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41.
Leaching of metals from sewage sludge during one year and their relationship to particle size 总被引:2,自引:0,他引:2
Leaching of metals from sewage sludge can lead to their accumulation in topsoil and can also contaminate groundwater. Our objectives were to document the metal leachates and the size distribution of leached particles from sewage sludge and to identify possible correlations with physical factors. Results from monthly lysimeter sampling showed an initial release followed by decline for most metals. Cadmium, Ca, Sr, Li, Mn, Ni and Zn showed a "cyclic" behaviour. Filtration revealed that this "cyclicity" had no correlation to the size of released particles, but Al, Cr, Fe, Cu, Ag and Pb were clearly related to release of coarser particles most of the year. Total metal amounts leached during one year, relative to original sludge content, had the order Na>Ca=Mg>Mn>Sr>Zn>K>Li=Ni>Cd>Co>Rb>Ag>Cr>Ba=Cu>Ga>Al=Pb=Fe. There were no simple correlations between monthly measured leachate concentrations and precipitation, temperature or pH of precipitation. Occasional leachate sampling might give misleading values for metals with "cyclic" behaviour. 相似文献
42.
Jenny Eriksson Åsa Forsman Anna Niska Susanne Gustafsson Gunilla Sörensen 《Traffic injury prevention》2019,20(8):56-61
AbstractObjective: In Sweden, cyclists, pedestrians, and moped riders share the space on combined pedestrian and cycle paths, and their speeds may differ greatly. Both actual speed and speed differences can potentially influence the number of accidents on the shared paths. As a starting point, this article studies the speed component and how cyclists’ speed varies at pedestrian and cycle paths depending on the day, week, and year; road user composition; and road design.Methods: Three data sources were used: Existing measurements of cycle speed and flow in 3 different Swedish municipalities, Eskilstuna (1 site, January–December 2015), Linköping (6 sites, 4?weeks in September–October 2015), and Stockholm (10 sites, 1–5?days in August–September 2015); complementary measurements of cycle speed and flow in Linköping (4 sites, 1–10?days in August–September 2016) and Stockholm (1 site, only part of 2?days in August 2016) were also conducted within the project, in addition to roadside observations of bicycle types at the 5 new sites.Results: The average speed of cyclists on the paths varied between 12.5 and 26.5?km/h. As expected, the lower average speeds were found in uphill directions, near intersections, and on paths with high pedestrian flows. The higher speeds were found in downhill directions and on commuter routes. In all, 70%–95% of road users observed on pedestrian and cycle paths were cyclists, and 5%–30% were pedestrians. The most common type of bicycle was a comfort bike, followed by a trekking bike. Electric-assisted bicycles and racer bikes occurred at all sites, with proportions of 1%–10% and 1%–15%, respectively. The 2 sites with the highest proportion of electric-assisted bicycles and racer bicycles also had the highest average speeds. The differences in average speed throughout the day, week, and year could only be assessed at one of the sites. Only small differences were found, with the most noticeable being that the average speed was lower in January and February (13.8?km/h) compared to the rest of the year (15.3–16.1?km/h). The average speed was also lower during daytime (14.7?km/h) than during other parts of the day (15.4–15.8?km/h).Conclusions: The relationship between bicycle type and measured speed was not entirely clear, but the results suggest that paths with higher proportions of electric and racer bicycles have higher average speeds. There also appears to be a connection between average speed and the width of the distribution; that is, the higher the average speed, the wider the speed distribution. More research is needed on how speed levels and speed variance affect accident risk. 相似文献
43.
Persson NJ Bucheli TD Gustafsson O Broman D Naes K Ishaq R Zebühr Y 《Chemosphere》2005,59(10):1475-1485
This study compares in situ observed porewater concentration of persistent organic pollutants (POPs) with predictions by common solid-water phase distribution models. Bottom sediments were sampled in The Grenlandsfjords, Norway, and the interstitial porewater was isolated from the solids by centrifugation and filtration. Both phases were analysed for polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/F), polycyclic aromatic hydrocarbons (PAH), and organic carbon. Based on the sediments' solid phase content of POPs, organic carbon, and soot carbon, we used the organic matter partitioning (OMP), and also the soot and organic matter partitioning (SOMP) model to estimate the porewater concentration. The OMP model gave better agreement to observations than the SOMP model for both PCDD/Fs and PAHs. The observed concentration of the PCDD/Fs in the sediments' porewater was much higher than in the deep water of the fjord. The logarithm of the organic matter-water partitioning coefficent (log K(OC)) in the porewater had positive linear regression on the logarithm of the octanol-water partitioning coefficient (log K(OW)). The slope of the regression model was indistinguishable from 1, except for the PAHs as a group which had a slope less than 1. This contrasts to previous studies undertaken in The Grenlandsfjords water column, where the slopes were higher than 1 for PCDD/Fs, and the K(OC) were much higher than the K(OW). One explanation may be that the influence of POPs adsorption to soots decrease because competitive sorption by other compounds in the sediment are higher than in the water column. This indicates that the sorption isotherms for these POPs need better understanding in order to be applicable in both the water column and the porewater. 相似文献
44.
Mikael Gillner Birgitta Fernstrm Jan-ke Gustafsson Jan Bergman Christian Cambillau 《Chemosphere》1986,15(9-12):1673-1680
We have investigated the capacity of various indoles to inhibit specific binding of [1,6-3H]2,3,7,8-tetrachlorodibenzo-
-dioxin ([3H]TCDD) in rat liver cytosol, as analyzed by electrofocusing in polyacrylamide gels. Of these indoles, indolo[3,2-
]carbazole was the most active. The IC50 value for TCDD receptor binding of indolo[3,2-
]carbazole as well as for 2,3,7,8-tetrachlorodibenzofuran was 3.6 nM. We have also studied the influence on binding exerted by introduction of some substituents on indolo[3,2-
]carbazole. Substitution with methyl groups at the 5 and 11 positions resulted in an increased affinity (IC50 1.2 nM) for the TCDD receptor as compared to the parent compound. Computer-supported molecular structure studies indicated that if the van der Waals radii of atoms are included, a rectangle of 6.8 × 13.7 Å may account for the binding of high-affinity ligands to the TCDD receptor. 相似文献
45.
