Century-long synchrony of fossil algae in a chain of Canadian prairie lakes

Synchronous fluctuations in limnological variables among lakes may signal that large-scale environmental factors regulate lake ecosystem structure, yet most estimates of temporal coherence are based on short (<25 yr) time series, and little is known of how synchrony varies among biological taxa or of the causes of temporal coherence. Here we used time series of 13 fossil pigments from diverse algal groups in seven lakes of the climatically sensitive Northern Great Plains to demonstrate that algal synchrony (S) during the 20th century arose mainly from interdecadal increases in algal abundance rather than from interannual coherence. Synchrony of time series differed greatly among algal taxonomic groups (S = 0.0-0.75) and was not usually spatially structured, but decreased 83% following removal of long-term trends using exponential models or first-difference calculations. Overall, coherence was greatest for labile compounds chl a (S = 0.53) and fucoxanthin (S = 0.75), possibly reflecting the influence of postdepositional degradation processes on fossil time series. However, analysis of chemically stable pigments also indicated that synchrony was great for cryptophytes (as alloxanthin, S = 0.42) and diatoms (diatoxanthin, S = 0.37), taxa that bloom in spring. In contrast, synchrony of total algal abundance was low (beta-carotene, pheophytin a, S < 0.10), reflecting low interannual coherence of summer taxa including colonial cyanobacteria and chlorophytes. Unexpectedly, past variations in climate, resource use, and urbanization explained >85% of algal variation in individual lakes, but only 35% of synchronous algal fluctuations, suggesting that the factors controlling algal synchrony differ from those regulating algal abundance.     

Recognition that causal processes change during plant invasion helps explain conflicts in evidence

Despite intensive research, we still have no general understanding of why plant invasions occur. Many different mechanisms of plant invasions have been proposed, but studies designed to investigate them often produce inconsistent results. It remains unclear whether this unsatisfying state of affairs reflects the complexity of the real world (in which every invasion is unique) or the failure to identify the key processes driving most plant invasions. Here we argue that greater generalization is possible, but only if we recognize that the ecological and evolutionary processes enabling a species to advance into a new area change during the course of an invasion. In our view, an invasion can often usefully be subdivided into a primary phase, in which the abundance of an often preadapted species increases rapidly (typically in resource-rich, disturbed habitats), and a secondary phase, in which further spread is contingent upon plastic responses or genetic adaptation to new ecological circumstances. We present various examples to show how this partitioning of the invasion phase sensu stricto produces new hypotheses about the processes underlying plant invasions. Some of these hypotheses can be conveniently tested by investigating plant invasions along strong environmental gradients such as those that occur in mountainous regions.     

Input and fate of anthropogenic estrogens and gadolinium in surface water and␣sewage plants in the hydrological basin of Prague (Czech Republic)

The concentration of the estrogens 17β-estradiol, estriol, estrone, 17α-ethinylestradiol, mestranol and norethisterone and of the anthropogenic gadolinium (Gd_ant) has been determined in the creeks and rivers, sewage treatment plants and water works of the city of Prague. The rapid degradation of estrogens in surface water allows the estrogen concentration gradient to be used as a very precise and sensitive guideline by which to pin-point sewage leaks into surface run-off water. The rather conservative behavior of Gd_ant in surface and ground water documents in the present case the presence of sewage water in the surface water cycle.     

Applied tracer tests in fractured rock: Can we predict natural gradient solute transport more accurately than fracture and matrix parameters?

Applied tracer tests provide a means to estimate aquifer parameters in fractured rock. The traditional approach to analysing these tests has been using a single fracture model to find the parameter values that generate the best fit to the measured breakthrough curve. In many cases, the ultimate aim is to predict solute transport under the natural gradient. Usually, no confidence limits are placed on parameter values and the impact of parameter errors on predictions of solute transport is not discussed. The assumption inherent in this approach is that the parameters determined under forced conditions will enable prediction of solute transport under the natural gradient. This paper considers the parameter and prediction uncertainty that might arise from analysis of breakthrough curves obtained from forced gradient applied tracer tests. By adding noise to an exact solution for transport in a single fracture in a porous matrix we create multiple realisations of an initial breakthrough curve. A least squares fitting routine is used to obtain a fit to each realisation, yielding a range of parameter values rather than a single set of absolute values. The suite of parameters is then used to make predictions of solute transport under lower hydraulic gradients and the uncertainty of estimated parameters and subsequent predictions of solute transport is compared. The results of this study show that predictions of breakthrough curve characteristics (first inflection point time, peak arrival time and peak concentration) for groundwater flow speeds with orders of magnitude smaller than that at which a test is conducted can sometimes be determined even more accurately than the fracture and matrix parameters.     

