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861.
Wang X Xing L Qiu T Han M 《Environmental science and pollution research international》2013,20(4):2236-2243
Both nitrate and pentachlorophenol (PCP) are familiar pollutants in aqueous environment. This research is focused on the simultaneous removal of nitrate and PCP from simulated contaminated groundwater using a laboratory-scale denitrification reactor packed with corncob as both carbon source and biofilm support. The reactor could be started up readily, and the removal efficiencies of nitrate and PCP reached up to approximately 98 % and 40–45 % when their initial concentrations were 50 mg N/L and 5 mg/L, respectively, after 15-day continuous operation at 10 h of hydraulic retention time (HRT) and 25 °C. Approximately 91 % of PCP removal efficiency was achieved, with 2.47 mg/L of chloride ion release at 24 h of HRT. Eighty-two percent of chlorine in PCP removed was ionized. The productions of 3-chlorophenol and phenol and chloride ion release indicate that the reductive dechlorination reaction is a major degradation pathway of PCP under the experimental conditions. 相似文献
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863.
双氧水-高锰酸钾催化氧化降解地下水中硝基苯的效能与机理 总被引:1,自引:0,他引:1
应用双氧水-高锰酸钾(H2O2-KMnO4)催化氧化作用,对地下水中硝基苯(NB)的降解效果和作用机理进行了研究,探讨了H2O2、KMnO4的不同浓度、不同pH值以及地下水中比较有代表性的共存离子钙(Ca2+)、镁(Mg2+)、铜(Cu2+)、锌(Zn2+)、重碳酸根(HCO3-)、碳酸根(CO23-)等因素对NB氧化... 相似文献
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867.
To assess the toxic effects of phenanthrene on earthworms, we exposed Eisenia fetida to artificial soils supplemented with different concentrations (0.5, 2.5, 12.5, mgkg(-1) soil) of phenanthrene. The residual phenanthrene in the soil, the bioaccumulation of phenanthrene in earthworms, and the subsequent effects of phenanthrene on growth, anti-oxidant enzyme activities, and lipid peroxidation (LPO) were determined. The degradation rate of low concentrations of phenanthrene was faster than it was for higher concentrations, and the degradation half-life was 7.3d (0.5 mgkg(-1)). Bioaccumulation of phenanthrene in the earthworms decreased the phenanthrene concentration in soils, and phenanthrene content in the earthworms significantly increased with increasing initial soil concentrations. Phenanthrene had a significant effect on E. fetida growth, and the 14-d LC(50) was calculated as 40.67 mgkg(-1). Statistical analysis of the growth inhibition rate showed that the concentration and duration of exposure had significant effects on growth inhibition (p<0.001). Superoxide dismutase (SOD) activity increased at the beginning (2 and 7d) and decreased in the end (14 and 28 d). Catalase (CAT) activity in all treatments was inhibited from 1 to 14 d of exposure. However, no significant perturbations in malondialdehyde (MDA) content were noted between control and phenanthrene-treated earthworms except after 2d of exposure. These results revealed that bioaccumulation of phenanthrene in E. fetida caused concentration-dependent, sub-lethal toxicity. Growth and superoxide dismutase activity can be regarded as sensitive parameters for evaluating the toxicity of phenanthrene to earthworms. 相似文献
868.
Cadmium accumulation in and tolerance of rice (Oryza sativa L.) varieties with different rates of radial oxygen loss 总被引:1,自引:0,他引:1
Wang MY Chen AK Wong MH Qiu RL Cheng H Ye ZH 《Environmental pollution (Barking, Essex : 1987)》2011,159(6):1730-1736
Cadmium (Cd) uptake and tolerance were investigated among 20 rice cultivars based on a field experiment (1.2 mg Cd kg−1 in soil) and a soil pot trial (control, 100 mg Cd kg−1), and rates of radial oxygen loss (ROL) were measured under a deoxygenated solution. Significant differences were found among the cultivars in: (1) brown rice Cd concentrations (0.11-0.29 mg kg−1) in a field soil, (2) grain Cd tolerance (34-113%) and concentrations (2.1-6.5 mg kg−1) in a pot trial, and (3) rates of ROL (15-31 mmol O2 kg−1 root d.w. h−1). Target hazard quotients were calculated for the field experiment to assess potential Cd risk. Significant negative relationships were found between rates of ROL and concentrations of Cd in brown rice or straw under field and greenhouse conditions, indicating that rice cultivars with higher rates of ROL had higher capacities for limiting the transfer of Cd to rice and straw. 相似文献
869.
鉴于Br2在交流示波极谱曲线上有切口,提出以盐酸和溴化钾的混合溶液夜底液,用溴酸钾标准溶液直接滴定水样中酚,以Br2的切口出现指示终点,由于本法不受色度,浊度等干优,故省去了预蒸馏等步骤,方法简便,快速。 相似文献
870.
通风换气改善居室空气质量及健康效应的研究 总被引:9,自引:0,他引:9
于1988年12月至1989年4月,对417户有儿童居室的通风换气与呼吸道健康状况进行了调查,并以模拟方式探讨改善措施。结果表明,85%居室每小时换气次数(ACH)介于0.5—1.0之间,ACH与儿童呼吸道每100人周(pw)症状率呈负相关关系(P<0.01),ACH<0.5儿童呼吸道症状率3.52/100pw高于其他组;开窗时ACH为关门窗时的4倍,室内空气中CO_2、HCHO、~(222)Rn浓度关门窗为开门时的1—3倍,室内风速<0.05m/s,通风效率E<1,致使污染物逐渐累积,长期接触有害健康,如若以“对流论”组织通风,则可有效地改善空气质量,增进居民健康。 相似文献