Accumulation of Heavy Metals in Epiphytic Lichens Near a Municipal Solid Waste Incinerator (Central Italy)

The epiphytic lichen Parmelia caperata was usedas biomonitor in the area of a municipal solid wasteincinerator (Poggibonsi, central Italy) to investigatethe levels and the spatial distribution of the heavymetals Al, Cd, Cr, Cu, Fe, Hg, Pb and Zn. Levels ofAl, Cu and Hg were similar to those in unpollutedareas, whereas high values were found for Cr, Zn andespecially Cd. The distribution pattern of the lastthree metals and the exponential relationship of theirconcentrations with distance from the incinerator,showed that the disposal plant is a local source ofatmospheric pollution due to Cd, Cr and Zn. For thesemetals, long-term hazard should be seriously taken into account.     

Application of Defined Co-Immobilized Microbial Consortium as a Ready-to-Use Seed Inoculum in Bod Analysis

A number of microorganisms were isolated from sewage. Biochemical Oxygen Demand (BOD-5 day) analysis was carried out by individual pure cultures. The cultures giving higher or equal BOD values as compared to reference GGA solution were selected for the formulation of a defined mixed microbial consortium. This microbial consortium was co-immobilized on calcium-alginate beads. Four synthetic and six industrial samples were tested for BOD by using immobilized beads as well as sewage as source of seeding materials. BOD values obtained with beads for all the synthetic as well as industrial samples were fairly comparable with those obtained with sewage. Reusability of prepared microbial beads was also checked with different synthetic and industrial samples and was compared with reference GGA solution. The same microbial beads can be reused three times for different BOD-5 day estimations. It is recommended that immobilized microbial beads can be used as a ready-to-use seeding material for BOD analysis.     

Inputs of chemicals from recreational activities into the Norwegian coastal zone

Wastewater treatment works effluent is often considered to be one of the most important point sources of a wide range of anthropogenic contaminants to aquatic systems, however, this paper discusses other potential sources. With the aim of establishing the important sources of UV filters, insect repellent and biocides to the aquatic environment, samples were collected from sites with direct (bathing areas and marinas) and indirect (sites receiving wastewater effluent) human influences. Sunscreens containing UV filters are used in large volumes during the summer months and often applied shortly before a person enters the water for swimming activities. The results presented here demonstrate that washing directly from the skin is an important point source of 4 UV filters to the Oslofjord. The insect repellent, diethyl toluamide, was also measured and it was concluded that washing from the skin was not such an important point source into the fjord. Concentrations of the biocide Irgarol 1051 were also measured and were elevated in the small boat marina and surrounding enclosed area. This work demonstrates that man recreational water-based activities are a diffuse source of some contaminants into coastal and fjord environments and this study provides an initial assessment of the levels being released.     

Identification and quantification of microcystins from a Nostoc muscorum bloom occurring in Oukaïmeden River (High-Atlas mountains of Marrakech, Morocco)

Atmospheric BTEX [benzene, toluene, ethylbenzene, o-xylene and (m + p)-xylene] concentrations have been determined in the Naples metropolitan area (NMA) and in two suburban areas located on the north within about 25 km, during 2006. The pollutants were collected by passive samplers (24-h samplings), and analysed by GC-MS. In all the areas analysed the average atmospheric benzene concentrations were higher than the limit value fixed by the European Union for 2010 and in NMA the average concentration (9.8 microg m(-3)) also exceeded the limit fixed for 2006. High linear correlation coefficients between the average daily concentrations of the different BTEX are indicative of a single major source, most likely the vehicular traffic. The temporal and spatial distribution of BTEX relative concentrations suggest that massive emissions in NMA negatively affect the quality of the air in northern suburban areas, prevalently during the hottest months of the year, probably due to transport by local seasonal winds. The ratios between BTEX daily concentrations showed a clear dependence on the intensity of solar actinic flow, indicating a major role of photochemical processes in the air cleaning from these volatile organic pollutants.     

Kinetics of sorption of lead on bed sediments of River Hindon, India

A number of low cost waste sorbent have been used for removal of heavy metals, however, few studies have been carried out on the sorption process on riverbed sediments in their natural state of occurrence. Stream sediments adsorb certain solutes from streams, thereby significantly changing the solute composition, but little is known about quantitatively describing sorption phenomena and rates of these processes. In the present investigation, sorption of lead ions on river bed sediments of river Hindon, a tributary of river Yamuna, India has been studied to demonstrate the role of bed sediments in controlling metal pollution. The effect of various operating variables, viz., initial concentration, solution pH, sediment dose, contact time and particle size has been studied. The sorption of lead ions increased with respect to pH and sorbent dose and decreased with sorbent particle size. Two important geochemical phases, iron and manganese oxide, also play important role in the sorption process. The sorption data were analysed using Langmuir and Freundlich isotherm models to determine the mechanistic parameters related to the sorption process. Further, although lead ions have more affinity for the fine fraction of the sediment, but the overall contribution of coarser fraction to sorption is more as compared to clay and silt fraction. The kinetic data suggest that the sorption of lead on bed sediments is an endothermic process, which is spontaneous at low temperature. The uptake of lead is controlled by both bulk and intraparticle diffusion mechanism.     

