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91.
Sophie Grima Véronique Bellon-Maurel Pierre Feuilloley Françoise Silvestre 《Journal of Polymers and the Environment》2000,8(4):183-195
During the last few years, biodegradable polymers have been developed to replace petrochemical polymers. Until now, research devoted to these polymers essentially focused on their biodegradability. There is now a need to bear out their nontoxicity. To verify this, the biodegradation must be carried out in accelerated laboratory tests which allow the metabolites and residues to be recovered. To reproduce the natural conditions (compost, field) as closely as possible, degradation experiments must be run on solid-state substrates. We review studies of aerobic degradation in solid-state substrates. This article focuses in particular on the environmental, physical, and chemical parameters (such as substrate nature, moisture, temperature, C/N ratio, and pH) that influence biodegradation kinetics. This study also aims at finding the solid substrate most adapted to residues and metabolite recovery. The most significant parameters would appear to be the substrate type, moisture content, and temperature. Inert substrates such as vermiculite are well suited to residue extraction. This review also opens the field to new research aimed at optimizing conditions for aerobic solid-state biodegradation and at recovering the metabolites and residues of this degradation process. 相似文献
92.
Louis Hautier Jean-Claude Grégoire Jérôme de Schauwers Gilles San Martin Pierre Callier Jean-Pierre Jansen Jean-Christophe de Biseau 《Chemoecology》2008,18(3):191-196
Summary. Under laboratory conditions, the multicolored Asian lady beetle, Harmonia axyridis is well known as an intraguild predator of other ladybirds. However the real impact of this exotic species on native species
was poorly investigated in the field. Because many ladybird species produce alkaloids as defensive compounds, we propose here
a new method of intraguild predation monitoring in coccinellids based on alkaloid quantification by GC-MS. In laboratory experiments,
adaline was unambiguously detected in fourth instar larvae of H. axyridis having ingested one egg or one first instar larva of Adalia bipunctata. Although prey alkaloids in the predator decreased with time, traces were still detected in pupae, exuviae and imagines of
H. axyridis having ingested one prey when they were fourth instar larvae. Analysis of H. axyridis larvae collected in two potato fields shows for the first time in Europe the presence of exogenous alkaloids in 9 out of
28 individuals tested. This new method of intraguild predation detection could be used more widely to follow the interactions
between predators and potential chemically defended insect preys. 相似文献
93.
Accounting for rate instability and spatial patterns in the boundary analysis of cancer mortality maps 总被引:1,自引:0,他引:1
Pierre Goovaerts 《Environmental and Ecological Statistics》2008,15(4):421-446
Boundary analysis of cancer maps may highlight areas where causative exposures change through geographic space, the presence
of local populations with distinct cancer incidences, or the impact of different cancer control methods. Too often, such analysis
ignores the spatial pattern of incidence or mortality rates and overlooks the fact that rates computed from sparsely populated
geographic entities can be very unreliable. This paper proposes a new methodology that accounts for the uncertainty and spatial
correlation of rate data in the detection of significant edges between adjacent entities or polygons. Poisson kriging is first
used to estimate the risk value and the associated standard error within each polygon, accounting for the population size
and the risk semivariogram computed from raw rates. The boundary statistic is then defined as half the absolute difference
between kriged risks. Its reference distribution, under the null hypothesis of no boundary, is derived through the generation
of multiple realizations of the spatial distribution of cancer risk values. This paper presents three types of neutral models
generated using methods of increasing complexity: the common random shuffle of estimated risk values, a spatial re-ordering
of these risks, or p-field simulation that accounts for the population size within each polygon. The approach is illustrated
using age-adjusted pancreatic cancer mortality rates for white females in 295 US counties of the Northeast (1970–1994). Simulation
studies demonstrate that Poisson kriging yields more accurate estimates of the cancer risk and how its value changes between
polygons (i.e., boundary statistic), relatively to the use of raw rates or local empirical Bayes smoother. When used in conjunction
with spatial neutral models generated by p-field simulation, the boundary analysis based on Poisson kriging estimates minimizes
the proportion of type I errors (i.e., edges wrongly declared significant) while the frequency of these errors is predicted
well by the p-value of the statistical test.
相似文献
Pierre GoovaertsEmail: |
94.
Alletto L Benoit P Bergheaud V Coquet Y 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):678-688
Laboratory studies were conducted to evaluate the effects of temperature and water pressure head on the degradation of the diketonitrile metabolite (DKN) of isoxaflutole during 84 d in samples collected in a loamy soil under conventional (CT) and conservation (MT) tillage systems. Soil temperature was the major factor controlling DKN degradation in the two tillage systems. The shortest half-lives (T1/2) were measured in the seedbed samples under MT at 25 °C and −33 cm water pressure head. We found that mouldboard ploughing under CT was responsible for the spatial variability of herbicide degradation properties, whereas under MT herbicide degradation was associated to the vertical distribution of organic matter. 相似文献
95.
Biache C Mansuy-Huault L Faure P Munier-Lamy C Leyval C 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):671-677
To evaluate the efficiency and the influence of thermal desorption on the soil organic compartment, contaminated soils from coking plant sites (NM and H) were compared to their counterparts treated with thermodesorption. The extractable organic matter, and the metal content and distribution with soil compartments were studied.In both thermodesorbed soils, PAH (polycyclic aromatic hydrocarbon) degradation exceeded 90%. However, the thermal desorption led not only to a volatilization of the organic compounds but also to the condensation of extractable organic matter.The treatments only affected the Fe and Zn distribution within the more stable fractions, whereas the organic compound degradation did not affect their mobility and availability. 相似文献
96.
