全文获取类型
收费全文 | 37篇 |
免费 | 2篇 |
国内免费 | 33篇 |
专业分类
环保管理 | 2篇 |
综合类 | 40篇 |
基础理论 | 21篇 |
污染及防治 | 7篇 |
评价与监测 | 2篇 |
出版年
2021年 | 2篇 |
2020年 | 2篇 |
2019年 | 3篇 |
2018年 | 4篇 |
2017年 | 3篇 |
2016年 | 3篇 |
2015年 | 4篇 |
2014年 | 1篇 |
2013年 | 2篇 |
2012年 | 6篇 |
2011年 | 2篇 |
2009年 | 2篇 |
2008年 | 1篇 |
2007年 | 5篇 |
2006年 | 4篇 |
2005年 | 4篇 |
2003年 | 1篇 |
2002年 | 2篇 |
2001年 | 1篇 |
2000年 | 7篇 |
1998年 | 4篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1994年 | 3篇 |
1992年 | 1篇 |
1990年 | 1篇 |
排序方式: 共有72条查询结果,搜索用时 187 毫秒
41.
以相同Al13含量、不同浓度的PAC为原料,利用乙醇-丙酮混合溶剂法、SO4^2-/Ba^2 沉淀置换法以及柱层析法分离提纯纳米Al13形态,同时利用Al-Ferron逐时络合比色法、^27Al-NMR等多种现代分析手段进行分析鉴定,比较其分离效果,并采用烧杯实验法和透光率脉动检测技术对Al13形态以及PAC、AlCl3的絮凝效果及絮凝过程中絮集物形成和增长的变化差异作了对比性研究.实验结果表明,乙醇.丙酮混合溶剂法对Al13分离纯化效果最好,分离所得Al13平均粒径大,聚合程度高.柱层析法受柱体积的影响只对低浓度的PAC有较好的分离效果;SO4^2-/Ba^2 沉淀置换法虽具有较好的分离效果,但分离过程有其他杂质离子的加入,影响到产品品质.混凝效果和动态实验结果表明,Al13形态是在絮凝过程中起电中和作用的主要形态,具有较强的除浊及脱色能力,在混凝过程中当絮体受到剪切力的破坏时Al13形态比PAC和AlCl3具有更强重新絮凝的能力. 相似文献
42.
Gao Baoyu Chu Yongbao Yue Qinyan Kong Chunyan Wang Xiaona 《Frontiers of Environmental Science & Engineering in China》2007,1(3):368-373
In order to investigate the characteristics of pure Nano-Al13, Nano-Al13 was separated and purified from a series of poly-aluminum chloride (PAC) solutions which had the same Al13 percentage but different total Al concentrations, by using column chromatography, ethanol-acetone resolving and SO2−
4/Ba2+ displacement. The Al13 species yield was characterized by Al-ferron timed complexation spectrophotometry and 27Al-NMR (nuclear magnetic resonance). The coagulation efficiency of Nano-Al13, PAC and AlCl3 in synthetic water was also investigated by Jar tests. The dynamic process and aggregation state of kaolin suspensions coagulating
with Nano-Al13, PAC and AlCl3 were similarly investigated using a photometric dispersion analyzer 2000 (PDA2000). The experimental results indicated that
the ethanol-acetone resolving method was simple and could separate the PAC solution at different concentrations, while column
chromatography could separate PAC solutions at low concentrations. The SO4
2−/Ba2+ displacement method could separate PAC solutions at high concentrations. However, extra inorganic cation and anion could
be added in the solution during separation. The coagulation efficiency and dynamic experimental results showed that Nano-Al13 with high positive-charged species was effective in removing turbidity and color. The dynamic process results showed that
Nano-Al13 also had the best recovery capability after shearing compared with PAC and AlCl3 because the Nano-Al13 conformation is more effective in charge neutralization.
Translated from Acta Scientiae Circumstantiae, 2005, 25(6): 767–772 [译自: 环境科学学报] 相似文献
43.
粉末活性炭对膜过滤性能的影响 总被引:4,自引:0,他引:4
向一体式膜生物反应器中投加粉末活性炭(PAC),可以显著提高膜的过滤性能,有效缓解膜的污染。研究结果表明:投加PAC的吸附作用减少了由于胞外聚合物(EPS)而引起的膜污染;膜表面PAC颗粒的存在减小了浓差极化层的厚度和水力边界层的厚度,提高了过滤物质的传递速率;膜表面形成的PAC层还可过滤微生物和胶体颗粒,减少了它们到达膜表面的数量。 相似文献
44.