Steven Banwart Eva-Lena Tullborg Karsten Pedersen Erik Gustafsson Marcus Laaksoharju Ann-Chatrin Nilsson Bill Wallin Peter Wikberg 《Journal of contaminant hydrology》1996,21(1-4)
Entrance tunnel construction at the Äspö Hard Rock Laboratory opened a conductive vertical fracture zone at a depth of 70 m on March 13, 1991. Three weeks later a sharp dilution front corresponding to 80% shallow water inflow to the originally saline fracture zone arrived at the entrance tunnel depth. In spite of this large inflow of shallow water, the fracture zone has remained persistently anoxic over a subsequent
period. Results from gas sampling and 14C dating of dissolved organic and inorganic carbon conclusively show that recent organic carbon is being transported into the fracture zone and oxidized to carbon dioxide. These results are important when considering possible changes of redox status in the deep groundwater environment during construction and operation of a repository for spent nuclear fuel. Opening this fracture zone to large-scale surface water inflow adds reducing capacity in the form of organic carbon. This implies that the soil cover may provide important protection against input of dissolved oxygen to fractures being drained during the open phase of the repository. 相似文献
46.
Current accelerating biodiversity loss is by many conservationists regarded as a result of economic development. Some economists agree on this viewpoint but argue it is valid at low income levels because of the need to secure a minimum living standard. On the other hand, economic development at higher income levels can instead mitigate biodiversity loss because of improved willingness and affordability to implement measures such as protected areas. This so-called environmental Kuznets relation is tested in this study by econometric analysis of cross-sectional data on a global scale. However, the results do not support this relation. Instead, we found a relation between economic and institutional development where economic development decreases biodiversity loss at a minimum level of institutional quality, i.e. minimum capacity to implement and secure property rights for the citizens. Our results thus question policies that neglect institutional quality for reversing biodiversity loss. Further, it was found that biodiversity loss increases with invasive species, high average temperature and precipitation, and spatial autocorrelation. 相似文献
47.
Carstensen Jacob Conley Daniel J. Almroth-Rosell Elin Asmala Eero Bonsdorff Erik Fleming-Lehtinen Vivi Gustafsson Bo G. Gustafsson Camilla Heiskanen Anna-Stiina Janas Urzsula Norkko Alf Slomp Caroline Villnäs Anna Voss Maren Zilius Mindaugas 《Ambio》2020,49(6):1194-1210
Ambio - The coastal zone of the Baltic Sea is diverse with strong regional differences in the physico-chemical setting. This diversity is also reflected in the importance of different... 相似文献
48.
Distribution of PCNs, PCBs, and other POPs together with soot and other organic matter in the marine environment of the Grenlandsfjords, Norway 总被引:3,自引:0,他引:3
The apparently dissolved concentration of polychlorinated naphthalenes (PCNs) and three planar polychlorinated biphenyls (pPCBs) were sampled and analysed in the water column of a marine fjord system. We also measured how much of these persistent organic pollutants (POPs) were associated with suspended particles. The field observations showed that an unexpectedly high portion of the pollutants were particle-associated. The factor of deviation from model predictions had positive linear regression on the soot carbon:particulate organic carbon ratio of the particles, and on estimates of the soot-water distribution coefficient for the PCNs. The spatial distribution of surface sediment concentrations of PCNs and polycyclic aromatic hydrocarbons (PAH) were found to consistently follow the sediment content of soot (f(SC)) to a larger extent than the bulk organic matter (f(OC)). There were no systematic differences in the strength of correlation of sediments concentrations of other POPs, i.e. octachlorostyrene and organochlorine pesticides with sediment concentration to f(SC) and f(OC). Mechanisms possible of generating these types of observations, e.g. adsorption to soot carbon in the marine particle, are discussed. 相似文献
49.
Lorenz Poellinger Anna Wilhelmsson Johan Lund Jan-ke Gustafsson 《Chemosphere》1986,15(9-12):1681-1686
An assessment of the physicochemical characteristics of the rat hepatic receptors for 2,3,7,8-TCDD and for corticosteroid hormones reveals striking analogies between both receptor systems. 相似文献
50.
Mats Gustafsson Göran Blomqvist Anders Gudmundsson Andreas Dahl Per Jonsson Erik Swietlicki 《Atmospheric environment (Oxford, England : 1994)》2009,43(31):4699-4702
Accelerated pavement wear is one of the major environmental disadvantages of studded tyres in northern regions and results in increased levels of PM10. Measurements of PM10 in a road simulator hall have been used to study the influence of pavement properties, tyre type and vehicle speed on pavement wear. The test set-up included three different pavements (one granite and two quartzite with different aggregate sizes), three different tyre types (studded, non-studded, and summer tyres) and different speeds (30–70 km h?1). The results show that the granite pavement was more prone to PM10 production compared to the quartzite pavements. Studded winter tyres yield tens of times higher PM10 concentrations compared to non-studded winter tyres. Wear from summer tyres was negligible in comparison. It was also shown that wear is strongly dependent on speed; every 10 km h?1 increase yielded an increase of the PM10 concentration of 680 μg m?3 in one of the simulator experiments. 相似文献