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101.
Results of 2 years monitoring of 210Po and 210Pb activity concentrations in soft tissue of the species Mytilus galloprovincialis from Croatian part of the Adriatic coast are presented. The samples were collected at thirteen coastal stations (some of which are also a part of the Mediterranean Mussel Watch Project) in spring and autumn of 2010 and 2011. The collected mussels were ranging between 4 cm and 6 cm in shell length. After sample pre-treatment lead and polonium were radiochemically separated on Sr resin. 210Po was determined by alpha-particle spectrometry and 210Pb was determined, via 210Bi, by a low-level gas proportional counter. The results of 210Po activity concentrations were found to vary between (104 ± 11) and (1421 ± 81) Bq kg−1 dry weight while 210Pb activity concentrations were much lower and in range (8.2 ± 5.3)–(94.1 ± 29.8) Bq kg−1 dry weight. Higher 210Po and 210Pb activity concentrations were determined in spring period. The inter-site differences seen in their activity concentrations can be due to natural background levels of sites. The 210Po/210Pb activity concentration ratios in all cases exceeded unity for all mussel samples and ranged between 4.0 and 47.9. 相似文献
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103.
Photocatalytic degradation of gaseous toluene by using immobilized titania/silica on aluminum sheets
Minoo Tasbihi Marko Kete Ashok M. Raichur Nata?a Novak Tu?ar Ur?ka Lavren?i? ?tangar 《Environmental science and pollution research international》2012,19(9):3735-3742
Purpose
The aim of this study was to prepare a highly active immobilized titania/silica photocatalyst and to test its performance in situ toward degradation of toluene as one of the major toxic indoor contaminants.Methods
In this work, two different titania layers immobilized on Al sheets were synthesized via low temperature sol?Cgel method employing presynthesized highly active titania powders (Degussa P25 and Millennium PC500, mass ratio 1:1): (a) with a silica/titania binder and a protective layer and (b) without the binder. The photocatalysts were characterized by X-ray diffraction, nitrogen sorption measurements, scanning electron microscopy (SEM), infrared spectroscopy, and UV?Cvis diffuse reflectance spectroscopy (DRS). The in situ photocatalytic degradation of gaseous toluene was selected as a probe reaction to test photocatalytic activity and to verify the potential application of these materials for air remediation.Results
Results show that nontransparent highly photocatalytically active coatings based on the silica/titania binder and homogeneously dispersed TiO2 powders were obtained on the Al sheets. The crystalline structure of titania was not altered upon addition of the binder, which also prevented inhomogeneous agglomeration of particles on the photocatalyst surface. The photoactivity results indicate that the adsorption properties and photocatalytic activity of immobilized photocatalysts with the silica/titania binder and an underlying protective layer were very effective and additionally, they exhibited considerably improved adhesion and uniformity.Conclusion
We present a new highly photocatalytically active immobilized catalyst on a convenient metallic support, which has a potential application in an air cleaning device. 相似文献104.
Bolanča Tomislav Strahovnik Tomislav Ukić Šime Stankov Mirjana Novak Rogošić Marko 《Environmental science and pollution research international》2017,24(19):16172-16185
Environmental Science and Pollution Research - This study describes the development of tool for testing different policies for reduction of greenhouse gas (GHG) emissions in energy sector using... 相似文献
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Monique Liesenjohann Thilo Liesenjohann Lenka Trebaticka Marko Haapakoski Janne Sundell Hannu Ylönen Jana A. Eccard 《Behavioral ecology and sociobiology》2011,65(11):2079-2089
Indirect exploitative competition, direct interference and predation are important interactions affecting species coexistence.
These interaction types may overlap and vary with the season and life-history state of individuals. We studied effects of
competition and potential nest predation by common shrews (Sorex araneus) on lactating bank voles (Myodes glareolus) in two seasons. The species coexist and may interact aggressively. Additionally, shrews can prey on nestling voles. We studied
bank vole mothers’ spatial and temporal adaptations to shrew presence during summer and autumn. Further, we focused on fitness
costs, e.g. decreased offspring survival, which bank voles may experience in the presence of shrews. In summer, interference
with shrews decreased the voles’ home ranges and they spent more time outside the nest, but there were no effects on offspring
survival. In autumn, we found decreased offspring survival in enclosures with shrews, potentially due to nest predation by
shrews or by increased competition between species. Our results indicate a shift between interaction types depending on seasonal
constraints. In summer, voles and shrews seem to interact mainly by interference, whereas resource competition and/or nest
predation by shrews gain importance in autumn. Different food availability, changing environmental conditions and the energetic
constraints in voles and shrews later in the year may be the reasons for the varying combinations of interaction types and
their increasing effects on the inclusive fitness of bank voles. Our study provides evidence for the need of studies combining
life history with behavioural measurements and seasonal constraints. 相似文献
108.
Electromagnetic therapy devices designed over the last 45 years have been based on empirical (trial-and-error) techniques.
This paper presents a novel approach to designing and engineering therapeutic devices. Based upon using a superconductive
quantum interference device (SQUID) magnetometer for registration of the magnetic field emitted by specific organs in norm
and after the injury/pathology, this approach avoids empirical engineering. The signal parameters recorded by the SQUID magnetometer
allow one to derive tissue- and/or disease-specific signals. This is made possible using contemporary, state-of-the-art controls
with engineering and computer science techniques. 相似文献
109.
In this paper we study optimal harvesting of the Norwegian spring-spawning herring stock. The biological model is described
by a discrete time age-structured model. The optimal harvesting patterns are studied numerically and the results show that
when using a linear cost function and constant price in the optimisation model, the optimal harvesting pattern is pulse fishing.
However, optimal constant fishing effort gives only slightly lower profit. Moreover, when price is made responsive to harvest
the optimal harvesting strategy is substantially smoothed.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
110.
Association of bound residues to soil humic matter may be accomplished by different binding mechanisms such as sequestration in hydrophobic interiors of the organic material or covalent linkage to the organic matter. The structures and chemical environments of compounds can be observed by NMR spectroscopy. We applied 15N-NMR spectroscopy to study the soil-bound residues of 15N-labeled simazine. As the 15N-isotope has a low sensitivity and natural abundance 15N-NMR experiments require long measurement times and often result in low signal-to-noise (S/N) ratios. Therefore, in addition to the use of 15N-labeled simazine, 15N-depleted compost was used to reduce the amount of background signal and enhance the sensitivity. The compost was produced from maize and wheat plants grown on sand with 15N-depleted NH4NO3 as sole nitrogen source. The plants were freeze-dried, ground and mixed with sand for composting. After a composting period of 224 days analysis of the compost revealed a 15N-content of 267 ppm as opposed to a natural abundance of 3650 ppm. Characterization of this artificial compost produced parameter values similar to those of a natural compost. The 13C-NMR-spectra of the humic and fulvic acids during different stages of maturity showed that there was a shift from single-bond functional groups to more complex double-bond and aromatic structures. Experiments with this compost showed an increased signal intensity. The improved sensitivity made it possible to obtain interpretable NMR signals in contrast to experiments with 15N-simazine on native soil where no signals were detectable. The data indicated that the bound residues of simazine are composed of metabolites resulting from N-dealkylation and triazine ring destruction. Silylation of the bound residues showed a very strong binding of the residues to the matrix as only a small fraction could be solubilized. 相似文献