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61.
Youn Kyu Yi Hyun Soo Kim Tam Tran Sung Kil Hong 《Journal of the Air & Waste Management Association (1995)》2014,64(7):797-807
Recovering valuable metals such as Si, Ag, Cu, and Al has become a pressing issue as end-of-life photovoltaic modules need to be recycled in the near future to meet legislative requirements in most countries. Of major interest is the recovery and recycling of high-purity silicon (>99.9%) for the production of wafers and semiconductors. The value of Si in crystalline-type photovoltaic modules is estimated to be ?$95/kW at the 2012 metal price. At the current installed capacity of 30 GW/yr, the metal value in the PV modules represents valuable resources that should be recovered in the future. The recycling of end-of-life photovoltaic modules would supply >88,000 and 207,000 tpa Si by 2040 and 2050, respectively. This represents more than 50% of the required Si for module fabrication. Experimental testwork on crystalline Si modules could recover a >99.98%-grade Si product by HNO3/NaOH leaching to remove Al, Ag, and Ti and other metal ions from the doped Si. A further pyrometallurgical smelting at 1520ºC using CaO–CaF2–SiO2 slag mixture to scavenge the residual metals after acid leaching could finally produce >99.998%-grade Si. A process based on HNO3/NaOH leaching and subsequent smelting is proposed for recycling Si from rejected or recycled photovoltaic modules.
Implications:The photovoltaic industry is considering options of recycling PV modules to recover metals such as Si, Ag, Cu, Al, and others used in the manufacturing of the PV cells. This is to retain its “green” image and to comply with current legislations in several countries. An evaluation of potential resources made available from PV wastes and the technologies used for processing these materials is therefore of significant importance to the industry. Of interest are the costs of processing and the potential revenues gained from recycling, which should determine the viability of economic recycling of PV modules in the future. 相似文献
62.
New information on the brooding reproduction of Amphiura carchara, and previous studies of several deep-sea congeners, contradict the prevailing notion that direct development is exceptional
among deep-sea echinoderms. Over 500 specimens of A. carchara from 2,850 to 4,100-m depths off the coast of California, USA, were studied. The species was found to be gonochoric, although
most brooding species of ophiuroids are hermaphroditic. Females each brooded up to 72 embryos at a time, with up to 10 in
a single bursa. The embryos of individual adults were often at different stages of development, but those brooded in a single
bursa tended to be at the same stage. Thus, the species has characteristics that breach the distinctions between sequential
and simultaneous brooding exhibited by shallow-water ophiuroids. The embryos developed from yolky eggs that are large for
an ophiuroid, with the mean largest oocytes 0.45 mm, and ranging to 1.28 mm in diameter. Almost all late-stage embryos were
positioned with their mouth and arms pressed against the wall of the bursa, possibly to facilitate the uptake of nutrients
from the parent. Thus, A. carchara may be matrotrophic. The largest embryos examined had a rudimentary disk skeleton, and arms with four joints and a terminal
plate. Emerging juveniles probably differ in disk diameter. The species appears to brood year round, although differences
in gonad size, the incidence of brooding, and the relative numbers of early developmental stages in summer and winter samples
indicated that there are seasonal trends in reproduction.
Received: 14 February 2000 / Accepted: 3 July 2000 相似文献
63.
Nehzat Motallebi Hien Tran Bart E. Croes Lawrence C. Larsen 《Journal of the Air & Waste Management Association (1995)》2013,63(7):876-888
Abstract This paper analyzes day-of-week variations in concentrations of particulate matter (PM) in California. Because volatile organic compounds (VOCs) and oxides of nitrogen (NOx) are not only precursors of ozone (O3) but also of secondary PM, it is useful to know whether the variations by day of week in these precursors are also evident in PM data. Concentrations of PM ≤10 μm (PM10) and ≤2.5[H9262]m in aerodynamic diameter (PM2.5) were analyzed. PM concentrations exhibit a general weekly pattern, with the maximum occurring late in the workweek and the minimum occurring on weekends (especially Sunday); however, this pattern does not prevail at all sites and areas. PM nitrate (NO3 -) data from Size Selective Inlet (SSI) samplers in the South Coast Air Basin (SoCAB) tend to be somewhat lower on weekends compared with weekdays. During 1988–1991, the weekend average was lower than the weekday average at 8 of 13 locations, with an average decrease of 1%. During 1997–2000, the weekend average was lower than the weekday average at 10 of 13 locations, with an average decrease of 6%. The weekend averages are generally lower than weekday averages for sulfates, organic carbon, and elemental carbon. Because heavy-duty trucks typically represent a major source of elemental carbon, the weekend decrease in heavy-duty truck traffic may also result in a decrease in ambient elemental carbon concentrations. 相似文献
64.
