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351.
Vitte I Duran R Jézéquel R Caumette P Cravo-Laureau C 《Environmental science and pollution research international》2011,18(6):1022-1032
Purpose
We studied the effect of alternations of aeration on both the autochthonous bacterial communities from an oily sludge to the endogenous polycyclic aromatic hydrocarbons (PAH) biodegradation compared to a permanent oxic condition. 相似文献352.
The biogeochemical dynamics of 15 perfluorinated compounds (PFCs) were investigated in a heavily urbanised river (River Seine, Paris, France). The target compounds included C4-C10 sulfonates and C5-C14 acids; eleven PFCs were detected and ∑PFCs ranged between 31 and 91 ng L−1 (median: 47 ng L−1). The molecular pattern was dominated by the perfluoroalkyl sulfonates PFHxS and PFOS (>54% of ∑PFCs), which were the only PFCs quantified in both the dissolved and particulate phases. For these PFCs, the sorbed fraction positively correlated with suspended sediment levels. Total PFC levels negatively correlated with river flow rate, which varied between 150 and 640 m3 s−1. This suggests the predominance of point sources (likely WWTP effluent discharge), but a contribution of non-point sources such as combined sewer overflow could not be excluded. The annual PFC mass flow was estimated at 500 kg, which is less than observed for other large European rivers. 相似文献
353.
Marc-Andre Berube Diane Schorr Richard J. Ball Veronic Landry Pierre Blanchet 《Journal of Polymers and the Environment》2018,26(3):970-979
The development of wood treatments is of increasing industrial importance. A novel technique for improving the properties of lodgepole pine and white pine through modification of the microstructure is described. The present investigation is devoted to the synthesis and determination of in situ parameters of citric acid and glycerol based polymers for wood impregnation. This solvent free approach is environmentally friendly and achieved through an esterification condensation reaction under acidic conditions. Crude glycerol and citric acid reactants were cross-linked via a curing process at 160?°C creating a polymer with only water as the byproduct. The ester bonds and crosslinking levels were controlled using different catalysts and citric acid contents and related to the reaction time and temperature. The nature of bonding within the polymers and at the wood cell walls was determined by FT-IR analysis. The thermal properties such as glass transition temperature (Tg) were studied using TGA/DSC and the effect of citric acid content and catalyst type determined. Dimensional stability of impregnated wood samples improved above 50% for each sample with HCl and p-TSA catalysts compared to control samples. FTIR spectra were studied to show the presence of the ester linkages of the polymer in situ at the wood cell walls. Bonding between the polymer and wood macromolecules were observed by scanning electron microscopy and interpreted as evidence of chemical bonds at the wood cells. When prepared using a catalyst, the polymer was intimately incorporated into wood structure significantly improving the substrate dimensional stability. Enhanced stability makes this approach of particular interest for exterior wood products especially as a green renewable option for the wood industry. 相似文献
354.
Habran Sarah Crespin Pierre Veschkens Mathieu Remy Suzanne 《Environmental science and pollution research international》2020,27(6):5681-5692
Environmental Science and Pollution Research - In response to the Walloon Environment and Health Program, the Scientific Institute of Public Services (ISSeP) developed an integrated approach of... 相似文献
355.
Irina Gaus Pascal Audigane Laurent Andr Julie Lions Nicolas Jacquemet Pierre Durst Isabelle Czernichowski-Lauriol Mohamed Azaroual 《International Journal of Greenhouse Gas Control》2008,2(4):605
Geochemistry plays an important role when assessing the impact of CO2 storage. Due to the potential corrosive character of CO2, it might affect the chemical and physical properties of the wells, the reservoir and its surroundings and increase the environmental and financial risk of CO2 storage projects in deep geological structures. An overview of geochemical and solute transport modelling for CO2 storage purposes is given, its data requirements and gaps are highlighted, and its progress over the last 10 years is discussed. Four different application domains are identified: long-term integrity modelling, injectivity modelling, well integrity modelling and experimental modelling and their current state of the art is discussed. One of the major gaps remaining is the lack of basic thermodynamical and kinetic data at relevant temperature and pressure conditions for each of these four application domains. Real challenges are the coupled solute transport and geomechanical modelling, the modelling of impurities in the CO2 stream and pore-scale modelling applications. 相似文献
356.
Evaluation of a low-cost adsorbent for removal of toxic metal ions from wastewater of an electroplating factory 总被引:2,自引:0,他引:2
Francisco W. Sousa Marcelo James Sousa Isadora R.N. Oliveira Andr G. Oliveira Rivelino M. Cavalcante Pierre B.A. Fechine Vicente O.S. Neto Denis de Keukeleire Ronaldo F. Nascimento 《Journal of environmental management》2009,90(11):3340-3344
In this study, sugar cane residue or bagasse was used for removal of toxic metal ions from wastewater of an electroplating factory located in northeast Brazil. Prior acid treatment increased the adsorption efficacies in batch wise experiments. The microstructure of the material before and after the treatment was investigated by X-ray diffraction, infrared spectroscopy and scanning electron microscopy. Column operations showed that removals of Cu2+, Ni2+ and Zn2+ from wastewater (in the absence of cyanide) were 95.5%, 96.3.0%, and 97.1%, respectively. Regeneration of the adsorbent obtained in acid indicated that the efficiencies decreased only after the fourth cycle of re-use. Acid-treated sugar cane bagasse can be considered a viable alternative to common methods to remove toxic metal ions from aqueous effluents of electroplating industries. 相似文献
357.
