脉冲喷吹2000mm长滤筒的清灰性能

为探究2 000 mm长滤筒滤筒在脉冲清灰时,不同喷吹条件(喷吹孔径、喷吹距离)对滤筒清灰性能的影响及沿长滤筒长度方向上侧壁压力峰值分布规律,设计脉冲喷吹实验,测定Φ147 mm×2 000 mm(覆PTFE膜)长滤筒在不同喷吹条件下的侧壁压力峰值.实验结果表明,2 000 mm长滤筒的最佳喷吹孔径为15 mm,最佳喷吹距离为240 mm,在0.5 MPa条件下,沿滤筒长度方向上各测点的侧壁压力峰值分别为P0 1 084、P1 1 898、P2 1 276、P3 1 556、P4 1 302和P5 3 258.并得出最佳喷吹距离随着喷吹孔径的减小而逐渐增大,以及沿长滤筒长度方向上侧壁压力峰值分布呈现先增加再减小再增加的分布规律.研究成果旨在为长滤筒过滤系统优化设计及滤筒除尘器代替滤袋除尘器的应用上提供指导.     

硫酸盐化对TiO2催化剂克劳斯活性的影响

采用硫酸铵浸渍的方法制得了一系列硫酸盐化的催化剂,运用TG、BET比表面测定、XRD、Raman、FTIR和SO2-TPD技术对催化剂进行了表征,并对催化剂进行了克劳斯活性评价。结果表明,硫酸盐化会导致催化剂比表面积和孔体积减小但不会使催化剂形成新的晶型,硫酸盐的形成使TiO2表面碱性变弱,硫酸根在TiO2表面形成的双齿螯合结构会阻碍SO2和H2S与催化剂表面的接触,碱性变弱和双齿螯合结构的形成导致了催化剂克劳斯活性降低,另外,负载的硫酸盐的量越多催化剂的克劳斯活性越低。     

The double-edged role of the digital economy in firm green innovation: micro-evidence from Chinese manufacturing industry

Environmental Science and Pollution Research - The digital economy, which gradually emerged with a new generation of information technologies, has become an unavoidable reality for manufacturing...     

上部开口诱导引流装置对卧式长滤筒清灰性能的影响

采用仿真模拟及喷吹实验,研究采用卧式长滤筒的脉冲滤筒除尘器的清灰性能。由于卧式长滤筒在截面形状、放置方式和筒身长度上与传统滤筒有明显区别,使得其清灰方式需要进一步优化。探究诱导引流装置的上部开口尺寸对卧式长滤筒清灰性能的影响发现,随着上部开口口径增大,压力均值逐渐增大,压力分布均匀性有所降低。综合清灰性能指标评价得出,D₁₆型上部开口引流装置在0.4 MPa,175 mm的喷吹参数下可实现卧式长滤筒的高效清灰。本研究结果可为卧式长滤筒清灰性能的优化提供参考。     

臭氧曝气沸石生物滤池处理硝基苯废水

利用臭氧曝气沸石生物滤池处理硝基苯废水,了解了该方法对废水中的硝基苯、氮和磷的去除效果,考察了水力停留时间的变化对污染物去除效果的影响。臭氧曝气沸石生物滤池与空气曝气沸石生物滤池相比,臭氧曝气生物滤池对硝基苯、COD、氨氮的去除效果优于空气曝气沸石生物滤池,对总磷的去除效果与空气曝气沸石生物滤池差别不大。当臭氧曝气沸石生物滤池的HRT=4 h、臭氧浓度为126 mg/L时,对初始浓度为100 mg/L的硝基苯污水去除率接近99%。在相同条件下,空气曝气沸石生物滤池对硝基苯的去除率仅为59%。在HRT=4 h、臭氧浓度为126 mg/L时,臭氧曝气沸石生物滤池与空气曝气沸石生物滤池对COD的去除率为94%和83%,对NH4+-N的去除率为64%和59%,对TP的去除率为42%和45%。     

The temporal changes in road stormwater runoff quality and the implications to first flush control in Chongqing, China

This study investigates the quality of stormwater runoff from a driveway in the southwest mountainous urban area of Chongqing, China, from 2010 to 2011. The results showed that the mean concentrations of chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) were 4.1, 2.4, and 2.2 times the grade V levels of the national surface water standard of China. The pollutant concentration peak preceded or synchronized with the rainfall intensity peak and occurred 10 min after the runoff started. The significant high pollutant concentration in the initial stage of the rainfall suggested that first flush control is necessary, especially for the most polluted constitutes, such as total suspended solids, COD, and TN. Three potential pollution sources were identified: the atmospheric dry and wet deposition (TN, NO₃ ^?-N, NH₄ ⁺-N, and DCu), the road sediment and materials (total suspended solids, COD, and TP), and the vehicle emissions (DPb and DZn). Therefore, this study indicates that reductions in road sediments and material pollution and dry and wet deposition should be the priority factors for pollution control of road stormwater runoff in mountainous urban areas.     

