西南喀斯特地区石漠化问题研究综述

喀斯特地区石漠化是在脆弱的生态地质背景基础上叠加了人类活动而出现的。西南地区的石漠化面积现仍约以2500km^2／a的速度进一步扩大。石漠化的生态治理工作的目的就是要在人为作用的干扰下,使这种逆向演替转变为顺向演替。石漠化治理思路设计的科学性、战略性、可行性决定了最后石漠化的治理结果。在喀斯特石漠化的治理中,要根据不同岩溶环境类型区及石漠化发育的不同程度和不同山地的立地条件,针对其特点,选择多种途径,运用恰当的恢复技术,制定出具体的开发治理措施,实行规模治理,以提高资源利用率,促进石漠化生态环境的综合治理。     

齐齐哈尔市建华区污染源普查工作的几点体会

介绍了齐齐哈尔市建华区环保局污染源普查工作,严格按照全国污染源普查办的统一要求,开展普查工作.主要工作流程有领导重视、大力宣传、统一思想、培训队伍、做好拉网清查,认真核实汇总,严格审查等工作流程.从而保证了污染源普查工作科学有序、高效优质的圆满完成.     

Effects of humic acid fractions with different polarities on photodegradation of 2, 4-D in aqueous environments

Four fractions (A, B, C, and D) of humic acids (HAs) were separated based on the polarity from weak to strong. UV-vis absorption and Fourier transform infrared spectroscopy (FTIR) analysis show that the fractions C and Dpossessedmore aromatic C=C content. The influences of HAs and their fractions on the photolysis were investigated by the photodegradation of 2,4-D solutions under simulated solar light irradiation. The degradation rate of 2,4-D was found to decrease in the presence of bulk HAs or their fractions especially at high HAs concentration. The fractions of strong polarity C and D retarded the degradation rate more than the fractions of weak polarity A and B. This could be attributed to the different absorption intensity of the four HAs fractions in the order of D ⩾ C > A > B, and the stronger π-π electron donor-acceptor interactions between the strong polar fractions and 2,4-D.     

Occurrence of phthalate esters in water and sediment of urban lakes in a subtropical city, Guangzhou, South China

Extensive use of phthalate esters (PAEs) in both industrial processes and consumer products has resulted in the ubiquitous presence of these chemicals in the environment. This study reports the first data on the concentrations of 16 phthalate esters (PAEs) in water and sediments of the urban lakes in Guangzhou City. PAEs were detected in all samples analyzed, mainly originating from urban stormwater runoff, atmospheric deposition, as well as untreated discharge of industrial wastewater and municipal sewage. The Sigma(16)PAEs concentrations in water and sediments ranged from 1.69 to 4.72 microg L(-1) and 2.27 to 74.94 microg g(-1)-dry weight (dw), with the mean concentrations of 2.91 microg L(-1) and 20.85 microg g(-1)-dw, respectively, which indicates that sediment is a significant sink for PAEs. Variability of the Sigma 16PAEs concentrations in water and sediment in the urban lakes was almost consistent. The spatial distribution of PAEs was site-specific. Of the 16 PAEs, DMP, DEP, DnBP, DiBP, DMPP, and DEHP were present in all water and sediment samples. DnBP was abundant in water (53.0-81.2%), while no single dominant congener was found in sediments. The abundances of DiBP were similar to those of DEHP, and DiBP and DEHP collectively accounted for 77.2-97.6% of the Sigma 16PAEs concentrations. Congener specific analysis confirmed that DnBP was a predictive indicator for the dissolved summation operator16 PAEs concentration (correlation coefficient r=0.968, p<0.01), and that DiBP was a predictive indicator for the sediment summation operator16 PAEs concentration (r=0.975, p<0.01). As compared to the results for other studies, the urban lakes of Guangzhou were moderately polluted by PAEs.     

Study on biosorption kinetics and thermodynamics of uranium by Citrobacter freudii

Biosorption has been developed as an effective and economic method to treat wastewater containing low concentrations of metal pollutants. In this study, a bacterium, Citrobacter freudii, was used as a biosorbent to adsorb uranium ions. The thermodynamics and kinetics of this adsorption, as well as its mechanism, were investigated. The results indicated that the biosorption rate could be better described by a pseudo 2nd-order model than a pseudo 1st-order model. The adsorption of U (VI) proceeded very rapidly in the first 30min and subsequently slowed down continuously for a long period. The biosorption isotherm of uranium by C. freudii could be described well by the Langmuir or Freundlich isotherm, and the latter was better. The thermodynamics parameters, DeltaH degrees , DeltaG degrees , and DeltaS degrees were calculated according to the results of the experiment, which showed this biosorption as being endothermic and spontaneous. The authors investigated the active sites of bacteria for biosorption and the results proved that carboxyl in the cell wall played an important role in biosorption.     

