Balance of conversion and degradation of 2,6-dichlorobenzonitrile -14C in humus soil

In a closed aerated laboratory soil test, volatilization and mineralization of 2,6-dichlorobenzonitrile-¹⁴C is negligible within 61 days. The major soil residues are parent compound, 2,6-dichlorobenzamide and unextractable residues.     

Seasonal variations of natural ventilation and radon-222 exhalation in a slightly rising dead-end tunnel

The concentration activity of radon-222 has been monitored, with some interruptions, from 1997 to 2005 in the end section of a slightly rising, dead-end, 38-m long tunnel located in the Phulchoki hill, near Kathmandu, Nepal. While a high concentration varying from 6 x 10(3) Bq m(-3) to 10 x 10(3) Bq m(-3) is observed from May to September (rainy summer season), the concentration remains at a low level of about 200 Bq m(-3) from October to March (dry winter season). This reduction of radon concentration is associated with natural ventilation of the tunnel, which, contrary to expectations for a rising tunnel, takes place mainly from October to March when the outside air temperature drops below the average tunnel temperature. This interpretation is supported by temperature measurements in the atmosphere of the tunnel, a few meters away from the entrance. The temporal variations of the diurnal amplitude of this temperature indeed follow the ventilation rate deduced from the radon measurements. In the absence of significant ventilation (summer season), the radon exhalation flux at the rock surface into the tunnel atmosphere can be inferred; it exhibits a yearly variation with additional transient reductions associated with heavy rainfall, likely to be due to water infiltration. No effect of atmospheric pressure variations on the radon concentration is observed in this tunnel. This experiment illustrates how small differences in the location and geometry of a tunnel can lead to vastly different behaviours of the radon concentration versus time. This observation has consequences for the estimation of the dose rate and the practicability of radon monitoring for tectonic purposes in underground environments.     

Mercury exposure in sporadic amyotrophic lateral sclerosis patients from Ganga plain region in India: A retrospective study

Amyotrophic lateral sclerosis (ALS), a progressive disorder that usually runs a fatal course within 2–5 years of onset, is characterized by loss of motor neurons in the cortex, brain stem, and spinal cord. In this study mercury (Hg) concentrations were determined in blood samples of 40 ALS patients, of whom 24 ALS patients were from the Ganga plain region and their metal levels were found to be significantly higher. In contrast, Hg levels in the 16 ALS patients from non-Ganga plain regions whose levels were similar to those of the control subjects. Mercury in stream water samples and freshly deposited stream sediment were determined in the locations of patients’ native residences along the Ganga plain region and metal levels were found to be higher than the threshold guideline values for Hg in stream waters recommended by WHO. The geo-accumulation index in selected sites of freshly deposited stream sediment ranged from moderate to highly polluted. The high levels of Hg observed in ALS patients may potentially alter the redox status of neuronal cell components and induce cell-death pathways.     

Erratum to: Elephants Also Like Coffee: Trends and Drivers of Human–Elephant Conflicts in Coffee Agroforestry Landscapes of Kodagu,Western Ghats,India

Kodagu district produces 2% of the world’s coffee, in complex, multistoried agroforestry systems. The forests of the district harbour a large population of the Asian elephant (Elephas maximus). The combined effects of high elephant density and major landscape changes due to the expansion of coffee cultivation are the cause of human–elephant conflicts (HEC). Mitigation strategies, including electric fences and compensation schemes implemented by the Forest Department have met with limited success. Building on previous studies in the area, we assessed current spatial and temporal trends of conflict, analysed local stakeholders’ perceptions and identified factors driving elephants into the estates. Our study, initiated in May 2007, shows that the intensity of HEC has increased over the last 10 years, exhibiting new seasonal patterns. Conflict maps and the lack of correlation between physical features of the coffee plantations and elephant visits suggest elephants move along corridors between the eastern and western forests of the district, opportunistically foraging when crossing the plantations. Dung analyses indicate elephants have selectively included ripe coffee berries in their diet. This is, to our knowledge, the first report of wild elephants feeding on coffee berries. If this new behaviour spreads through the population, it will compound an already severe conflict situation. The behavioural plasticity, the multiplicity of stakeholders involved, the difficulty in defining the problem and the limits of technical solutions already proposed suggest that HEC in Kodagu has the ingredients of a “wicked” problem whose resolution will require more shared understanding and problem solving work amongst the stakeholders.     

