Ein Beitrag zur Photostabilität organischer Umweltchemikalien in Gegenwart von Wasserstoffperoxid in aquatischen Systemen

It is well documented that the photolysis of H₂O₂ generates OH radicals which play an important role in explaining the degradation of environmental chemicals in aqueous medium. In the following work relative reaction rate constants of some representative substances were determined with wavelengths above 290 nm in the presence of H₂O₂. The results show, that the used system is suitable to check the OH radical reactivity of organic compounds under natural conditions.     

Education for Sustainable Development: The Johannesburg Summit and Beyond

The World Summit on Sustainable Development (WSSD), held in Johannesburg during 26 August and 4 September 2002, was a truly remarkable event, not least because it identified and committed the world community to what has to be done to realise Agenda 21 objectives. Discussion begins with the "means of implementation" of the Johannesburg Plan of Implementation (JPI). Education for, and raising awareness of, sustainable development are the key commitments in the "means of implementation". The issues central to these commitments are discussed. The crucial role of moral philosophy in education for sustainable development is then discussed. Defining the "problem" as lack of progress (in fact negative progress between Rio and Johannesburg) towards global sustainable development, a cause–effect relationship of the "problem" is developed based on a systematic and logical analysis. It shows that the "cause" is West's profoundly materialistic, environment-degrading and exploitative attitude and activities to satisfy grossly unsustainable, hedonistic and insatiably avaricious Western life-styles – life-styles that are held up by the West as "ideal" fruits of economic "development" to be aspired by all. The "effects" are pollution of air, water and soil; mounting loss of biodiversity, ecosystems and species; relentlessly widening north–south divide, etc. It is argued that while science and technology can address some of the "effects", they cannot address the "cause". Only moral philosophy can by fundamentally re-orienting moral values genuinely to respect nature and the environment. Based on sound and tested principles of Educational Psychology, a proposal is then made for including moral philosophy in the formal curricula (content and pedagogy) of primary, secondary and higher education for instilling in children and young people genuinely environment-respecting moral values. To this end a generic syllabus for the secondary level is proposed. Finally, it is argued that if the scientific community really believes that science or technology alone can radically change the pervasive environment-degrading moral values to those that genuinely respect the environment, thus paving the way to real global sustainability, then it must demonstrate how this could be done and explain why, despite their abundant science and technology, the developed nations are the biggest polluters and consumers with grossly unsustainable life-styles. Certainly, examples would be much more convincing than rhetoric or tired old clichés about how science and technology alone could deliver global sustainable development.     

A simple method for the extraction of mutagens from airborne particles

Organic materials were extracted with acetone from filters of airborne particles by soaking, shaking, soxhletion, and sonication. These extracts were tested with and without S9 for mutagenicity using Ames assay and arabinose-resistant assay of Salmonella typhimurium. Among the extraction methods, soaking extract had the highest mutagenic activity followed by sonication, shaking, and soxhletion in both the assays. With the samples studied, it was concluded that soaking with acetone for 1/2 hr is the simplest and an efficient procedure for the extraction of mutagens from airborne particles.Results of cooperative investigation of NIOSH and West Virginia Agricultural and Forstry Experimental Station. Published with the approval of the Director of the West Virginia Agricultural and Forestry Experiment Station as Scientific Paper No. 1822.     

Evaluating the effectiveness of fingerling stocking and ecological perspectives in enhancing fish harvest in a large tropical reservoir of Northern India

Environment, Development and Sustainability - The present study evaluated the effectiveness of stocking the Gangetic carps, viz. Labeo catla, Labeo rohita, and Cirrhinus mrigala, in a large...     

Fate of benzo(a)pyrene-C during brew process

Benzo(a)pyrene-¹⁴C (1 ppm) was applied to wort and boiled with hops in a brew process. The wort after filtration was subjected to fermentation. The hops and yeast were found to contain more than 99 % of applied radioactivity and consisted of benzo(a)pyrene. The radioactivity dissolved in beer was less than 1 % and the chemical nature could not be identified.     

Comparative studies on biomass productivity and lipid content of a novel blue-green algae during autotrophic and heterotrophic growth

Environmental Science and Pollution Research - Algae have long been acclaimed as the attractive renewable source for generating third-generation biofuels, particularly biodiesel. Under the present...     

'Pheromone-like' compounds in the cuticle of aquatic Chironomus larva

Chironomid midges are the most commonly found dipteran insects in all types of aquatic ecosystems. Cuticular extract was bio-assayed, and it exhibited enhanced attraction to the larvae. Therefore, it was subsequently analysed by gas chromatography-mass spectrometry. Two compounds were identified as farnesol and farnesene. Bioassay of farnesol indicated its attractive properties. The components present in the cuticular extract can, therefore, be considered as pheromone-like compounds.     

Balance of conversion and degradation of 2,6-dichlorobenzonitrile -14C in humus soil

In a closed aerated laboratory soil test, volatilization and mineralization of 2,6-dichlorobenzonitrile-¹⁴C is negligible within 61 days. The major soil residues are parent compound, 2,6-dichlorobenzamide and unextractable residues.     

Seasonal variations of natural ventilation and radon-222 exhalation in a slightly rising dead-end tunnel

The concentration activity of radon-222 has been monitored, with some interruptions, from 1997 to 2005 in the end section of a slightly rising, dead-end, 38-m long tunnel located in the Phulchoki hill, near Kathmandu, Nepal. While a high concentration varying from 6 x 10(3) Bq m(-3) to 10 x 10(3) Bq m(-3) is observed from May to September (rainy summer season), the concentration remains at a low level of about 200 Bq m(-3) from October to March (dry winter season). This reduction of radon concentration is associated with natural ventilation of the tunnel, which, contrary to expectations for a rising tunnel, takes place mainly from October to March when the outside air temperature drops below the average tunnel temperature. This interpretation is supported by temperature measurements in the atmosphere of the tunnel, a few meters away from the entrance. The temporal variations of the diurnal amplitude of this temperature indeed follow the ventilation rate deduced from the radon measurements. In the absence of significant ventilation (summer season), the radon exhalation flux at the rock surface into the tunnel atmosphere can be inferred; it exhibits a yearly variation with additional transient reductions associated with heavy rainfall, likely to be due to water infiltration. No effect of atmospheric pressure variations on the radon concentration is observed in this tunnel. This experiment illustrates how small differences in the location and geometry of a tunnel can lead to vastly different behaviours of the radon concentration versus time. This observation has consequences for the estimation of the dose rate and the practicability of radon monitoring for tectonic purposes in underground environments.     

Mercury exposure in sporadic amyotrophic lateral sclerosis patients from Ganga plain region in India: A retrospective study

Amyotrophic lateral sclerosis (ALS), a progressive disorder that usually runs a fatal course within 2–5 years of onset, is characterized by loss of motor neurons in the cortex, brain stem, and spinal cord. In this study mercury (Hg) concentrations were determined in blood samples of 40 ALS patients, of whom 24 ALS patients were from the Ganga plain region and their metal levels were found to be significantly higher. In contrast, Hg levels in the 16 ALS patients from non-Ganga plain regions whose levels were similar to those of the control subjects. Mercury in stream water samples and freshly deposited stream sediment were determined in the locations of patients’ native residences along the Ganga plain region and metal levels were found to be higher than the threshold guideline values for Hg in stream waters recommended by WHO. The geo-accumulation index in selected sites of freshly deposited stream sediment ranged from moderate to highly polluted. The high levels of Hg observed in ALS patients may potentially alter the redox status of neuronal cell components and induce cell-death pathways.