Simulation and Evaluation of Control Strategies for Ozone Reduction in a Complex Terrain in Southwestern Spain

During the central months of the year, southwestern Spain is under strong insolation and weak synoptic forcing, promoting the development of sea breezes and mountain-induced winds and creating recirculations of pollutants. The complex topography of the Southwestern Iberia Peninsula induces the formation of vertical layers, into which the pollutants are injected and subjected to long-distance transport and compensatory subsidence. The characteristics of these highly complex flows have important effects on the pollutant dispersion. Air pollution studies in very complex terrains require high-resolution modelling for resolving the flow dynamics. This paper shows the results obtained from using the MM5-CAMx multiscale-nested air quality model to relate the sensitivity regimes for ozone, nitrogen oxides and volatile organic compounds in an area of high geographical complexity. The article assesses the impact on the hourly and eight-hourly maximum daily ozone concentrations of four reduction strategies during two ozone pollution episodes. This analysis of the ozone response has led to a preliminary evaluation of the effectiveness of the most common control strategies: traffic, industry, mixed traffic and industry, and closure of some of the largest industries (oil and petrochemical refineries). Photochemical indicators show that ozone chemistry in southwestern Spain is strongly sensitive to NO _x . However, volatile organic compound-sensitive points are found in areas with anthropogenic influence (highways, cities and industrial parks). Our results indicate that reductions in road traffic lead to ozone reductions over large areas, whereas reductions in industrial emissions, despite sometimes showing greater decreases in the maximum hourly and eight-hourly ground-level ozone levels, lead to ozone reductions in a local area only. In the control study case, with the oil refinery and the petrochemical plants closed, decreases in ozone hourly concentrations are up to 40% higher than in the other emission control scenarios studied. This analysis provides an assessment of the effectiveness of different policies for controlling precursor emissions by comparing the modelled results for different scenarios.     

The electro-oxidation of tetracycline hydrochloride in commercial DSA® modified by electrodeposited platinum

Environmental Science and Pollution Research - Tetracycline hydrochloride (TCH) electro-oxidation by commercial DSA® and commercial DSA® modified by platinum electrodeposition was...     

Cointegrated land use and CO2 emissions—the silent Columbian cattle revolution

The objective of this research is to discuss the relationship between the growth of livestock and the environmental impact it generates in Colombia. For this, data were extracted from the FAO STAT for the period of 1961 to 2017. The livestock inventory has had a significant growth during the last 50 years. This has generated environmental exposure and the release of carbon, sequestered by continuous deforestation performed in the practice of extensive livestock. Recurring to vector error correction models, we observed the existence of long-term relations between CO₂ emissions from dairy cattle and emissions from slaughtered cattle, deforestation, pastures, and forest development. Changes in CO₂ emissions from dairy cattle tend to be anticipated by changes in CO₂ emissions from the other analyzed sources, which prove how the current investment in dairy cattle results from the accumulated debates in Colombia regarding the different sources of livestock emissions.

     

Guidelines for the strategic management of flood risks in industrial plant oil in the Brazilian coast: adaptive measures to the impacts by relative sea level rise

This study provides guidelines for strategic management in industrial oil plants linked to uncertainties of climate change through the development of integrated planning methodology with focus on coastal flooding events caused by relative sea level rise (RSLR). The research site is in Redonda Island, located in Guanabara Bay, Rio de Janeiro City, Brazil, and since 1960, it constitutes an industrial oil plant facility. The region suffers interaction with storms and meteorological tides from extratropical cyclones over the South Atlantic Ocean, being vulnerable to risks of disasters, floods, and coastal erosion. A Program on Vulnerability and Adaptation Assessments to Relative Sea Level Rise (“Programa de Avaliação e Adaptação às Vulnerabilidades de Elevação do Nível Relativo do Mar—PAAVENRM”) was developed to avoid compromising the regional and local development in the industrial system of the island, which is an ad hoc instrument designed to anticipate and reduce risks, damages, and losses by occurrence of extreme climatic events in coastal areas prone to flooding caused by RSLR. Results from computer simulation modeling indicate 37 prospective qualitative scenarios that consolidate the conditions of future climate vulnerability of the plant, starting from United Nations Intergovernmental Panel on Climate Change (IPCC) information for RSLR up to 2100. Three quantitative forecasting scenarios were simulated, under boundary conditions preset for different altimetric ranges subject to submersion, based upon ordinary and extraordinary tides measured in the area in relation to RSLR, which allowed the evaluation of the industrial infrastructure at risk. Furthermore, three thematic maps were elaborated for the planning of specific coastal protection interventions. Percentages of physical damage and property losses were estimated. The importance of applying guidelines for medium and long-term corporate strategy management, integrating the risk of flooding, the rigging of civil defense systems, meteorology, and of the plans, programs, and existing systems and others to be developed is highlighted. From this perspective, the proposed scenarios help to identify the most relevant alternatives for mitigation and adaptation under technical criteria for decision making in the study area.     

On sensitivity analysis: Let’s use it more!

