长三角经济能源约束下的大气污染问题及对区域协作的启示

长三角地区大气污染治理取得一定成效,然而空气质量改善逐渐进入瓶颈期和攻坚期,大气污染治理战略需要从宏观层面系统谋划。本文系统分析了近10年来长三角区域经济、能源、产业、交通的发展状况和趋势,结合区域大气污染物浓度水平的演变,分析了大气污染与经济社会发展的耦合关系。结合当前区域空气污染的空间分布差异以及经济能源交通结构的内在差别,识别了大气污染的区内差异特征及关键制约因素。在此基础上,从能源结构和产业结构调整、交通结构优化、分区施策、深化治理等角度,为深化区域大气污染联防联控,持续改善大气污染问题提出了政策建议。     

Isovaleraldehyde elimination by UV/TiO2 photocatalysis: comparative study of the process at different reactors configurations and scales

A proposal for scaling-up the photocatalytic reactors is described and applied to the coated catalytic walls with a thin layer of titanium dioxide under the near ultraviolet (UV) irradiation. In this context, the photocatalytic degradation of isovaleraldehyde in gas phase is studied. In fact, the removal capacity is compared at different continuous reactors: a photocatalytic cylindrical reactor, planar reactor, and pilot unit. Results show that laboratory results can be useful for reactor design and scale-up. The flowrate increases lead to the removal capacity increases also. For example, with pilot unit, when flowrate extends four times, the degradation rate varies from 0.14 to 0.38 g h^?1 m_cat ^?2. The influence of UV intensity is also studied. When this parameter increases, zboth degradation rate and overall mineralization are enhanced. Moreover, the effects of inlet concentration, flowrate, geometries, and size of reactors on the removal capacity are also studied.     

Distinct diversity of the czcA gene in two sedimentary horizons from a contaminated estuarine core

In estuarine ecosystems, trace metals are mainly associated with fine grain sediments which settle on mudflats. Over time, the layers of sediments accumulate and are then transformed by diagenetic processes, recording the history of the estuary’s chemical contamination. In such a specific environment, we investigated to what extent a chronic exposure to contaminants could affect metal-resistant sedimentary bacteria in subsurface sediments. The occurrence and diversity of cadmium resistance genes (cadA, czcA) was investigated in 5- and 33-year-old sediments from a highly contaminated estuary (Seine France). Primers were designed to detect a 252-bp fragment of the czcA gene, specifically targeting a transmembrane helice domain (TMH IV) involved in the proton substrate antiport of this efflux pump. Although the cadA gene was not detected, the highest diversity of the sequence of the czcA gene was observed in the 5-year-old sediment. According to the percentage of identity at the amino acid level, the closest CzcA relatives were identified among Proteobacteria (α, β, γ, and δ), Verrucomicrobia, Nitrospirae, and Bacteroidetes. The most abundant sequences were affiliated with Stenotrophomonas. In contrast, in the 33-year-old sediment, CzcA sequences were mainly related to Rhodanobacter thiooxydans and Stenotrophomonas, suggesting a shaping of the metal-resistant microbial communities over time by both diagenetic processes and trace metal contamination.     

强化土著微生物处理硝基苯和苯胺污染地下水

以硝基苯、苯胺为主要污染物的污染地下水为研究对象,加入激活剂(乳糖、Na2HPO4、乳糖+Na2HPO4、乙醇、牛肉膏、蛋白胨)激活土著微生物,并考察其对土著微生物生长及硝基苯、苯胺降解效果的影响。加入激活剂3d后测各个水样的脱氢酶活性,对培养9d后的水样进行气相色谱/质谱(GC/MS)分析。结果表明,加入乳糖的水样中,其微生物相对增长率达157.2%,硝基苯、苯胺的相对去除率分别为14.90%和0.79%;加入Na2HPO4和乙醇的水样中,其微生物增长和硝基苯、苯胺降解情况均没有明显变化;加入乳糖+Na2HPO4的水样中,微生物相对增长率达180.3%,硝基苯、苯胺的相对去除率分别为24.20%和1.21%;加入牛肉膏的水样中,微生物的相对增长率为830.7%,硝基苯、苯胺的相对去除率分别为99.99%和99.67%;加入蛋白胨的水样中,其微生物相对增长率为686.0%,硝基苯、苯胺的相对去除率分别为99.33%和58.94%。GC/MS分析结果表明,加入激活剂后对氯苯胺、1-甲基-4-硝基苯等其他有机物的降解率均有提高。由此可见,通过激活土著微生物修复有机物污染地下水是可行的。     