Faucher K Fichet D Miramand P Lagardère JP 《Environmental pollution (Barking, Essex : 1987)》2008,151(1):148-157
The effect of chronic exposure to a low concentration (0.5 microg l(-1)) of cadmium ions was investigated on escape behaviour of sea bass, Dicentrarchus labrax, using video analysis. Observations were also performed on the microanatomy of lateral system neuromasts. When fish were exposed for 4h per day over 8 days to the cadmium ions, most of both types of neuromasts observed remained intact. However, some of them presented damaged sensory maculae. Whereas before cadmium exposure, fish responded positively to nearly all the lateral system stimulations, after exposure they decreased by about 10% their positive responses to stimulations. From the 15th day after the beginning of cadmium exposure, neuromasts presented progressively less damage, cadmium accumulation in gills and scales decreased significantly and fish escape behaviour had recovered. This study presents a new concept in ecotoxicology: using behavioural change to reveal the effects of pollution levels, scarcely detectable by currently used techniques (physiological responses). 相似文献
358.
Ozone risk assessment for plants: central role of metabolism-dependent changes in reducing power 总被引:2,自引:0,他引:2
Dizengremel P Le Thiec D Bagard M Jolivet Y 《Environmental pollution (Barking, Essex : 1987)》2008,156(1):11-15
The combination of stomatal-dependent ozone flux and total ascorbate level is currently presented as a correct indicator for determining the degree of sensitivity of plants to ozone. However, the large changes in carbon metabolism could play a central role in the strategy of the foliar cells in response to chronic ozone exposure, participating in the supply of reducing power and carbon skeletons for repair and detoxification, and modifying the stomatal mode of functioning. To reinforce the accuracy of the definition of the threshold for ozone risk assessment, it is proposed to also consider the redox pool (NAD(P)H), the ratio between carboxylases and the water use efficiency as indicators of the differential ozone tolerance of plants. 相似文献
359.
Massad RS Loubet B Tuzet A Cellier P 《Environmental pollution (Barking, Essex : 1987)》2008,154(3):390-403
The ammonia stomatal compensation point of plants is determined by leaf temperature, ammonium concentration ([NH4+]apo) and pH of the apoplastic solution. The later two depend on the adjacent cells metabolism and on leaf inputs and outputs through the xylem and phloem. Until now only empirical models have been designed to model the ammonia stomatal compensation point, except the model of Riedo et al. (2002. Coupling soil-plant-atmosphere exchange of ammonia with ecosystem functioning in grasslands. Ecological Modelling 158, 83-110), which represents the exchanges between the plant's nitrogen pools. The first step to model the ammonia stomatal compensation point is to adequately model [NH4+]apo. This [NH4+]apo has been studied experimentally, but there are currently no process-based quantitative models describing its relation to plant metabolism and environmental conditions. This study summarizes the processes involved in determining the ammonia stomatal compensation point at the leaf scale and qualitatively evaluates the ability of existing whole plant N and C models to include a model for [NH4+]apo. 相似文献
360.
Andreas Klumpp Wolfgang Ansel Gabriele Klumpp Jörn Breuer Philippe Vergne María José Sanz Stine Rasmussen Helge Ro-Poulsen Àngela Ribas Artola Josep Peñuelas Shang He Jean Pierre Garrec Vicent Calatayud 《Atmospheric environment (Oxford, England : 1994)》2009,43(2):329-339
Within a European biomonitoring programme, Italian ryegrass (Lolium multiflorum Lam.) was employed as accumulative bioindicator of airborne trace elements (As, Cd, Cr, Cu, Fe, Ni, Pb, Sb, V, Zn) in urban agglomerations. Applying a highly standardised method, grass cultures were exposed for consecutive periods of four weeks each to ambient air at up to 100 sites in 11 cities during 2000–2002. Results of the 2001 exposure experiments revealed a clear differentiation of trace element pollution within and among local monitoring networks. Pollution was influenced particularly by traffic emissions. Especially Sb, Pb, Cr, Fe, and Cu exhibited a very uneven distribution within the municipal areas with strong accumulation in plants from traffic-exposed sites in the city centres and close to major roads, and moderate to low levels in plants exposed at suburban or rural sites. Accumulation of Ni and V was influenced by other emission sources. The biomonitoring sites located in Spanish city centres featured a much higher pollution load by trace elements than those in other cities of the network, confirming previously reported findings obtained by chemical analyses of dust deposition and aerosols. At some heavily-trafficked sites, legal thresholds for Cu, Pb, and V contents in foodstuff and animal feed were reached or even surpassed. The study confirmed that the standardised grass exposure is a useful and reliable tool to monitor and to assess environmental levels of potentially toxic compounds of particulate matter. 相似文献