A short-cut method for assessing absorbents for post-combustion carbon dioxide capture

A short-cut method for the estimation of the minimum regeneration energy and optimum solvent flow rate in post-combustion carbon dioxide capture by absorption is presented. It is developed for comparing solvents of which only little thermo-physical data is known. The closed absorber–desorber cycle is described by an equilibrium stage model (modified Kremser equation with discretized equilibrium curves). The method can be implemented in any mathematical toolbox or as stand-alone solution. The only required input is the solubility data at absorber and desorber conditions, the heat of absorption and heat capacities. The caloric data may be estimated. The method was applied to monoethanolamine (MEA) and two solvents from the EU-project CASTOR. Comparisons with experimental results from pilot-plant studies with MEA show that the method, despite its simplicity, gives reasonable results. The method should also be useful in other applications where absorbents, of which only little data is available, need to be screened.     

Heavy metal contamination of drinking water in Kamrup district, Assam, India

This study was undertaken to assess the heavy metal concentration of the drinking water with respect to zinc, copper, cadmium, manganese, lead and arsenic in Kamrup district of Assam, India. Ground water samples were collected from tube wells, deep tube wells and ring wells covering all the major hydrogeological environs. Heavy metals in groundwater are estimated by using Atomic Absorption Spectrometer, Perkin Elmer Analyst 200. Data were assessed statistically to find the distribution pattern and other related information for each metal. The study revealed that a good number of the drinking water sources were contaminated with cadmium, manganese and lead. Arsenic concentrations although did not exceeded WHO limits but was found to be slightly elevated. Copper and zinc concentrations were found to be within the prescribed WHO limits. An attempt has also been made to ascertain the possible source of origin of the metals. Positive and significant correlation existing between manganese with zinc and copper indicates towards their similar source of origin and mobility. In view of the present study and the level of heavy metal contamination, it could be suggested to test the potability of the water sources before using it for drinking purpose.     

Contemporary forest loss in Myanmar: Effect of democratic transition and subsequent timber bans on landscape structure and composition

This study addresses the effect of political transition and subsequent timber bans on forest loss in Myanmar, in the context of identified drivers. Cook’s Distance (CD) was applied to remotely sensed time-series forest loss dataset to measure the effect of the events. Forest loss derived fragmentation metrics were linked to drivers at a landscape scale. Results show that at the national level, the political transition in 2011 had maximum effect (CD 0.935) on forest loss while the timber bans decreased forest loss by 612.04 km² and 213.15 km² in 2015 and 2017 (CD 0.146 and 0.035), respectively. The effect of the events varied for different States/Regions. The dominant drivers of change shifted from plantations in 2011 to infrastructure development in 2015. This study demonstrates the effects of policy on forest loss at various scales and can inform decision-makers for forest conservation, planning and development of mitigation measures.     

Arsenate and arsenite-induced inhibition and recovery in two diazotrophic cyanobacteria Nostoc muscorum and Anabaena sp.: study on time-dependent toxicity regulation

Environmental Science and Pollution Research - Exposure time, metal bio-accumulation, and upregulation of ascorbate-glutathione (AsA-GSH) cycle are the key factor that provide tolerance against...     

Spatial patterns of off-the-system traffic crashes in Miami–Dade County,Florida, during 2005–2010

Objective: The objective of this study is to analyze the spatial distribution of the vehicles involved in crashes in Miami–Dade County. In addition, we analyzed the role of time of day, day of the week, seasonality, drivers’ age in the distribution of traffic crashes.

Method: Off-the-system crash data acquired from the Florida Department of Transportation during 2005–2010 were divided into subcategories according to the risk factors age, time of day, day of the week, and travel season. Various spatial statistics methods, including nearest neighbor analysis, Getis-Ord hot spot analysis, and kernel density analysis revealed substantial spatial variations, depending on the subcategory in question.

Results: Downtown Miami and South Beach showed up consistently as hotspots of traffic crashes in all subcategories except fatal crashes. However, fatal crashes were concentrated in residential areas in inland areas.

Conclusion: This understanding of patterns can help the county target high-risk areas and help to reduce crash fatalities to create a safer environment for motorists and pedestrians.     

Impact of long-term wastewater application on microbiological properties of vadose zone

Impact of wastewater irrigation on some biological properties was studied in an area where treated sewage water is being supplied to the farmers since 1979 in the western part of National Capital Territory of New Delhi under Keshopur Effluent Irrigation Scheme. Three fields were selected which had been receiving irrigation through wastewater for last 20, 10 and 5 years. Two additional fields were selected in which the source of irrigation water was tubewell. The soil bacterial and fungal population density was studied in soil layers of 0?C15, 15?C30, 30?C60 and 60?C120 cm depths. Groundwater samples were collected from the piezometers installed in the field irrigated with sewage water for last 20, 10 and 5 years. Results indicate that there was significant increase in bacterial and fungal count in sewage-irrigated soils as compared to their respective control. The population density of bacteria and fungi in waste water-irrigated soils increased with the duration of sewage water application and decreased with increasing depth. The bacterial and fungal count was also directly proportional to organic carbon, sand and silt content and negatively correlated to the clay content, electrical conductivity, pH and bulk density of the soil. Groundwater under sewage-irrigated fields had higher values of most probable number (MPN) index as compared to that of tubewell water-irrigated fields. All the shallow and deep groundwaters were found to be contaminated with faecal coliforms. The vadose zone had filtered the faecal coliform to the tune of 98?C99%, as the MPN index was reduced from ??18,000 per 100 ml of applied waste water to 310 per 100 ml of groundwater under 20 years sewage-irrigated field. The corresponding values of MPN were 250 and 130 per 100 ml of shallow groundwater under 10 and 05 years sewage-irrigated fields, respectively. Rapid detection of faecal contamination suggested that the Citrobacter freundii and Salmonella were dominant in shallow groundwater, while Escherichia coli was dominant in deep groundwater collected from sewage-irrigated field.     

Biodegradable Chitosan-g-Poly(methacrylamide) Microspheres for Controlled Release of Hypertensive Drug

Chitosan-g-poly(methacrylamide) (CS-g-PMAAm) was synthesized by redox polymerization. The synthesized graft copolymers were used to prepare microspheres (MS) by water/oil (W/O) emulsion technique and cross-linked with glutaraldehyde (GA). Developed microspheres were encapsulated using enalapril maleate (ENAM) as a model drug (hypertension) and characterized by fourier transform infrared spectroscopy, differential scanning calorimetry and scanning electron microscopy. The physico-chemical properties of the microspheres were studied by calculating drug entrapment efficiency, and drug release kinetics. % of encapsulation efficiency (% EE) increased with increase in drug loading and methacrylamide (MAAm) content. The minimum % EE (65.2 ± 1.6) was observed in case of microsphere containing 40 % MAAm, 5 % ENAM and 10 mL glutaraldehyde. The release profiles indicate that formulation containing highest (10 mL) crosslinking agent microspheres has the slow release.