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51.
Maria Grazia Gnoni Paolo A. Bragatto 《Journal of Loss Prevention in the Process Industries》2013,26(4):751-758
Major Accident Hazard (MAH) and Occupational Safety and Health (OSH) are two separated topics in both industrial practice and legislation; recently, interest is increasing toward an integrated risk assessment mainly forced by the tendency to a more efficient safety management system. The present study proposes a semi-quantitative approach to integrate MAH in OSH risk assessment. The two risk types are characterized by opposite features: the OSH analysis is usually task-based and focused on job profiles, while the MAH analysis is space-based and focused on plant characteristics. The basic idea of the proposed approach is to merge spatial information and job profile features in order to improve OSH assessment; thus, a risk index derived by the recent standard ISO 12100 (2010) has been adapted. In detail, the proposed index combines exposure times of each worker at each plant unit – derived from the OSH analysis – with damage areas derived from MAH analysis allowing a quantitative assessment of the MAH risk level for each individual job profile. The model has been tested in a large petrochemical plant; several hypotheses have been developed in order to validate the model. Results have showed the potentiality of the proposed approach in providing a common and coherent representation of both MAH and OSH risks, according to job profiles and plant units. 相似文献
52.
This work presents an unconventional procedure for the recovery of spent Al-rich caustic soda solutions from the pickling of dies for the production of aluminium extrusions. Caustic soda was regenerated at roughly 70%, by precipitating aluminate, after addition of a silica source, in the form of zeolite A, a microporous material that is widely used in many technological sectors. It was shown that the process is reliable and can be repeated for several cycles, provided the concentration of the caustic soda solution is suitably restored. The by-product obtained, zeolite A, proved to be a high-grade material with performance as a cation exchanger and physical sorbent that is certainly comparable to that reported in literature (e.g., cation exchange capacity equal to 5.14 meq g(-1) vs. 5.48 meq g(-1) and water vapour adsorption capacity of 26.5% vs. 27.6% at 16 torr and 298 K). The economics of the process, although not examined yet, would appear generally favourable, considering that zeolite A is a valuable by-product which widely covers the costs for the recovery of the spent solutions. There are, therefore, significant prospects for the use of zeolite A, particularly as a builder in detergent formulation. 相似文献
53.
Anna Gagliardo Maria Savini Angelo De Santis Giacomo Dell’Omo Paolo Ioalè 《Behavioral ecology and sociobiology》2009,64(2):289-296
Some authors have proposed that homing pigeons are able to correct the error in orientation following a phase-shift treatment
by using the magnetic compass reference. They reported that clock-shifted pigeons bearing magnets display a greater deflection
compared to magnetically unmanipulated clock-shifted birds. However, this hypothesis tested by recording pigeons’ vanishing
bearings has led to contradictory results. The present study reports pigeons’ tracks recorded with a GPS and shows that clock-shifted
pigeons bearing magnets displayed a greater deviation through the whole route compared to the magnetically unmanipulated shifted
pigeons. Moreover, the analysis of the tracks shows that the birds belonging to both experimental groups stop in coincidence
with their subjective night. When re-starting their journey, the birds corrected the clock-shift induced error in orientation,
but the magnetically manipulated pigeons were less efficient in doing so. Our results are consistent with the hypothesis that
homing pigeons released from unfamiliar location re-orient after clock shift by using the magnetic compass. 相似文献
54.
Quantification of copepod gut content by differential length amplification quantitative PCR (dla-qPCR) 总被引:1,自引:0,他引:1
Christofer Troedsson Paolo Simonelli Verena Nägele Jens C. Nejstgaard Marc E. Frischer 《Marine Biology》2009,156(3):253-259
Quantification of feeding rates and selectivity of zooplankton is vital for understanding the mechanisms structuring marine
ecosystems. However, methodological limitations have made many of these studies difficult. Recently, molecular based methods
have demonstrated that DNA from prey species can be used to identify zooplankton gut contents, and further, quantitative gut
content estimates by quantitative PCR (qPCR) assays targeted to the 18S rRNA gene have been used to estimate feeding rates
in appendicularians and copepods. However, while standard single primer based qPCR assays were quantitative for the filter
feeding appendicularian Oikopleura dioica, feeding rates were consistently underestimated in the copepod Calanus finmarchicus. In this study, we test the hypothesis that prey DNA is rapidly digested after ingestion by copepods and describe a qPCR-based
assay, differential length amplification qPCR (dla-qPCR), to account for DNA digestion. The assay utilizes multiple primer
sets that amplify different sized fragments of the prey 18S rRNA gene and, based on the differential amplification of these
fragments, the degree of digestion is estimated and corrected for. Application of this approach to C. finmarchicus fed Rhodomonas marina significantly improved quantitative feeding estimates compared to standard qPCR. The development of dla-qPCR represents a
significant advancement towards a quantitative method for assessing in situ copepod feeding rates without involving cultivation-based
manipulation. 相似文献
55.