Cover estimation versus density counting in species-rich pasture under different grazing intensities

Two methods for monitoring of grassland vegetation were compared: visual estimation of plant cover (C) and plant densities counting (D). C and D were performed in monthly intervals for three vegetation growing seasons after imposing different grazing regimes on abandoned grassland in 1998. Species scores obtained from paired redundancy analyses (RDA) of C and D data were compared and Spearman's rank correlations were used to show if the two methods give comparable results. Results of C and D were highly correlated in the first two growing seasons only. In the third season, correlation was substantially lower as the sward structure was more heterogeneous due to creation of differently defoliated patches especially under extensive grazing. Presence of the same plant species with different habit in frequently and in infrequently grazed patches, reduced significance of Spearman's rank correlations. Cover estimation can fully substitute plant density counting in grassland with lower proportion of frequently and infrequently grazed patches only, but caution should be used when comparing different management regimes in long term analyses.     

Multivariate statistical study of seasonal variation of BTEX in the surface water of Savitri River

Volatile organic compounds (VOCs) analysis was carried out for the surface water of the Savitri river during the period of June 2005 to June 2007. BTEX compounds (Benzene, Toluene, Xylene & Ethyl benzene) were analyzed by using micro extraction technique (Purge & Trap). Concentrations of these BTEX compounds were ranging from 0.1 to 1.5 ppm during sampling period. Higher concentrations of BTEX were found at sampling location VI. Concentration of ethyl benzene was very low as compare to other compounds. However, the concentration of benzene was very high. Seasonal variations in conc. of BTEX compounds were observed and higher concentration was detected during the summer season. Salting-out effect had given higher quantification values. In PCA and PFA, the component loading for all the variables are positively correlated. Death of fishes was observed in the river that is indication of severe pollution problem.     

Assessing benthic community condition in Chesapeake Bay: does the use of different benthic indices matter?

Federal and state environmental agencies conduct several programs to characterize the environmental condition of Chesapeake Bay. These programs use different benthic indices and survey designs, and have produced assessments that differ in the estimate of the extent of benthic community degradation in Chesapeake Bay. Provided that the survey designs are unbiased, differences may exist in the ability of these indices to identify environmental degradation. In this study we compared the results of three indices calculated on the same data, and the assessments of two programs: the Chesapeake Bay Program and the Mid-Atlantic Integrated Assessment (MAIA). We examined the level of agreement of index results using site-based measures of agreement, evaluated sampling designs and statistical estimation methods, and tested for significant differences in assessments. Comparison of ratings of individual sites was done within separate categories of water and sediment quality to identify which indices summarize best pollution problems in Chesapeake Bay. The use of different benthic indices by these programs produced assessments that differed significantly in the estimate of degradation. A larger fraction of poor sites was classified as good by the Environmental Monitoring and Assessment Program’s Virginian Province and MAIA benthic indices compared to the Chesapeake Bay benthic index of biotic integrity, although overall classification efficiencies were similar for all indices. Differences in survey design also contributed to differences in assessments. The relative difference between the indices remained the same when they were applied to an independent dataset, suggesting that the indices can be calibrated to produce consistent results.     

Identification of air pollutant sampling period using horizontal dilution potential

A new model is proposed for estimating horizontal dilution potential of an area using wind data. The mean wind speed and wind direction variation are used as a measure of linear and angular spread of pollutant in the atmosphere. The methodology is applied to monitored hourly wind data for each month of 1 year for wind data collected at Vadodara, Gujarat and monthly dilution potential is estimated. It is found that there is a gradual variation of horizontal dilution potential over a year with limited dilution during post monsoon period i.e., October and November and a high dilution in pre monsoon period i.e., May and June. This information can be used to design air quality sampling network and duration of sampling for source apportionment study. Air pollutant sampling during high dilution period can be carried out for identifying urban and rural dust and wind blown dust from mining activity. Air pollutant sampling during low dilution period can be carried out for capturing large amount of particulate matter from anthropogenic sources like elevated stack of furnace.     

The reproduction of Enchytraeus sp.—technical improvement for the counting of juveniles

Soil-dwelling annelids of the genus Enchytraeus are used in ecotoxicology for testing of chemicals mixed in artificial soil or for testing of wastes and soils of unknown quality. ISO 16387 describes a method for determining the effects of substances or contaminated soils on survival and reproduction of Enchytraeus albidus or of the smaller species Enchytraeus buchholzi or Enchy-traeus crypticus. After the total test duration of 6 (or 4)?weeks, the juveniles hatched in the meantime are counted. There are several possible extraction techniques, which are always followed by counting the juveniles by hand, but none of them seems easy to handle. We proposed a new modification of the worm extraction method using flotation of fixed and stained juveniles followed by taking a photograph. The digital image of the juveniles is evaluated by computer processing. It makes the counting of juveniles much easier and less labor intensive.