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121.
Elżbieta Regulska Joanna Karpińska 《Environmental science and pollution research international》2014,21(7):5242-5248
A novel composite with an enhanced photocatalytic activity was prepared and applied to study the removal of bezafibrate (BZF), a hypolypemic pharmaceutical, from an aqueous environment. For the enhancement of titanium dioxide photoactivity a fullerene derivative, 2-(ferrocenyl) fulleropyrrolidine (FcC60), was synthesized and applied. Obtained composite was found to show a higher catalytic activity than pristine TiO2. Therefore, high hopes are set in composites that are based on carbonaceous nanomaterials and TiO2 as a new efficient photocatalysts. 相似文献
122.
Patrycja Marczewska Marek Miszczyk Marlena Płonka Dorota Kronenbach-Dylong Dariusz Szeremeta Mieczysław Sajewicz 《Journal of environmental science and health. Part. B》2013,48(7):590-597
Azoxystrobin (methyl(2E)-2-{2-[6-(2-cyanophenoxy)pyrimidin-4-yloxy] phenyl}-3-methoxyacrylate) is an active ingredient used to protect crops against fungal diseases. The experience of the Polish control laboratory indicates relatively frequent cases of counterfeit plant protection products (PPPs) containing this active substance. The present study aimed to use chemometric methods to model chemical fingerprints obtained by different chromatographic techniques to verify the original formulation of PPPs containing the active substance azoxystrobin. The pesticides used in the study came from different sources (including stores and warehouses), were manufactured at a different time and came from different production batches. The results obtained with the HPLC-DAD and HS-GC-MS techniques were then modeled using principal component analysis (PCA) and soft independent modeling by class analogy (SIMCA) classifier. The proposed approach has been confirmed as useful for verifying the authenticity of PPPs and can be used in the routine control testing of SC pesticides containing azoxystrobin. 相似文献
123.
Evci ED Bilgin MD Akgör S Zencirci SG Ergiń F Beşer E 《Environmental monitoring and assessment》2007,134(1-3):471-477
Objectives The purpose of this study was to determine electromagnetic fields, electric fields, humidity, temperature, and illumination
levels in hairdresser salons located in the downtown area of Aydin, Turkey. Also some health problems which could be related
with the occupational factors are evaluated.
Materials and methods The study was carried out in 30 hairdresser salons, all of which had been registered within the past 5 years. Electric and
electromagnetic fields, illumination, temperature and humidity measurements were determined for hairdryers, hood hairdryers
and depilatory heaters in the participating salons. A brief questionnaire about characteristics and the health status of hairdressers
and workplace conditions was prepared and administered to the hairdressers at the salons.
Results The mean electric fields of hairdryers, hood hairdryers and depilatory heaters were determined as 518 ± 74, 1,123 ± 199, and
648 ± 146 in V/m, respectively, at 5 cm from the surface of each device. These appliances generate mean electromagnetic fields
in excess of 0.25 μT at 5 cm: hand-held hairdryers, 5.0 ± 0.7 μT; hood hairdryers, 1.6 ± 0.3 μT; and depilatory heaters 1.9 ± 0.6 μT.
Total average of cumulative electric and electromagnetic fields, measured at a distance of 90 cm from the surface of these
three devices was calculated to be 98.8 V/m and 0.5 μT, in the participating salons.
Conclusions This preliminary study suggests that physical environmental factors in the salons may be contributing to the health problems
of the hairdressers, and the electrical equipments in the workplaces may have cumulative electric and electromagnetic effects. 相似文献
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127.
Magdalena Urbaniak Edyta Kiedrzyńska Adam Grochowalski 《Environmental monitoring and assessment》2017,189(2):90
The occurrence, concentrations, patterns, and loads of 17 2,3,7,8-substituted congeners of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were determined in treated wastewater collected at the outlets from 14 wastewater treatment plants (WTPs), divided into three size categories. The analysis also considered the effect of wastewater outflow on the final concentrations of PCDDs/Fs, as the samples were collected during flooding and stable hydrological conditions. None of the studied WTPs were found to completely remove toxic congeners of PCDDs/Fs from wastewater: the PCDD concentrations in the outgoing effluent during stable wastewater flow ranged from 2.99 to 177.19 pg/L, PCDFs from 6.05 to 51.30 pg/L, and the Toxic Equivalent (TEQ) was between 0.94 and 4.87 pg/L. The results from high wastewater flow were less diversified, ranging from 5.04 to 8.85 pg/L for PCDDs, from 11.47 to 32.33 pg/L for PCDFs and from 2.00 to 4.65 pg/L for TEQ. The smallest WTPs demonstrated the highest average total and TEQ concentrations due to limited volume, short retention time and outdated technology, and, hence, insufficient treatment efficiency. The largest WTPs have the potential to substantially affect the quality of river water, as despite being associated with the lowest concentrations, they released much greater volumes of treated wastewater and, hence, the greatest amounts of analyzed compounds. Elevated TEQ values were observed at high flow in all WTP size categories indicating the impact of high and stable wastewater flow on the concentrations of the observed PCDDs/Fs. 相似文献
128.