紫外—荧光检测器高效液相色谱法测定PM2.5中16种多环芳烃

建立了一种利用高效液相色谱(HPLC)同时分离和测定大气颗粒物中16种优控多环芳烃(PAHs)的方法。样品经二氯甲烷超声提取,浓缩后经乙腈定容,以乙腈和水作为流动相进行反相HPLC梯度淋洗分离后,由紫外检测器串联程序波长荧光检测器检测。通过实验条件的优化,实现了16种PAHs组分基线完全分离和高灵敏度检测。16种PAHs检测限为0.05～1.20μg/L,回收率在75.0%～106.0%,相对标准偏差在0.27%～7.42%,均符合方法学的要求。将该方法用于测定贵阳市不同功能区PM2.5中PAHs的含量,具有快速简便、准确灵敏、重现性好等优点,适合大批量样品的分析。     

生态服务价值评价在山区城市土地规划中的应用——以万源市太平镇为例

生态系统服务价值的变化决定着区域的可持续发展,其评估已成为生态学研究的热点之一,其研究结果对维持地区生态平衡、合理利用土地资源、建立可持续的土地利用模式等具有重要意义。本文在综合已有研究的基础上,通过估算万源市太平镇不同海拔高度土地生态服务价值量,探讨经济发展与生态服务价值变化的关系。结果表明,城市规划区的自然生态系统服务功能的价值是不可忽视的,自然生态系统无论是从物质上还是经济上,都为万源市太平镇的国民经济和社会可持续发展提供者重要支撑。从生态系统服务功能角度,海拔750 m高程是太平镇城市用地扩张的控制线。     

高效藻类塘在污水处理中的研究及应用前景

高效藻类塘是在传统稳定塘的基础上发展起来的极具推广价值的污水处理技术。它具有停留时间短,水深浅,对氮磷的去除效果好的特点。本文阐述了高效藻类塘的特点、影响因素及去除机理,并展望了其应用前景。     

分级加荷条件下公路软基路堤沉降的预测方法

软土地基上修筑路堤多采用分级施工的方法。在传统双曲线沉降预测法的基础上，提出了软土地基上路堤分级施工情况下沉降预测的一个新模型，该模型考虑了土的非线性特性和固结性质随荷载的变化，可实现尽早预报沉降的要求。通过工程实例验证了所提模型的适用性。     

浅论大气环境管理重心由总量控制向质量改善转型

我国目前公众对大气环境污染问题的敏感度较高,全面改善空气环境质量业已成为重要的民生问题,并日益紧迫,为此必须在政策顶层设计上制定出科学合理的大气环境管理技术路线和系统有效的对策措施。本文在总结我国大气环境管理成功经验和分析未来大气环境质量面临的形势与挑战的基础上,提出我国大气环境管理重心必须由总量控制向质量改善转型以及相关对策措施:突破我国目前大气复合污染这一城市群社会经济发展的瓶颈,从环境管理体制等方面看,应重点做好以下工作:第一,在管理机制方面,构建"统一规划、统一监测、统一监管、统一评估、统一协调"的区域联防联控工作机制;第二,推行区域主要大气污染物排污权有偿使用与交易机制等制度;第三,建立起以空气质量改善为核心的总量控制方法,实施SO2、NOx、颗粒物、VOCs等多污染物的协同减排;第四,探索有利于联防联控的新机制和新模式。