Removal of PCBs from wastewater using fly ash 总被引:23,自引:0,他引:23
Liquids and sludges containing polychlorinated biphenyls (PCBs) can be treated to concentrate the PCBs in a solid residue. The latter can then be handled to destroy the PCBs. A study on sorption kinetics of PCBs on fly ash was conducted in controlled batch systems. TCB and HeCB are removed at 25 degrees C by adsorption on fly ash up to 97% at pH 7, with an adsorbent dose of 5 g/l. An examination of the thermodynamic parameters shows that the adsorption of TCB and HeCB by fly ash is a process occurring spontaneously at ambient conditions. Activation energies for the sorption process ranged between 5.6 and 49.1 kJ/mol. It was observed that the rate at which TCB and HeCB are adsorbed onto fly ash showed a diffusion limitation. The uptake rate of TCB and HeCB increases with increasing initial concentration and gradually tends to a constant value. A decrease in the adsorption of TCB and HeCB was observed when interfering ions and other PCB congeners were present. Changing the pH in the aqueous solution from 2 to 10 had no effect on the adsorption process. Overall, fly ash can be used for an efficient removal of PCBs from several aqueous solutions. 相似文献
97.
Effects of age and sex ratios on offspring recruitment rates in translocated black rhinoceros 下载免费PDF全文
Jay V. Gedir Peter R. Law Pierre du Preez Wayne L. Linklater 《Conservation biology》2018,32(3):628-637
Success of animal translocations depends on improving postrelease demographic rates toward establishment and subsequent growth of released populations. Short‐term metrics for evaluating translocation success and its drivers, like postrelease survival and fecundity, are unlikely to represent longer‐term outcomes. We used information theory to investigate 25 years of data on black rhinoceros (Diceros bicornis) translocations. We used the offspring recruitment rate (ORR) of translocated females—a metric integrating survival, fecundity, and offspring recruitment at sexual maturity—to detect determinants of success. Our unambiguously best model (AICω = 0.986) predicted that ORR increases with female age at release as a function of lower postrelease adult rhinoceros sex ratio (males:females). Delay of first postrelease reproduction and failure of some females to recruit any calves to sexual maturity most influenced the pattern of ORRs, and the leading causes of recruitment failure were postrelease female death (23% of all females) and failure to calve (24% of surviving females). We recommend translocating older females (≥6 years old) because they do not exhibit the reproductive delay and low ORRs of juveniles (<4 years old) or the higher rates of recruitment failure of juveniles and young adults (4–5.9 years old). Where translocation of juveniles is necessary, they should be released into female‐biased populations, where they have higher ORRs. Our study offers the unique advantage of a long‐term analysis across a large number of replicate populations—a science‐by‐management experiment as a proxy for a manipulative experiment, and a rare opportunity, particularly for a large, critically endangered taxon such as the black rhinoceros. Our findings differ from previous recommendations, reinforce the importance of long‐term data sets and comprehensive metrics of translocation success, and suggest attention be shifted from ecological to social constraints on population growth and species recovery, particularly when translocating species with polygynous breeding systems. 相似文献
98.
The urban fringe is recognized as the arena of many conflicts involving land uses and values. The development and operation of hazardous waste facilities give rise to numerous conflicts and confrontations. An analysis of three cases in Montreal's rural-urban fringe based on a review of articles in the regional press demonstrates the utility of a common conceptual framework based on the awareness cycle which is represented in five phases. The application of the sustainable development concept to the hazardous wastes issue requires adopting approaches emphasizing participation of all the actors and interests involved, right from project design to the closure and dismantling of the facility. The fundamental challenge is that of promoting the excellence of the various stakeholders in terms of the quality of their participation in order to achieve sustainable acceptability of the project, often in a modified form compared to its initial conception.Dr Pierre André is Assistant Professor and Dr Christopher R. Bryant is Full Professor in the Département de Géographie, Université de Montreal. Romain Coté has completed an MSc degree in the Hygiène du milieu et de l'environnement programme at the Université de Montreal. 相似文献
99.
In revegetation trials on disturbed riverbank sites in the Montréal region (Québec, Canada), an analysis of their structure by means of their biotic and abiotic components was undertaken. Vegetation sampling and physical surveys, together with soil analyses of 62 stands, grouped in 20 sectors, were carried out in the summer of 1986. The statistical analyses of biotic and abiotic data were executed in parallel by a hierarchical agglomerative cluster analysis (arithmetic average clustering) and by an ordination in reduced space (principal coordinate analysis). The species colonizing these riverbanks are, for the most part, ruderals from the Montréal region, of which more than 50% are introduced species. The pioneering communities characterizing these artificial habitats have had very little impact on the physical conditions of their environment; therefore, the ordination on the plant communities proves to be strongly correlated to the ordination stemming from the abiotic components. The statistical analysis retains the original sectors, underlining the fact that each human intervention generally results in the creation of a particular ecological situation. 相似文献
100.
Annie Tissot Pierre Boule Serge Lambert Jacques Lemaire Jean-Claude Palla 《Chemosphere》1985,14(9):1221-1230
A test of acute toxicity on DAPHNIA MAGNA is suggested to evaluate the efficiency of the phototransformation as a route of abiotic degradation. This test is recommended for compounds phototransformed into a complex mixture of products. Hydroquinone, 2-chloro-, 4-chloro-, 2,4-dichloro-, 2,4,6-trichloro- and pentachlorophenol were studied as examples. In any case the phototransformation is an useful depollution technique on condition the irradiation to be completed as far as the ultimate step of phototransformation. 相似文献