Tran B. Nguyen Adam P. Bateman David L. Bones Sergey A. Nizkorodov Julia Laskin Alexander Laskin 《Atmospheric environment (Oxford, England : 1994)》2010,44(8):1032-1042
The chemical composition of secondary organic aerosol (SOA) generated from the ozonolysis of isoprene (C5H8) in the presence of an OH scavenger was examined using high-resolution electrospray ionization mass spectrometry (ESI-MS) in the mass range m/z = 50–1000. The chemical composition of SOA is complex, with more than 1000 assigned peaks observed in the positive and negative ion mode spectra. Only a small fraction of peaks correspond to known products of isoprene oxidation, such as pyruvic acid, glycolic acid, methylglyoxal, etc. The absolute majority of the detected peaks correspond to highly oxidized oligomeric constituents of SOA, with an average O:C molar ratio of 0.6. The corresponding organic mass (OM) to organic oxygen (OO) ratio is 2.4. Approximately 8% of oxygen atoms in SOA are in the form of peroxides, as quantified with an iodide test. Double bond equivalency (DBE) factors, representing the sum of all double bonds and rings, increase by 1 for every 1–2 additional carbon atoms in the molecule. The number of unoxidized CC double bonds is estimated to be less than 10%; the remaining DBE is due to CO carbonyl groups. Kendrick analysis suggests that the prevalent oligomer building blocks are small carbonyls with a C1–C2 skeleton. Formaldehyde (CH2O) is identified as the most common repetitive building block in the observed oligomeric compounds. 相似文献
65.
Tran D Massabuau JC Garnier-Laplace J 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):821-826
Multi-stress situations are a major question and low-oxygenated waters (hypoxia) are a growing problem. Importantly, hypoxia stimulates the ventilatory flow rate in aquatic animals and this increases gill exposure to contaminants. Surprisingly, in the freshwater clam Corbicula fluminea, this is associated with increased bioaccumulation of uranium in gills but not in deep tissues. We searched for an explanation by analyzing hemolymph U-transport in Corbicula exposed to 0.36 μM dissolved uranium at various O2-levels for 10 days. In hypoxia, one observed an increased U concentration in the arterial hemolymph flowing from gills to tissues but this was not associated with an increased U concentration in the venous hemolymph nor in the other tissues. We conclude that the cardiac flow rate must have decreased to explain this absence of over-accumulation. In addition to its already known deleterious effects, uranium can thus deeply impair cardiac flow rate in exposed aquatic animals during multi-stress exposures. 相似文献
66.
Thanigaivel S. Rajendran Saravanan Gnanasekaran Lalitha Chew Kit Wayne Tran Dang Thuan Tran Hoang-Dung Nghia Nguyen Khoi Show Pau Loke 《Environmental Chemistry Letters》2023,21(2):821-837
Environmental Chemistry Letters - Fossil fuel depletion and carbon dioxide emissions are calling for carbon neutral energies such as algal biofuels, yet actual production of agal biofuels is... 相似文献
67.
Ngo Thanh Huy Van Dieu-Anh Tran Hoai Le Nakada Norihide Tanaka Hiroaki Huynh Trung Hai 《Environmental science and pollution research international》2021,28(10):12082-12091
Environmental Science and Pollution Research - This study evaluated the occurrence of PPCPs in Cau River (Vietnam). Surface water and sediment samples were collected to determine PPCP... 相似文献
68.
Nguyen Van-Truc Vo Thi-Dieu-Hien Tran Thanh-Dai Nguyen Thi-Nhu-Khanh Nguyen Thanh-Binh Dang Bao-Trong Bui Xuan-Thanh 《Environmental science and pollution research international》2021,28(45):63558-63571
Environmental Science and Pollution Research - The occurrence of arsenic (As) in groundwater (drilled well water) that were used for drinking, cooking, and personal hygiene and its risks to human... 相似文献
69.
Nguyen Ngoan Thi Thao Nguyen Luan Minh Nguyen Thuy Thi Thanh Nguyen Thuong Thi Nguyen Duyen Thi Cam Tran Thuan Van 《Environmental Chemistry Letters》2022,20(4):2531-2571
Environmental Chemistry Letters - Because many engineered nanoparticles are toxic, there is a need for methods to fabricate safe nanoparticles such as plant-based nanoparticles. Indeed, plant... 相似文献
70.
Le Thuy Minh Pham Phuong Thi Nguyen Truong Quang Nguyen Trung Quang Bui Minh Quang Nguyen Hoa Quynh Vu Nam Duc Kannan Kurunthachalam Tran Tri Manh 《Environmental science and pollution research international》2022,29(31):46767-46777
Environmental Science and Pollution Research - Seven parabens including methylparaben (MeP), ethylparaben (EtP), propylparaben (PrP), iso-propylparaben (iPrP), butylparaben (BuP), benzylparaben... 相似文献