Cecylia Łukaszuk Elżbieta Krajewska-Kułak Andrzej Guzowski Bogumiła Kraszyńska Magdalena Grassmann Radosław Dobrowolski 《Journal of the Air & Waste Management Association (1995)》2013,63(9):1141-1144
The aim of this study was to analyze the incidence of fungi in the chapel crypt. The MAS 100 was used to monitor the air pollution. The lowest numbers of fungal colonies were isolated at the entrance to the cemetery (2400 CFU/m3). The outside temperature ranged from 24.5oC to 28.1oC, and relative humidity was between 35.3% and 46.4 %. The highest of fungal colonies from air samples at baseline were isolated inside the crypt when coffin was opened (4820 CFU/m3). The temperature in the crypt at baseline varied between 19.6°C and 25.6°C and humidity was between 50.8% and 60.1%. The number of fungal colonies increased significantly at the end of the study. Ten species of fungi were isolated from air samples inside and outside the chapel, and seven species of fungi were isolated on the surface of the exterior and interior of the chapel. Thirteen types/species of fungus were isolated from air samples collected in the crypt; 15 species of fungi were isolated on the walls, surface of the coffin, bones and other objects. Assessment of fungi in the air samples and different surfaces of the crypt, it revealed very high levels of molds in the air samples.Implications: Assessment of fungi in the air samples and different surfaces of the crypt revealed high levels of molds in the air samples. Fungal numbers within the crypt exceed recommended limits for occupational exposure. Employees working in the crypts should know about these hazards. 相似文献
129.
Magdalena Gucia Grażyna Jarzyńska Anna K. Kojta Jerzy Falandysz 《Journal of environmental science and health. Part. B》2013,48(2):81-88
Mature specimens of Parasol Mushroom were collected annually in the outskirts of the Siemiany (2000–2003) and Rafa (2001–2003) sites in the northern part of Poland to examine temporal variations and similarities in the composition of 20 chemical elements. Analysis was done under the same condition and using well-validated analytical methods. Elements were determined by inductively coupled plasma–atomic emission spectroscopy and cold vapour–atomic absorption spectroscopy (Hg). The ranges of Ag, Al, Ba, Ca, Cd, Co, Cu, Cr, Fe, Hg, K, Mg, Mn, Na, Ni, P, Pb, Rb, Sr and Zn concentrations in the caps of fruiting bodies were similar (p > 0.05; Mann-Whitney U test) for both geographically distant sites, and these specimens from Rafa were more contaminated with Pb (p < 0.05; Mann-Whitney U test). The annual collections of caps in the Siemiany site varied in Ag, Al, Ba, Ca, Cd, Co, Cu, Fe, Hg, Na, Rb and Sr and contents (0.05 < p < 0.001), while they were similar in Cr, K, Mg, Mn, Ni, P, Pb and Zn (p > 0.05; Mann-Whitney U test). The annual collections of specimens from the Rafa site varied in contents of Ag, Al, Ba, Ca, Fe, Hg, K, Mg, Mn, P, Rb and Zn (p > 0.05), while they were similar in Cd, Co, Cr, Cu, Na, Ni, Pb and Sr (p < 0.05). The results of this study imply that metallic elements content of Parasol Mushroom collected at the same undisrupted sites, and hence keeping the same geochemical condition for mushroom development and fructification (the same stands and probably the same mycelia), can fluctuate over the years or the life-span of mycelium. Hence, when assessing the nutritional value of essential metallic elements and status of non-essential or toxic metallic elements in Parasol's Mushroom caps (and probably also of other mushrooms species) to man, the possible fluctuation in contents over time have to be taken into account. 相似文献
130.
Agata J. Wilczyńska-Piliszek Sławomir Piliszek Jerzy Falandysz 《Journal of environmental science and health. Part. B》2013,48(7):660-669
In this study the values of subcooled vapor pressures (log PL) were estimated for 209 trans chloroazobenzenes (Ct-ABs) that fill some gaps in analytical and experimental data on these compounds. There are 209 chloro derivatives of trans azobenzenes that are relatively stable and more environmentally relevant than 209 chloro cis congeners. The calculations models were based on the Quantitative Structure-Property Relationship (QSPR) scheme using the semi-empirical method (PM6) in molecular package (MOPAC) software and density functional theory (DFT) method using B3LYP functional and 6-311++G** basis set) in Gaussian 03 software method and the artificial neural networks (ANNs) prediction. The values of log PL predicted by models used varied between ?3.94 to ?2.66 for Mono-; ?4.85 to ?2.97 for Di-; ?5.18 to ?3.17 for Tri-; ?6.02 to ?3.77 for Tetra-; ?6.64 to ?4.64 for Penta-; ?7.36 to ?4.76 for Hexa-; ?7.54 to ?5.79 for Hepta-; ?7.75 to ?6.64 for Octa-; ?7.89 to ?7.44 for Nona-Ct-Abs; and ?8.09 and ?8.13 for Deca-Ct-AB. Based on these values Ct-ABs can be grouped localized among relatively low (log PL ?4 to ?2) and low (log PL < ?4) mobile Persistent Organic Pollutants (POPs). Both the calculation methods employed were characterized by similar prediction ability of subcooled vapor pressure values of Ct-ABs, while those of PM6 are much more efficient due to a cheaper hardware used and around 300-fold less time spent on calculations. 相似文献