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91.
Heavy metal (Pb,Zn) uptake and chemical changes in rhizosphere soils of four wetland plants with different radial oxygen loss 总被引:4,自引:0,他引:4
Lead and Zn uptake and chemical changes in rhizosphere soils of four emergent-rooted wetland plants; Aneilema bracteatum,
Cyperus alternifolius, Ludwigia hyssopifolia and Veronica serpyllifolia were investigated by two experiments: (1) rhizobag filled with
“clean” or metal-contaminated soil for analysis of Pb and Zn in plants and rhizosphere soils; and (2) applied deoxygenated solution for
analyzing their rates of radial oxygen loss (ROL). The results showed that the wetland plants with di erent ROL rates had significant
e ects on the mobility and chemical forms of Pb and Zn in rhizosphere under flooded conditions. These e ects were varied with
di erent metal elements and metal concentrations in the soils. Lead mobility in rhizosphere of the four plants both in the “clean”
and contaminated soils was decreased, while Zn mobility was increased in the rhizosphere of the “clean” soil, but decreased in the
contaminated soil. Among the four plants, V. serpyllifolia, with the highest ROL, formed the highest degree of Fe plaque on the root
surface, immobilized more Zn in Fe plaque, and has the highest e ects on the changes of Zn form (EXC-Zn) in rhizosphere under both
“clean” and contaminated soil conditions. These results suggested that ROL of wetland plants could play an important role in Fe plaque
formation and mobility and chemical changes of metals in rhizosphere soil under flood conditions. 相似文献
92.
Natural zeolite was modified by loading cetylpyridinium bromide (CPB) to create more e cient sites for humic acid (HA) adsorption.
The natural and CPB modified zeolites were characterized with X-ray di raction, field emission scanning electron microscopy, Fourier
transform infrared spectroscopy and elemental analysis. The e ects of various experimental parameters such as contact time, initial HA
concentration, solution pH and coexistent Ca2+, upon HA adsorption onto CPB modified zeolites were evaluated. The results showed
that natural zeolite had negligible a nity for HA in aqueous solutions, but CPB modified zeolites exhibited high adsorption e ciency
for HA. A higher CPB loading on natural zeolites exhibited a larger HA adsorption capacity. Acidic pH and coexistent Ca2+ were
proved to be favorable for HA adsorption onto CPB modified zeolite. The kinetic process was well described by pseudo second-order
model. The experimental isotherm data fitted well to Langmuir and Sips models. The maximum monolayer adsorption capacity of CPB
modified zeolite with surfactant bilayer coverage was found to be 92.0 mg/g. 相似文献
93.
94.
完善广东省环境应急管理机制研究 总被引:1,自引:0,他引:1
通过对多起北江污染事件(2005年北江镉污染、2010年北江铊污染、2011年武江河锑污染)的案例分析,探究突发环境污染事件的共同特征(由企业违法排污重金属污染物或EPA重点控制优先污染物造成)和演变趋势(影响范围逐渐扩大致应急管理要求逐渐提高),提出重点防控环境优先污染物、整治重污染行业、加强环境承载能力预警、实行强制环境责任保险制度等环境应急管理对策,完善广东省环境应急管理机制. 相似文献
95.
山东省汽车喷涂行业VOCs排放特征研究 总被引:3,自引:1,他引:2
采用气袋采样-气相色谱/质谱法,采集并分析了山东省内小型通用车、货车、电动商务车以及半挂车4类典型汽车喷涂企业挥发性有机物(VOCs)的排放特征。结果表明:山东省汽车喷涂企业中VOCs排放总量以及检出数量排序为:半挂车喷涂企业电动商务车喷涂企业货车喷涂企业小型通用车喷涂企业。各类汽车喷涂企业喷漆以及烘干车间排放的VOCs大多以苯类物质为主(小型通用车面漆烘干车间除外),在小型通用车以及半挂车涂装企业废气中烷烃类物质占比较大。不同企业以及各企业不同工序之间特征VOCs排放浓度有较大差别,喷漆车间特征VOCs浓度要远高于烘干车间。 相似文献
96.
97.
Yanhui Zhan Jianwei Lin Yanling Qiu Naiyun Gao Zhiliang Zhu 《Frontiers of Environmental Science & Engineering in China》2011,5(1):65-75
Surfactant-modified natural zeolites (SMNZ) with different coverage types were prepared by loading hexadecyltrimethyl ammonium
bromide (HTAB) onto the surface of a natural zeolite. The adsorption behavior of humic acid (HA) on SMNZ was investigated.
Results indicate that the adsorbent SMNZ exhibited a higher affinity toward HA than the natural zeolite. HA removal efficiency
by SMNZ increased with HTAB loading. Coexisting Ca2+ in solution favored HA adsorption onto SMNZ. Adsorption capacity decreased with an increasing solution pH. For typical SMNZ
with bilayer HTAB coverage, HA adsorption process is well described by a pseudo-second-order kinetic model. The experimental
isotherm data fitted well with the Langmuir model. Calculated maximum HA adsorption capacities for SMNZ with bilayer HTAB
coverage at pH 5.5 and 7.5 were 63 and 41 mg·g−1, respectively. E2/E3 (absorbance at 250 nm to that at 365 nm) and E4/E6 (absorbance at 465 nm to that at 665 nm) ratios of
the residual HA in solution were lower than that of the original HA solution. This indicates that the HA fractions with high
polar functional groups, low molecular weight (MW), and aromaticity had a stronger tendency for adsorption onto SMNZ with
bilayer HTAB coverage. Results show that HTAB-modified natural zeolite is a promising adsorbent for removal of HA from aqueous
solution. 相似文献
98.
本文详细研究了在硫酸介质中,邻苯氨基苯甲酸与NO_3~-和NO_2~-离子显色体系的光度性质与形成条件。结果表明,显色产物的最大吸收λ_(?)位于560—565nm。在此波长下,表观摩尔吸光系数分别为:ε′NO_3~-=1.07×10~5和ε′NO_2~-=1.77×10~5。符合Beer定律的浓度范围为:0.03—0.15 μg/ml(NO_2~--N)和0.05—0.20 μg/ml(NO_3~--N)。据此,拟定了分光光度联合训定NO_3~--N和NO_2~--N的新方法,应用于地表水的测定,得到了满意的结果。 相似文献
99.
100.
环境污染对生态危害经济损失风险评估模式的综述 总被引:2,自引:0,他引:2
从风险评价和环境经济学角度,综述了环境污染对生态环境危害经济报失的评估模式。 相似文献