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51.
- DOI: http://dx.doi.org/10.1065/espr2006.02.294
Background, Aim and Scope. To better address the requirements of the changing multilateral order, the United Nations Industrial
Development Organization (UNIDO) Cleaner Production Programme, in 2004, developed the new Sustainable Industrial Resource
Management (SIRM) approach. This approach is in accordance with the principles decided at the United Nations Conference on
Environment and Development (UNCED) in Rio de Janeiro, Brazil in 1992. Unlike the traditional approaches to environmental
management, the SIRM concept captures the idea of achieving sustainable industrial development through the implementation
of circular material and energy flows in the entire production chain and reduction of the amount of material and energy used
with greater efficiency solutions. The SIRM approach seeks to develop new models to encourage a shift from selling products
to supplying services, modifying, in this manner, the supplier/user relationship and resulting in a win-win situation for
the economy and the environment. Chemical Leasing represents such a new service-oriented business model and is currently being
promoted by UNIDO′s Cleaner Production Programme.
Main Features. One of the potential approaches to address the problems related to ineffective use and over-consumption of
chemicals is the development and implementation of Chemical Leasing business models. These provide concrete solutions to the
effective management of chemicals and on the ways negative releases to the environment can be reduced. The Chemical Leasing
approach is a strategy that addresses the obligations of the changing international chemicals policy by focusing on a more
service-oriented strategy. Mexico is one of the countries that were selected for the implementation of UNIDO's demonstration
project to promote Chemical Leasing models in the country. The target sector of this project is the chemical industry, which
is expected to shift their traditional business concept towards a more service and value-added approach. This is being achieved
through the development of company specific business models that implement the above-indicated Chemical Leasing concept with
the support from the Mexican National Cleaner Production Centre (NCPC).
Results and Conclusions. The implementation of Chemical Leasing in Mexico has proven to be an efficient instrument in enhancing
sustainable chemical management and significantly reducing emissions in Mexico. Several companies from the chemical industrial
sector implement or agreed to implement chemical leasing business models. Based on the positive findings of the project,
several Mexican companies started to negotiate contents of possible Chemical Leasing contracts with suitable business partners.
The project further aimed at disseminating information on Chemical Leasing. It successfully attracted globally operating companies
in the chemicals sector to explore possibilities to implement Chemical Leasing business models in Mexico. At the international
level, the results of the UNIDO project were presented on 20TH September 2005 during a side event of the Strategic Approach
to International Chemicals Management (SAICM) Preparation Conference in Vienna.
Recommendations and Outlook. To facilitate the promotion and application of Chemical Leasing project at international level,
UNIDO is currently developing a number of tools to standardize Chemical Leasing projects. These include, among others, Chemical
leasing contract models; Chemical Leasing data base to find partners for chemical leasing; and guidelines to implement Chemical
Leasing projects and work programmes. 相似文献
52.
53.
54.
Mary Ann Rozance Diana Denham Sarah Kidd 《Journal of Environmental Policy & Planning》2020,22(3):413-427
ABSTRACTThe success of ecological restoration efforts is tightly coupled with the effectiveness of many U.S. environmental policies. Yet scholars have raised questions about the ability of restoration to produce intended results. We use a case study of tidal wetland restoration planning in Oregon to examine how neoliberal environmental governance exercises influence through a set of knowledge politics that produces subpar outcomes. We present three main findings: (1) restoration policies produce a restoration economy based on a conception of wetland as commodity (2) practitioners in this restoration economy exhibit competitive behavior resulting in a piecemeal rather than a landscape approach to restoration; and (3) limited monitoring prevents changes to existing policies. Practitioners offer insight into the challenge of treating wetlands as a commodity and call for more monitoring to challenge the assumptions of hegemonic knowledge practices that reinforce a neoliberal environmental governance regime. The divergent ideas of reflexive practitioners, though not yet manifest as action, show where changes to restoration governance might be possible. 相似文献
55.
Mercury in fish from African lakes 总被引:1,自引:0,他引:1
Karen Kidd 《Natural resources forum》2005,29(2):177-178
56.
Rožič PŽ Dolenec T Baždarić B Karamarko V Kniewald G Dolenec M 《Environmental science and pollution research international》2011,19(7):2708-2721
Introduction and purpose
Studies examining the environmental impact of marine aquaculture have increased significantly in number during the last few decades. The present paper investigates a region of rapid growth in intensive aquaculture and its influence on the local marine ecosystem.Discussion
This study was undertaken with the specific aim of assessing the effect of fish farming on marine sediment at a farm near the island of Vrgada in the Central Adriatic. Data obtained regarding major (Si, Al, K, Na, Fe, Ca, Mg), minor (Mn, P, Ti) and trace (As, Au, Ba, Cd, Co, Cr, Cs, Cu, Ga, Hf, Hg, Mo, Nb, Ni, Pb, Rb, Sb, Sc, Se, Sr, Ta, Th, Tl, U, V, Y, Zn, Zr) elements were used to estimate the spatial and temporal distribution of metals in the sediment and their possible relationship with local aquacultural activity.Results
Although the measured concentrations of heavy metals in sediment below fish cages were notably different and potentially a result of farming activity, the values were generally lower than background concentrations observed in the Central Adriatic. In contrast, concentrations of heavy metals at a reference site unaffected by aquaculture varied from lower levels to values even higher than those observed below the high-production cages. Furthermore, calculated environmental index values indicate that the sediment below the farm is either uncontaminated or suffers from only low levels of contamination.Conclusion
Such results suggest that the effect of observed fish farm activity on the local marine ecosystem is practically negligible. 相似文献57.
