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Cootes Paradise is a coastal wetland, adjacent to Hamilton Harbour at the western tip of Lake Ontario. The marsh has been considerably degraded due to the excessive sediment and nutrient input from sewage treatment plants (STPs), marsh tributaries and Combined Sewer Overflows (CSOs). Although there has been reduction in nutrient loadings from external sources, high nutrient levels, and a prolific algal growth remain a problem in Cootes Paradise. To assess the importance of external versus internal nutrient loadings to the marsh, nutrient fluxes from sediments were estimated using porewater profiles at three locations from 2001 and five additional sites from 2002. The fluxes varied between 0.27 and 5.25 mg P m−2 day−1, with sites receiving outfalls of STP and CSO having highest fluxes (∼5 mg P m−2 day−1). Mean phosphorus release rate of 2.02 mg P m−2 day−1 was calculated from the spatial distribution of the non-apatite inorganic phosphorus (NAI-P) in sediments, employing a relationship between the NAI-P and P fluxes. The results confirm that sediment P geochemistry is important in regulating the P pool in porewater which, consequently, governs the P fluxes from sediments.  相似文献   
174.
We report the diagnosis of amnion rupture sequence made by sonography and fetoscopy during the first trimester of gestation in a case of missed abortion. The investigation revealed a demised fetus with the characteristics of 9 weeks of development. The early fetus had an amnion adhesion at the tip of the nose and strands of amnion wrapped around the terminal phalanges of both feet. No defects in addition to the face and limb involvement were identified. The karyotype was normal: 46,XX. In the reported case, fetoscopy allowed confirmation of the sonographic diagnosis of an amnion rupture sequence in the first trimester of gestation and consequently helped to clarify the cause of abortion in this case of early fetal demise. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   
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We examined the effect of instream large wood on denitrification capacity in two contrasting, lower order streams — one that drains an agricultural watershed with no riparian forest and minimal stores of instream large wood and another that drains a forested watershed with an extensive riparian forest and abundant instream large wood. We incubated two types of wood substrates (fresh wood blocks and extant streambed wood) and an artificial stone substrate for nine weeks in each stream. After in situ incubation, we collected the substrates and their attached biofilms and established laboratory‐based mesocosm assays with stream water amended with 15N‐labeled nitrate‐N. Wood substrates at the forested site had significantly higher denitrification than wood substrates from the agricultural site and artificial stone substrates from either site. Nitrate‐N removal rates were markedly higher on woody substrates compared to artificial stones at both sites. Nitrate‐N removal rates were significantly correlated with biofilm biomass. Denitrification capacity accounted for only a portion of nitrate‐N removal observed within the mesocosms in both the wood controls and instream substrates. N2 accounted for 99.7% of total denitrification. Restoration practices that generate large wood in streams should be encouraged for N removal and do not appear to generate high risks of instream N2O generation.  相似文献   
177.
Total TEQ emissions (PCDD/F and PCB) from industrial sources   总被引:3,自引:0,他引:3  
Luthardt P  Mayer J  Fuchs J 《Chemosphere》2002,46(9-10):1303-1308
Flue gas samples from eight different sources (industrial plants and crematories) have been analyzed for PCDD/Fs and PCBs and total Toxicity EQuivalents (TEQ) values have been calculated using the latest WHO toxicity equivalent factors from 1998. A contribution of PCBs to the Total TEQ up to 16% was found, within the 12 WHO-PCBs PCB-126 contributes mostly to the TEQ. Thermodynamic stability of PCBs was calculated semiempirically using the MOPAC program package and differences in the heat of formation (HoF) were compared to the distribution of PCBs in real samples. Partial correspondence between fact and theory could be found.  相似文献   
178.
Due to environmental constraints and reactive water management practices, water shortages exist across the Everglades ecosystem. A growing human population and continued wetlands damage and loss decrease the system's ability to provide water for sustained natural areas and for human uses. 'The Restudy' is an $8 billion plan to restore the Everglades while also continuing to provide water storage for urban and agricultural areas. The Restudy proposes a mix of water storage systems to provide for the predicted future growth in water demand. This mix is purported to be the most cost-efficient at providing water supplies, within the constraints of unchanged agricultural and urban land use. However, a sensitivity analysis of the Restudy's cost equation reveals that the total cost of water storage systems is influenced by real estate, land acquisition and water treatment costs. The interaction of land use and agricultural policies can affect these cost factors, and can change the relative cost-efficiency between storage systems. Real estate and land acquisition costs are affected by several 1996 Farm Bill provisions, which influence the cost of aboveground water storage systems versus Aquifer Storage and Recovery systems. The Governor's Commission for a Sustainable South Florida recommendations also influence the water storage options available to the Restudy. Due to the Restudy's initial assumptions and constraints, it may not advocate the most economically and ecologically sound remediation.  相似文献   
179.
Conventional electron microscopy has significantly contributed to the understanding of structure-function relationships in living systems on cellular and macromolecular levels. New approaches and strategies will provide further insight into the organization of life. These new developments include cryopreparation and imaging techniques, X-ray microanalysis on frozen samples, electron energy loss spectroscopy, electron spectroscopic imaging, electron microscopic immunocytochemistry, preparation and imaging of ordered two-dimensional arrays of macromolecules, and computer image analysis and reconstruction. The techniques are described. Selected examples illustrate potential and limitations of these approaches and strategies.  相似文献   
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