Baoyu Gao Yongbao Chu Qinyan Yue Chunyan Kong Xiaona Wang 《Frontiers of Environmental Science & Engineering》2007,1(3):368-373
In order to investigate the characteristics of pure Nano-Al13, Nano-Al13 was separated and purified from a series of poly-aluminum chloride (PAC) solutions which had the same Al13 percentage but different total Al concentrations, by using column chromatography, ethanol-acetone resolving and SO2? 4/Ba2+ displacement. The Al13 species yield was characterized by Al-ferron timed complexation spectrophotometry and 27Al-NMR (nuclear magnetic resonance). The coagulation efficiency of Nano-Al13, PAC and AlCl3 in synthetic water was also investigated by Jar tests. The dynamic process and aggregation state of kaolin suspensions coagulating with Nano-Al13, PAC and AlCl3 were similarly investigated using a photometric dispersion analyzer 2000 (PDA2000). The experimental results indicated that the ethanol-acetone resolving method was simple and could separate the PAC solution at different concentrations, while column chromatography could separate PAC solutions at low concentrations. The SO4 2?/Ba2+ displacement method could separate PAC solutions at high concentrations. However, extra inorganic cation and anion could be added in the solution during separation. The coagulation efficiency and dynamic experimental results showed that Nano-Al13 with high positive-charged species was effective in removing turbidity and color. The dynamic process results showed that Nano-Al13 also had the best recovery capability after shearing compared with PAC and AlCl3 because the Nano-Al13 conformation is more effective in charge neutralization. 相似文献
45.
Yang Jin Qinyan Yue Kunlun Yang Suqing Wu Shengjie Li Baoyu Gao Yuan Gao 《环境科学学报(英文版)》2018,30(1):43-49
A novel cathodic–anodic-electrolysis packing(CAEP) used in the treatment of pyridine wastewater was researched, which mainly consisted of 4,4′-diamino-2,2′-disulfonic acid(DSD acid) industrial iron sludge. The physical properties and morphology of the packing were studied. The CAEP was used in a column reactor during the pretreatment of pyridine wastewater. The influence of p H, hydraulic retention time(HRT), the air–liquid ratio(A/L)and the initial concentration of pyridine were investigated by measuring the removal of total organic carbon(TOC) and pyridine. The characterization results showed that the bulk density, grain density, water absorption percentage and specific surface area were 921 kg/m3,1086 kg/m3, 25% and 29.89 m~2/g, respectively; the removal of TOC and pyridine could reach50% and 58% at the optimal experimental conditions(p H = 3, HRT = 8 hr, A/L = 2). Notably,the surface of the packing was renewed constantly during the running of the filter, and the handling capacity was stable after running for three months. 相似文献
46.
A coagulation/flocculation process using the composite flocculant polyaluminum chloride-epichlorohydrin dimethylamine (PAC-EPI-DMA) was employed for the treatment of an anionic azo dye (Reactive Brilliant Red K-2BP dye). The effect of viscosity (ηup), basicity (B = [OH]/[Al]) and organic content (WP) on the flocculation performance as well as the mechanism of PAC-EPI-DMA flocculant were investigated. The ηup was the key factor affecting the dye removal efficiency of PAC-EPI-DMA. PAC-EPI-DMA with an intermediate ηup (2400 mPa.sec) gave higher decolorization efficiency by adsorption bridging and charge neutralization due to the co-effect of PAC and EPI-DMA polymers. The WP of the composite flocculant was a minor important factor for the flocculation. The adsorption bridging of PAC-EPI-DMA with ηup of 300 or 4300 mPa.sec played an important role with the increase of WP, whereas the charge neutralization of them was weaker with the increase of WP. There was interaction between WP and B on the removal of reactive dye. The composite flocculant with intermediate viscosity and organic content was effective for the treatment of reactive dyeing wastewater, which could achieve high reactive dye removal efficiency with low organic dosage. 相似文献
47.
Kangying Guo Baoyu Gao Jie Wang Jingwen Pan Qinyan Yue Xing Xu 《Frontiers of Environmental Science & Engineering》2021,15(5):103
48.
49.
50.
聚硅氯化铝(PASC)的形态分布及转化规律Ⅰ.Al-Ferron逐时络合比色法研究PASC溶液中铝的形态分布及转化规律 总被引:1,自引:0,他引:1
采用Al-Ferron逐时络合比色法比较研究了PASC与PAC中铝的形态分布及转化规律.实际结果表明,在PASC中,由于聚硅酸与铝水解聚合产物间的相互作用,使得铝的水解聚合形态分布及转化情况发生了变化.在相同B值条件下,PASC中Ala和Al b的含量低于PAC中相应Als和Alb的含量,而PASC中Alc的含量却大于PAC中Alc的含量.共聚法制备的PASC(共)与复合法制备的PASC(复)相比较,PASC(复)具有较高的Ala和 Alb含量,较低的Alc含量.这说明制备工艺对PASC中铝的形态分布具有一定的影响. 相似文献