The key factors that influence the population growth rate can be identified with sensitivity analysis. Caswell presented an algorithm based on vector calculus that speeds up, and improves the practicality of the application of the sensitivity analysis, by calculating the derivatives of the explicit elements from the population Leslie matrix. Despite the usefulness of the sensitivity analysis, it is still barely applied to empirical data, partially due to requirements of high quality demographic data and failure of compatibility between time intervals of field data collection and organism’s life stage timing. This can result in the absence of a certain vital rate as a separated element in the population projection matrix, and thus intricacy in obtaining its sensitivity. In this note we call the attention for the applied value of sensitivity analysis, and also we point to a simple formula that is easily implemented in Caswell Matlab algorithm, to calculate the sensitivity of a vital rate that is not explicit as a matrix element.     

Human and crab exposure to mercury in the Caribbean coastal shoreline of Colombia: impact from an abandoned chlor-alkali plant

Human hair samples from male and female people aged 6-85 years, as well as muscle of crabs (Callinectes sapidus and Callinectes bocourti) were collected from different fishing places along the Caribbean coastal shoreline of Colombia and analyzed for total mercury (T-Hg) in order to establish the impact of mercury-polluted sediments in Cartagena bay on the ecosystem. Hair T-Hg in inhabitants varied between 0.1 and 21.8 microg/g, with average and median of 1.52 microg/g and 1.1 microg/g, respectively. Differences between sampling locations were significant (P<0.01) and median values decreased in the order: Ca?o del Oro (1.5 microg/g)相似文献   

Antibiotic resistance of Enterococcus spp. isolated from wastewater and sludge of poultry slaughterhouses

Antibiotimicrobial resistance was investigated in 537 Enterococcus spp. isolates recovered from 22 samples of crude inflow, treated effluent and sludge collected in wastewater treatment plants of eight poultry slaughterhouses of Portugal. No significant differences (P > 0.05) were found in the resistance to each antimicrobial agent with regards to the origin of the sample (inflow, sludge and effluent). Many of the isolates displayed resistance to tetracycline (85.7%), erythromycin (45.7%), nitrofurantoin (34.0%) and rifampicin (17.8%). Resistance was also observed, but to a lesser extent, to ciprofloxacin (10.2%), ampicillin (8.0%), chloramphenicol (4.6%), vancomycin (0.9%) and gentamicin (0.4%). Resistance to three or more antimicrobial classes was present in 37.1% of the isolates. Wastewater treatment resulted in viable enterococci decrease between less than 1 log and 4 log; nevertheless, more than 4.4 x 10(5) colony forming units (CFU)/100 mL were present in the outflow of the plants and thus resistant enterococci are not prevented from reaching the general environment.     

Identification and chemical characterization of industrial particulate matter sources in southwest Spain

A detailed physical and chemical characterization of coarse particulate matter (PM10) and fine particulate matter (PM2.5) in the city of Huelva (in Southwestern Spain) was carried out during 2001 and 2002. To identify the major emission sources with a significant influence on PM10 and PM2.5, a methodology was developed based on the combination of: (1) real-time measurements of levels of PM10, PM2.5, and very fine particulate matter (PM1); (2) chemical characterization and source apportionment analysis of PM10 and PM2.5; and (3) intensive measurements in field campaigns to characterize the emission plumes of several point sources. Annual means of 37, 19, and 16 microg/m3 were obtained for the study period for PM10, PM2.5, and PM1, respectively. High PM episodes, characterized by a very fine grain size distribution, are frequently detected in Huelva mainly in the winter as the result of the impact of the industrial emission plumes on the city. Chemical analysis showed that PM at Huelva is characterized by high PO4(3-) and As levels, as expected from the industrial activities. Source apportionment analyses identified a crustal source (36% of PM10 and 31% of PM2.5); a traffic-related source (33% of PM10 and 29% of PM2.5), and a marine aerosol contribution (only in PM10, 4%). In addition, two industrial emission sources were identified in PM10 and PM2.5: (1) a petrochemical source, 13% in PM10 and 8% in PM2.5; and (2) a mixed metallurgical-phosphate source, which accounts for 11-12% of PM10 and PM2.5. In PM2.5 a secondary source has been also identified, which contributed to 17% of the mass. A complete characterization of industrial emission plumes during their impact on the ground allowed for the identification of tracer species for specific point sources, such as petrochemical, metallurgic, and fertilizer and phosphate production industries.     

Bioconcentration of trichlorfon insecticide in pacu (Piaractus mesopotamicus)

Pacu (Piaractus mesopotamicus) is one of the most representative fish species of Brazilian fish culture, produced in most Brazilian States due to its importance for food diet and sport fishery. This research work investigated the bioconcentration of trichlorfon [phosphonic acid, (2,2,2-trichloro-1-hydroxyethyl)-dimethyl ester] insecticide in pacu under fish ponds culture conditions and a first-order kinetic insecticide dissipation in the water. Trichlorfon was applied at a rate of 4.62 x 10(4) mg to each of three nurseries containing 4.2 x 10(5)l of water. The fish ponds were built on the soil and supported 60 young pacus fishes. The concentrations of trichlorfon fitted to an equivalent non-linear kinetic type model, allows estimate the values of trichlorfon concentration in the water and fishes. These estimations together with the bioconcentration factor determined in the fishes, allowed establishing theoretical reference limit values for human consumption of fishes produced under cultivation systems with trichlorfon. This information will contribute to enlarge the database on pesticide use in Brazilian commercial fish farming, especially about the use of trichlorfon as chemotherapy for the control of fish ectoparasites.