重庆市岩溶地区生态系统脆弱性分析

岩溶地区具有独特的地质地貌,在人为干扰作用影响下很容易导致当地生态系统稳定性降低,生态环境恶化,产生水土流失和石漠化等一系列生态问题。重庆市岩溶区面积占全市总面积的51％,同样面临着一系列的生态环境问题。通过分析岩溶地区生态系统的结构脆弱性、过程脆弱性、功能的脆弱性和人为胁迫脆弱的表现,发现导致生态系统脆弱的原因主要是水文、地质、植被等自然因素和人口压力以及不合理利用等人为因素,针对这些原因为生态系统恢复和重建提供合理建议。     

基于指数平滑技术的水体污染灰色预测模型及应用

文章在分析传统灰色GM（1,1）预测模型所存在的缺陷基础上提出采用指教平滑技术和灰色理论相结合的方法构建一新的ES—GM（1,1）预测模型。新的预测模型通过指数平滑技术和二次累加生成技术将原始的水质污染监测数据进行处理挖掘数据序列潜在的规律性,以2001年到2007年长江南京段水质主要污染监测数据作为实例和传统预测模型进行对比分析计算,结果证明新ES—GM（1,1）的预测模型精度大大提高。长江南京段水质污染预测计算结果表明如果不采取有效的污染预防和控制措施,到2012年COD蜊和BOD5年平均浓度值将分别上升到1．791mg/L和2043mg／L。     

光催化降解馆藏文物环境的低浓度NOx和有机酸

馆藏文物环境中氮氧化物和有机酸对文物材料的破坏性很大,净化难度很大。研究了气-固相下光催化耦合净化馆藏文物环境低浓度NOx与有机酸的效果,探讨了动力学过程。实验结果表明：负载型TiO2/γ-Al2O3光催化剂在可见光照条件下对馆藏文物保护环境下的有机酸和NOx都有良好的降解效果,可达到97%以上。净化效率受到初始浓度的影响较大,但在低浓度下NOx和有机酸之间没有明显的竞争抑制作用,光催化反应过程遵循表观一级反应动力学。     

Field experiment on biological contact oxidation process to treat polluted river water in the Dianchi Lake watershed

In this study two types of biological contact oxidation processes (BCOP), a step-feed (SBCOP) unit and an inter-recycle (IBCOP) unit, were designed to investigate the treatment of heavily polluted river water. The Daqing River, which is the largest pollutant contributor to the Dianchi Lake, one of the most eutrophic freshwater lakes in China, was taken for the case study. It was found that the SBCOP had higher adaptability and better performance in the reduction of COD, TN, and TP, which made it applicable for the treatment of polluted river water entering the Dianchi Lake. Nitrification rate was observed to be greatly affected by the influent temperature. During each season, the nitrification in the SBCOP was higher than that in the IBCOP. TN removal efficiency in the SBCOP was higher than that in the IBCOP during the winter and spring but poorer during the summer, possibly due to the inhibition of denitrification by higher dissolved oxygen level in the summer. Moreover, symbiotic algaebacteria growth may be conducive to the removal of pollutants.     

渤海COD入海通量估算及其分配容量优化研究

在系统分析环渤海地区各种污染源的基础上,估算了1979～2005年渤海COD的入海通量,并基于宏观环境-经济分配容量模型,对渤海COD的环境容量进行了优化分配.结果表明,自20世纪70年代末至今,渤海COD入海通量总体上"M"形变化趋势,年均入海通量180.4万t/a.渤海COD排海总量主要来源于以入海河流为主的陆源排放,高达72.3%;环渤海13个城市中,营口排放所占比例最大高达13.6%,沧州仅为2.5%.在一类水质标准条件下,2005、2010年13城市COD排放均需不同程度的削减,平均削减15.7%和38.3%;在二类水质标准条件下,除2010年潍坊和滨州2市需削减外,其他城市COD排放均满足海洋环境容量的要求.