This study presents the results of experimental Fenton-like treatments conducted on marine sediment slurries (2g sediment vs. 20 ml liquid). The sediment was collected in a harbor situated in a high density industrial area, characterized by a great hydrocarbon C>12 and PAHs contamination. The investigated parameters were: the H(2)O(2) dose, the reagent's pH and the effect of a phosphate salt and ferrous iron addition. To evaluate sediment's characteristics COD, particle size, thermogravimetric and differential thermal analyses were performed under N(2) and O(2) atmosphere while dissolved organic carbon and COD analyses were performed on the filtrate. Results indicate that the treatment was able to change the organic matter to a less hydrophobic state, to destroy part of the organic carbon (up to 78% decrease of the 200-400 degrees C labile organic matter), to lower the COD of the sediment (60% COD removal maximum) and to increase the cumulated distribution undersize. In addition as the treated sediment showed easier-to-handle characteristics, reduced caking and lower aggregation capacity, the modified Fenton treatment could also be considered a pre-treatment of a successive thermal treatment. 相似文献
56.
de Zorzi P Barbizzi S Belli M Barbina M Fajgelj A Jacimovic R Jeran Z Menegon S Pati A Petruzzelli G Sansone U Van der Perk M 《Chemosphere》2008,70(5):745-752
In the frame of the international SOILSAMP project, funded and coordinated by the National Environmental Protection Agency of Italy (APAT), uncertainties due to field soil sampling were assessed. Three different sampling devices were applied in an agricultural area using the same sampling protocol. Cr, Sc and Zn mass fractions in the collected soil samples were measured by k(0)-instrumental neutron activation analysis (k(0)-INAA). For each element-device combination the experimental variograms were calculated using geostatistical tools. The variogram parameters were used to estimate the standard uncertainty arising from sampling. The sampling component represents the dominant contribution of the measurement uncertainty with a sampling uncertainty to measurement uncertainty ratio ranging between 0.6 and 0.9. The approach based on the use of variogram parameters leads to uncertainty values of the sampling component in agreement with those estimated by replicate sampling approach. 相似文献
57.
Environmental odours assessment from waste treatment plants: dynamic olfactometry in combination with sensorial analysers "electronic noses" 总被引:1,自引:0,他引:1
Littarru P 《Waste management (New York, N.Y.)》2007,27(2):302-309
After an overview about the criteria of odour nuisance in different technical laws, about electronic noses analysers and about dynamic olfactometry, in the present paper the authors describe an application of dynamic olfactometry in combination with the determinations of electronic noses. The coordination of the two approaches permits optimisation of the advantages offered by both methods to the measurable and objective evaluation of the odour nuisance from waste treatment plants and chemical plants. 相似文献
58.
A review on usnic acid,an interesting natural compound 总被引:1,自引:0,他引:1
Lichens are a world-widespread consortium of fungal and photosynthetic partners. Usnic acid is one of the most common and abundant lichen metabolites, well known as an antibiotic, but also endowed with several other interesting properties. This review summarises the most relevant studies on usnic acid, focusing on a number of biological activities in different fields. On the basis of the existing literature, usnic acid seems to be an exclusive lichen product. No synthetic derivatives more effective than the natural form are known. Both the (+) and (-) enantiomers of usnic acid are effective against a large variety of Gram-positive (G+) bacterial strains, including strains from clinical isolates, irrespective of their resistant phenotype. Of particular relevance is the inhibition of growth of multi-resistant strains of Streptococcus aureus, enterococci and mycobacteria. The (+)-usnic acid enantiomer appears to be selective against Streptococcus mutans without inducing perturbing side effects on the oral saprophyte flora. On the other hand, the (-)-usnic acid enantiomer is a selective natural herbicide because of its blocking action against a specific key plant enzyme. Other recognised characteristics of usnic acid are ultraviolet absorption and preserving properties. The toxicology, the in vitro anti-inflammatory effects and the mechanism of action of usnic acid need to be investigated in greater detail in order to reach clinical trials and to allow further applications. Furthermore, more research is needed to make possible intensive lichen culture, in order to produce large quantities of lichen substances for pharmaceutical, cosmetic and agricultural purposes. Some biological aspects, i.e. the possible biological roles of usnic acid, are discussed. 相似文献
59.
A method is proposed for ordering molecules on a scale of conformational rigidity on the basis of a parameter (the F number), which to a first approximation is evaluated with the three-states rotational isomeric-state scheme. Some particularly rigid paraffins are discussed.
相似文献60.