Life cycle assessment of active and passive groundwater remediation technologies

Groundwater remediation technologies, such as pump-and-treat (PTS) and funnel-and-gate systems (FGS), aim at reducing locally appearing contaminations. Therefore, these methodologies are basically evaluated with respect to their capability to yield local improvements of an environmental situation, commonly neglecting that their application is also associated with secondary impacts. Life cycle assessment (LCA) represents a widely accepted method of assessing the environmental aspects and potential impacts related to a product, process or service. This study presents the set-up of a LCA framework in order to compare the secondary impacts caused by two conceptually different technologies at the site of a former manufactured gas plant in the city of Karlsruhe, Germany. As a FGS is already operating at this site, a hypothetical PTS of the same functionality is adopted. During the LCA, the remediation systems are evaluated by focusing on the main technical elements and their significance with respect to resource depletion and potential adverse effects on ecological quality, as well as on human health. Seven impact categories are distinguished to address a broad spectrum of possible environmental loads. A main point of discussion is the reliability of technical assumptions and performance predictions for the future. It is obvious that a high uncertainty exists when estimating impact specific indicator values over operation times of decades. An uncertainty analysis is conducted to include the imprecision of the underlying emission and consumption data and a scenario analysis is utilised to contrast various possible technological variants. Though the results of the study are highly site-specific, a generalised relative evaluation of potential impacts and their main sources is the principle objective rather than a discussion of the calculated absolute impacts. A crucial finding that can be applied to any other site is the central role of steel, which particularly derogates the valuation of FGS due to the associated emissions that are harmful to human health. In view of that, environmental credits can be achieved by selecting a mineral-based wall instead of sheet piles for the funnel construction and by minimising the steel consumption for the gate construction. Granular activated carbon (GAC) is exclusively considered as the treatment material, both in-situ and on-site. Here it is identified as an additional main determinant of the relative assessment of the technologies since it is continuously consumed.     

Export of nutrients from golf courses on the Precambrian Shield

Annual export rates, or fluxes, of total nitrogen (TN), nitrate, total phosphorus (TP) and potassium from four streams on two golf courses on the Precambrian Shield were compared with those from forested reference locations. Overall, the mean annual fluxes of K, TN, NO(3) and TP from golf courses were greater than from forested areas by 10, 2, 6 and 2 times, respectively. The overall mean export coefficients (kg/ha/yr) were 16 for K, 5.2 for TN, 2.1 for NO(3) and 0.14 for TP. For TN and TP, these are similar to those reported from cropland in Canada by Chambers and Dale.     

Predicting Gran alkalinity and calcium concentrations in river waters over a national scale using a novel modification to the G-BASH model

Monthly stream water calcium and Gran alkalinity concentration data from 11 sub-catchments of the Nether Beck in the English Lake District have been used to appraise the transferability of the Scottish, River Dee-based G-BASH model. Readily available riparian zone geochemistry and flow paths were used initially to predict minimum and mean stream water concentrations at the Nether Beck, based on calibration equations from the River Dee catchment data. Predicted values significantly exceeded observed values. Differences in runoff between the two areas, leading to a dilution effect in the Nether Beck, explained most of the difference between observed and predicted values. Greater acid deposition in the Lake District also reduced stream water Gran alkalinity concentrations in that area. If regional differences in precipitation, evapotranspiration and pollutant deposition are incorporated into the model, it may then be used reliably to predict catchment susceptibility to acidification over a wide regional (national) scale.     

Air quality measurements for the aerosol research and inhalation epidemiology study

Measurements of pollutant gases, airborne particulate matter mass and composition, and meteorology have been made at a core site near downtown Atlanta, GA, since August 1998 in support of the Aerosol Research and Inhalation Epidemiology Study (ARIES). This site is one of eight in the Southeastern Aerosol Research and Characterization network. The measurement objective is to provide a long-term, multivariate dataset suitable for investigating statistical associations of respiratory and cardiovascular disease with airborne particulate matter composition, meteorology, and copollutant gases through epidemiologic modeling. Measurements are expected to continue through 2010. Ancillary multiyear measurements at additional sites in the Atlanta metropolitan area and in short-term exposure assessments have been used to estimate the exposure/measurement error associated with using data from a central site to approximate human exposures for the entire area. To date, 13-, 25-, and 53-month air quality datasets have been used in epidemiologic analyses.     

Radioactivity in trinitite six decades later

The first nuclear explosion test, named the Trinity test, was conducted on July 16, 1945 near Alamogordo, New Mexico. In the tremendous heat of the explosion, the radioactive debris fused with the local soil into a glassy material named Trinitite. Selected Trinitite samples from ground zero (GZ) of the test site were investigated in detail for radioactivity. The techniques used included alpha spectrometry, high-efficiency gamma-ray spectrometry, and low-background beta counting, following the radiochemistry for selected radionuclides. Specific activities were determined for fission products (90Sr, 137Cs), activation products (60Co, 133Ba, 152Eu, 154Eu, 238Pu, 241Pu), and the remnants of the nuclear fuel (239Pu, 240Pu). Additionally, specific activities of three natural radionuclides (40K, 232Th, 238U) and their progeny were measured. The determined specific activities of radionuclides and their relationships are interpreted in the context of the fission process, chemical behavior of the elements, as well as the nuclear explosion phenomenology.