Analysis of different nutrient status of liquid bio-fertilizer of different combinations of buffalo dung with gram bran and water hyacinth through vermicomposting by <Emphasis Type="Italic">Eisenia fetida</Emphasis>

The animal, agro-wastes and water hyacinth (Eichhornia crassipes) are a serious problem for the society and ecosystem. The present study carried out the management of water hyacinth and observation of nutritional status like pH, electrical conductivity (EC), total organic carbon (TOC), total Kjeldahl nitrogen (TKN), C/N ratio, total phosphorus and total calcium (TCa) of liquid bio-fertilizer (vermiwash) before and after vermicomposting of feed materials of different combinations of buffalo dung (BD) with water hyacinth (WH) and gram bran (GB). After vermicomposting of different combinations of BD with WH and agro-wastes, significant decrease in level of pH, EC, TOC and C/N ratio was observed, whereas significant increase in TKN, TK, TAP and TCa level in vermiwash of final vermicompost with respect to initial feed material was observed. The pH of initial mixture in all combinations has tended to basic in nature, while in final vermicompost, it becomes neutral/basic. The significant increase was observed in the level of TKN, TK, TAP in BD + GB + WH (1:2:1) and TCa in BD + GB + WH (1:1:2) vermiwash of final vermicompost of combination, whereas decrease was observed in TOC, C/N ratio, pH and EC in BD + WH (1:1), BD + GB + WH (1:1:1), BD + GB + WH (1:2:1) and BD + GB (1:1), respectively.     

Chromium in tannery industry effluent and its effect on plant metabolism and growth

Different dilution levels of tannery treated effluent and their corresponding concentration of chromium (Cr6+) were studied in a petridish culture experiment on seed germination and seedling growth in radish (Raphanus sativus L). The different concentrations of Cr6+ (2, 5 and 10 ppm) and treated tannery effluent (10, 25 and 50%) showed reduction in seedling growth and related enzymatic activities with increase in concentration of Cr6+ in treatments and effluent both. The low concentration of chromium (2 ppm) and effluent dilution (10%) showed significant growth reduction separately. At this concentration of chromium and effluent dilution chlorophyll content, amylase, catalase and protein contents remained unchanged while with increase in Cr6+ concentration (>2ppm) and effluent dilution (> 10%) in treatments showed growth inhibitory effects.     

A heuristic for setting effective standards to ensure global environmental sustainability

Most environmental professionals and decision-makers, and certainly the public at large, hold the view that the integrity of earth’s natural environment will be conserved for posterity and sustainable development achieved if all the nations rigorously enforced their environmental and emission standards. It is argued in this paper that this view, sincerely held by many as an “axiomatic truth,” is mistaken and misplaced. This is because as a biogeochemical entity the Earth has limited self-regenerative capacity (SRC) to cope with anthropogenic pollution, and all kinds of environmental problems ensue when that limit is exceeded. Indeed, mounting environmental problems now occurring on all fronts amply testify to the fact that the limit has already been exceeded. They also provide necessary and sufficient proof that environmental and emission standards have been woefully inadequate for protecting earth’s natural environment and life-support systems. It is argued that true global environmental sustainability will be achieved, paving the way to true global sustainable development, if and only if global environmental and emission standards are set so that global anthropogenic pollution does not exceed the limit of earth’s natural SRC to cope with such pollution. These and related issues are discussed in this paper. A simple mathematical model using basic mathematics is also presented to explain how the phenomenon of “positive feedback” works in some of the environmental problems to exacerbate environmental degradation and progressively to erode nature’s SRC.

A Simple Model to Determine In Situ Mixing Height Growth from Surface Measurements

A generic In Situ Mixing Height Growth (IMG) model, capable of predicting the real-time growth of the mixed layer and its diurnal evolution from routinely observed simple surface meteorological is developed. The algorithm for the determination of temporally growing daytime mixing height includes both convective and mechanical turbulence contributions. It accounts for neutral as well as height varying potential temperature gradients above the mixed layer. For thermally stable and mechanically dominated unstable night time Atmospheric Boundary Layer (ABL) the module uses similarity formulae based on the wind velocity [1]), the Monin—Obukhov length [2], and the Coriolis parameter. In the convective case simple slab model is integrated, based on initial lapse rate and the surface heat flux. The lapse rate is evaluated on the basis of vertical atmospheric stability, surface type and surface temperature. This differentiates the IMG model from other existing mixing height models that need initial measured lapse rate for calculation. IMG model is site specific as it calculates the radiative incoming heat flux depending on the solar declination estimates based on-site latitude and longitude. The IMG model is applied to calculate mixing height for India by using surface data (viz. wind speed, surface temperature, surface type) from 152 surface meteorological stations. Results have been evaluated with radiosonde mixing height data procured from 18 upper air stations. Sensitivity analysis of the model with respect to various parameters is performed. The model is formulated after reviewing presently available radiosonde mixing height data in India and can satisfactorily provide an alternative means of estimating mixing height for air pollution dispersion models.