Limitations for heavy metal release during thermo-chemical treatment of sewage sludge ash 总被引:1,自引:0,他引:1
Nowak B Perutka L Aschenbrenner P Kraus P Rechberger H Winter F 《Waste management (New York, N.Y.)》2011,31(6):1285-1291
Phosphate recycling from sewage sludge can be achieved by heavy metal removal from sewage sludge ash (SSA) producing a fertilizer product: mixing SSA with chloride and treating this mixture (eventually after granulation) in a rotary kiln at 1000 ± 100 °C leads to the formation of volatile heavy metal compounds that evaporate and to P-phases with high bio-availability. Due to economical and ecological reasons, it is necessary to reduce the energy consumption of this technology. Generally, fluidized bed reactors are characterized by high heat and mass transfer and thus promise the saving of energy. Therefore, a rotary reactor and a fluidized bed reactor (both laboratory-scale and operated in batch mode) are used for the treatment of granulates containing SSA and CaCl2. Treatment temperature, residence time and - in case of the fluidized bed reactor - superficial velocity are varied between 800 and 900 °C, 10 and 30 min and 3.4 and 4.6 m s−1. Cd and Pb can be removed well (>95 %) in all experiments. Cu removal ranges from 25% to 84%, for Zn 75-90% are realized. The amount of heavy metals removed increases with increasing temperature and residence time which is most pronounced for Cu.In the pellet, three major reactions occur: formation of HCl and Cl2 from CaCl2; diffusion and reaction of these gases with heavy metal compounds; side reactions from heavy metal compounds with matrix material. Although, heat and mass transfer are higher in the fluidized bed reactor, Pb and Zn removal is slightly better in the rotary reactor. This is due the accelerated migration of formed HCl and Cl2 out of the pellets into the reactor atmosphere. Cu is apparently limited by the diffusion of its chloride thus the removal is higher in the fluidized bed unit. 相似文献
58.
Spatial distribution of trace metals in the Krka River, Croatia: an example of the self-purification 总被引:2,自引:0,他引:2
The spatial distribution of dissolved and total trace metals (Zn, Cd, Pb and Cu) in the Krka River (partly located in the Krka National Park) has been studied using a "clean" sampling, handling and analysis technique. Differential pulse anodic stripping voltammetry (DPASV) with a hanging mercury drop electrode (HMDE) has been used for trace metal analysis. The Krka River has been divided into the upper and lower flow region with respect to the metals concentration and main physico-chemical parameters. A significant increase in trace metal concentration as the result of the untreated waste water discharge downstream of Knin Town has been registered in the upper flow region. Due to a specific characteristic of the Krka, the so-called self-purification process, a decrease in the elevated trace metals concentration from the water column takes place at numerous small lakes formed by tufa barriers (at the end of the upper flow region). The clean groundwater input at the beginning of the lower flow region additionally contributes to the observed decrease in trace metals concentration in the Krka, maintaining them at a very low level in the remaining region of fresh-water flow. The determined median total concentrations were zinc 120-7400 ng l(-1), cadmium 3-8 ng l(-1), lead 11-250 ng l(-1) and copper 110-440 ng l(-1). Karst rivers, such as the Krka River, with extremely low natural concentrations of trace metals are highly sensitive to the anthropogenic influence. Therefore, such aquatic systems require implementation of strict protection regimes in the entire catchments area. 相似文献
59.
Veltman K Huijbregts MA Vijver MG Peijnenburg WJ Hobbelen PH Koolhaas JE van Gestel CA van Vliet PC Hendriks AJ 《Environmental pollution (Barking, Essex : 1987)》2007,146(2):428-436
The mechanistic bioaccumulation model OMEGA (Optimal Modeling for Ecotoxicological Applications) is used to estimate accumulation of zinc (Zn), copper (Cu), cadmium (Cd) and lead (Pb) in the earthworm Lumbricus rubellus. Our validation to field accumulation data shows that the model accurately predicts internal cadmium concentrations. In addition, our results show that internal metal concentrations in the earthworm are less than linearly (slope<1) related to the total concentration in soil, while risk assessment procedures often assume the biota-soil accumulation factor (BSAF) to be constant. Although predicted internal concentrations of all metals are generally within a factor 5 compared to field data, incorporation of regulation in the model is necessary to improve predictability of the essential metals such as zinc and copper. 相似文献
60.
A model is described that may help to resolve uncertainty and controversy over the long-term consequences of sludge applications to arable land, especially with regard to the effects of sludge adsorption characteristics on trace metal solubility and bioavailability (e.g., the sludge "time bomb" or sludge "protection" hypotheses). Mass balances of organic and inorganic material derived from sludge and crop residues are simulated. Each pool has a potentially different adsorption affinity for trace metals, and this leads to changes in the adsorption capacity of sludge-amended soil that influence leaching and crop uptake. Model simulations were compared with measured changes in organic carbon and ethylenediaminetetraacetic acid (EDTA)-extractable cadmium contents in a clay loam soil following 41 years of sludge applications. The model adequately reproduced the data, although discrepancies in the vertical distribution of Cd were attributed to the effects of macropore transport and root-uptake driven recirculation. A Monte Carlo sensitivity analysis demonstrated that the most important parameters affecting leaching and crop uptake were the Cd loading and parameters controlling adsorption, especially the partition coefficient for sludge-derived inorganic material and the exponent regulating the effect of pH on sorption. Scenario simulations show that no general conclusions can be drawn with respect to the validity of the sludge "time bomb" and sludge "protection" hypotheses. Either may occur, or neither, depending on three key system parameters: the ratio of sludge adsorption capacity to the initial adsorption capacity of the soil, the proportion of the sludge adsorption capacity contributed by the inorganic fraction, and the sludge Cd loading. 相似文献