM mass recovered in the leachates (30.1?±?1.63 %) was obtained from cropped experimental units. In addition, the LCM leaching constant and its leaching potential as obtained from the first-order model were higher in the leachates from the cropped experimental units. Lower concentrations of sulfadimethoxine were also detected in leachates and in soil. Enrofloxacin and oxytetracycline occurred only in soil, which is consistent with high soil interaction.     

Post-acquisition data processing for the screening of transformation products of different organic contaminants. Two-year monitoring of river water using LC-ESI-QTOF-MS and GCxGC-EI-TOF-MS

This study describes a comprehensive strategy for detecting and elucidating the chemical structures of expected and unexpected transformation products (TPs) from chemicals found in river water and effluent wastewater samples, using liquid chromatography coupled to electrospray ionization quadrupole-time-of-flight mass spectrometer (LC-ESI-QTOF-MS), with post-acquisition data processing and an automated search using an in-house database. The efficacy of the mass defect filtering (MDF) approach to screen metabolites from common biotransformation pathways was tested, and it was shown to be sufficiently sensitive and applicable for detecting metabolites in environmental samples. Four omeprazole metabolites and two venlafaxine metabolites were identified in river water samples. This paper reports the analytical results obtained during 2 years of monitoring, carried out at eight sampling points along the Henares River (Spain). Multiresidue monitoring, for targeted analysis, includes a group of 122 chemicals, amongst which are pharmaceuticals, personal care products, pesticides and PAHs. For this purpose, two analytical methods were used based on direct injection with a LC-ESI-QTOF-MS system and stir bar sorptive extraction (SBSE) with bi-dimensional gas chromatography coupled with a time-of-flight spectrometer (GCxGC-EI-TOF-MS).     

Treatment of a wastewater from a pesticide manufacture by combined coagulation and Fenton oxidation

The treatment of a non-biodegradable agrochemical wastewater has been studied by coupling of preliminary coagulation—flocculation step and further Fenton oxidation. High percentages of chemical oxygen demand (COD) removal (up to 58 %) were achieved in a first step using polyferric chloride as coagulant. This reduced significantly the amount of H₂O₂ required in the further Fenton oxidation. Using the stoichiometric amount relative to COD around 80 % of the remaining organic load was mineralized. The combined treatment allowed achieving the regional discharge limits of ecotoxicity at a cost substantially lower than the solution used so far where these wastewaters are managed as hazardous wastes.     

Spatial modeling of factor analysis scores

The use of mosses as biomonitors operates as an indicator of their concentration in the environment, becoming a methodology which provides a significant interpretation in terms of environmental quality. The different types of pollution are variables that can not be measured directly in the environment - latent variables. Therefore, we propose the use of factor analysis to estimate these variables in order to use them for spatial modelling. On the contrary, the main aim of the commonly used principal components analysis method is to explain the variability of observed variables and it does not permit to explicitly identify the different types of environmental contamination. We propose to model the concentration of each heavy metal as a linear combination of its main sources of pollution, similar to the case of multiple regression where these latent variables are identified as covariates, though these not being observed. Moreover, through the use of geostatistical methodologies, we suggest to obtain maps of predicted values for the different sources of pollution. With this, we summarize the information acquired from the concentration measurements of the various heavy metals, and make possible to easily determine the locations that suffer from a particular source of pollution.     

Impact of gold mining associated with mercury contamination in soil,biota sediments and tailings in Kenya

This work considered the environmental impact of artisanal mining gold activity in the Migori–Transmara area (Kenya). From artisanal gold mining, mercury is released to the environment, thus contributing to degradation of soil and water bodies. High mercury contents have been quantified in soil (140 μg kg^?1), sediment (430 μg kg^?1) and tailings (8,900 μg kg^?1), as expected. The results reveal that the mechanism for transporting mercury to the terrestrial ecosystem is associated with wet and dry depositions. Lichens and mosses, used as bioindicators of pollution, are related to the proximity to mining areas. The further the distance from mining areas, the lower the mercury levels. This study also provides risk maps to evaluate potential negative repercussions. We conclude that the Migori–Transmara region can be considered a strongly polluted area with high mercury contents. The technology used to extract gold throughout amalgamation processes causes a high degree of mercury pollution around this gold mining area. Thus, alternative gold extraction methods should be considered to reduce mercury levels that can be released to the environment.     

Comparative study of the urban quality of life in Cuban first-level cities from an objective dimension

The urban quality of life (UQoL) from objective dimension was analyzed in the main Cuban cities. An Urban Quality of Life Index (UQoLI) was developed in collaboration with 60 experts (five in each city). These experts belong to one of two categories: in charge of the planning of the city and members of the Municipal Council of Administration. One hundred and forty-two directors of the Local District Administration also participated in the analysis. The UQoLI includes three dimensions: social services, economic performance, and urban services, the importance of which is weighed according to expert criteria. A Ranking of the studied cities, sorted by the UQoLI, shows a tendency of increase it UQoL in the west even and central regions. This tendency contradicts one of the foundations of the Cuban sustainable development framework, i.e., equity.     

An assessment of the metabolic profile implied by agricultural change in two rural communities in the North of Argentina

The soy expansion model in Argentina generates structural changes in traditional lifestyles, which can be associated with different biophysical and socioeconomic impacts. To explore this issue, we apply an innovative method for integrated assessment—the multi-scale integrated analysis of societal and ecosystem metabolism framework—to characterize two communities in the Chaco Region, Province of Formosa, North of Argentina. These communities have recently experienced the expansion of soy production, altering their economic activity, energy consumption patterns, land use and human time allocation. The integrated characterization presented in the paper illustrates the differences (biophysical, socioeconomic and historical) between the two communities that can be associated with different responses. The analysis of the factors behind these differences has important policy implications for the sustainable development of local communities in the area.