Carbon dioxide fixation by Chlorella sp. USTB-01 with a fermentor-helical combined photobioreactor

A promising microalgal strain isolated from fresh water, which can grow both autotrophically on inorganic carbon under lighting and heterotrophically on organic carbon without lighting, was identified as Chlorella sp. USTB-01 with the phylogenetic analysis based on 18S ribosomal ribonucleic acid (rRNA) gene sequences. In the heterotrophic batch culture, more than 20.0 g·L⁻¹ of cell dry weight concentration (DWC) of Chlorella sp. USTB-01 was obtained at day 5, and which was used directly to seed the autotrophic culture. A novel fermentor-helical combined photobioreactor was established and used to cultivate Chlorella sp. USTB-01 for the fixation of carbon dioxide (CO₂). It showed that the autotrophic growth of Chlorella sp. USTB-01 in the combined photobioreactor was more effective than that in the fermentor alone and the maximum DWC of 2.5 g·L⁻¹ was obtained at day 6. The highest CO₂ fixation of 95% appeared on day 1 in the exponential growth phases of Chlorella sp. USTB-01 and 49.8% protein was found in the harvested microalgal cells.     

合肥市水环境承载力评估

从经济、人口、资源和技术管理等角度分析了影响水环境承载力的因素,结合研究区的特点确定了评价的指标体系.采用向量模法对合肥市2000年-2007年的水环境承载力进行评估.结果表明:合肥市的水环境承载力水平较低,但总体呈逐年上升趋势,评价值由2000年的0.027增加到2007年的0.077.在主要的水资源支持因素中,经济发展和技术管理因素对水环境的贡献增长速度最快,而自然资源因素则是主要的不稳定因素.为了协调经济发展和环境保护,提高水环境承载力,开源节流,提高水资源量是维持水环境承载力的重要途径之一.     

Reduction behaviors of permanganate by microbial cells and concomitant accumulation of divalent cations of Mg2+, Zn2+, and Co2+

Permanganate treatment is widely used for disinfection of bacteria in surface-contaminated water. In this paper, the fate of the dissolved permanganate in aqueous solution after contact with cells of Pseudomonas fluorescens was studied. Concomitant accumulation of divalent cations of Mg~(2+), Zn~(2+), and Co~(2+) during precipitation of Mn oxides was also studied. The time course of the Mn concentration in solution showed an abrupt decrease after contact of Mn(VII) with microbial cells, followed by an increase after ～ 24 hr.XRD analysis of the precipitated Mn oxides, called biomass Mn oxides, showed the formation of low-crystalline birnessite. Visible spectroscopy and X-ray absorption near edge structure(XANES) analyses indicated that dissolved Mn(VII) was reduced to form biomass Mn oxides involving Mn(IV) and Mn(III), followed by reduction to soluble Mn(II).The numbers of electron transferred from microbial cells to permanganate and to biomass Mn oxides for 24 hr after the contact indicated that the numbers of electron transfer from microbial cell was approximately 50 times higher to dissolved permanganate than to the biomass Mn oxides in present experimental conditions. The 24 hr accumulation of divalent cations during formation of biomass Mn oxides was in the order of Co~(2+) Zn~(2+) Mg~(2+).XANES analysis of Co showed that oxidation of Co~(2+) to Co~(3+) resulted in higher accumulation of Co than Zn and Mg. Thus, treatment of surface water by KMnO_4 solution is effective not only for disinfection of microorganisms, but also for the elimination of metal cations from surface water.     

Vertical distribution and temporal evolution of formaldehyde and glyoxal derived from MAX-DOAS observations: The indicative role of VOC sources

Formaldehyde (HCHO) and glyoxal (CHOCHO) are important oxidization intermediates of most volatile organic compounds (VOCs), but their vertical evolution in urban areas is not well understood. Vertical profiles of HCHO, CHOCHO, and nitrogen dioxide (NO₂) were retrieved from ground-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) observations in Hefei, China. HCHO and CHOCHO vertical profiles prefer to occur at higher altitudes compared to NO₂, which might be caused by the photochemistry-oxidation of longer-lived VOCs at higher altitudes. Monthly means of HCHO concentrations were higher in summer, while enhanced amounts of NO₂ were mainly observed in winter. CHOCHO exhibited a hump-like seasonal variation, with higher monthly-averaged values not only occurred in warm months (July-August) but also in cold months (November-December). Peak values mainly occurred during noon for HCHO but emerged in the morning for CHOCHO and NO₂, suggesting that HCHO is stronger link to photochemistry than CHOCHO. We further use the glyoxal to formaldehyde ratio (GFR) to investigate the VOC sources at different altitudes. The lowest GFR value is almost found in the altitude from 0.2 to 0.4 km, and then rises rapidly as the altitude increases. The GFR results indicate that the largest contributor of the precursor VOC is biogenic VOCs at lower altitudes, while at higher altitudes is anthropogenic VOCs. Our findings provide a lot more insight into VOC sources at vertical direction, but more verification is recommended to be done in the future.