Exposure of traffic police to Polycyclic aromatic hydrocarbons in Beijing, China

Exposure of on-duty traffic police in Beijing to polycyclic aromatic hydrocarbons (PAHs) was investigated during the summer, 2004 using a personal sampling technique in measuring both particulate and gaseous phase PAHs. The results were then compared with those from two control sites away from the street. Exposure levels to gaseous and particulate PAHs for the traffic police were found to be 1525 +/- 759 ngm(-3) and 148 +/- 118 ngm(-3), respectively, representing 2-2.5 times higher levels than those at the control sites. The daily inhalation exposure of the police was estimated to be 277 ngkg(-1)d(-1). Most of the PAHs exposure came from the vapor phase, particularly NAP, FLO and PHE. Based on calculated PAH diagnostic ratios, the major source of PAHs exposure was from vehicle exhaust. The effects of temperature, humidity and atmospheric stability on exposure levels are also discussed.     

Ecotoxicological evaluation of the short term effects of fresh and stabilized textile sludges before application in forest soil restoration

The short term (eco)toxicity potential of fresh and stabilized textile sludges, as well as the short term (eco)toxicity of leachates obtained from both fresh and stabilized textile sludges, was evaluated by a battery of toxicity tests carried out with bacteria, algae, daphnids, fish, earthworms, and higher plants. The (eco)toxicological results showed that, after 120 d of stabilization, the experimental loading ratio of 25% sludge:75% soil (v/v) (equivalent to 64.4 ton/ha) did not significantly increase toxicity effects and increased significantly the biomass yield for earthworms and higher plants. The rank of biological sensitivity endpoints was: Algae approximately Plant biomass > Plant germination approximately Daphnids > Bacteria approximately Fish > Annelids. The lack of short term toxicity effects and the stimulant effect observed with higher plants and earthworms are good indications of the fertilizer/conditioner potential of this industrial waste, which after stabilization can be used in the restoration of a non-productive forest soil.     

Changes in the soil environment from excessive application of fertilizers and manures to two contrasting intensive cropping systems on the North China Plain

Effects of excessive fertilizer and manure applications on the soil environment were compared in greenhouse vegetable systems shifted from wheat-maize rotations 5-15years previously and in wheat-maize rotations. N, P and K surpluses to the greenhouses were 4328, 1337 and 1466kgha(-1)year(-1), respectively compared to 346, 65 and -163kgha(-1)year(-1) to wheat-maize fields. Subsequently, substantial mineral N and available P and K accumulated in the soil and leaching occurred down the soil profile in the greenhouses. Soil pH under vegetables was significantly lower than in the wheat-maize fields, while the EC was significantly higher in the vegetable soils. The mean Cd concentration in the vegetable soils was 2.8 times that in the wheat-maize rotations. Due to excessive fertilizer application in greenhouse vegetable production in northeast China, excessive salt and nitrate concentrations may accumulate and soil quality may deteriorate faster than in conventional wheat-maize rotations.     

Interception of residual nitrate from a calcareous alluvial soil profile on the North China Plain by deep-rooted crops: a 15N tracer study

15N-labeled nitrate was injected into different depths of an alluvial calcareous soil profile on the North China Plain. Subsequent movement of NO3- -N and its recovery by deep-rooted maize (Zea mays L.) and shallow-rooted eggplant (Solanum melongena L.) were studied. Under conventional water and nutrient management the mean recoveries of 15N-labeled nitrate from K(15)NO3 injected at depths 15, 45, and 75 cm were 22.4, 13.8, and 7.8% by maize and 7.9, 4.9, and 2.7% by eggplant. The recovery rate by maize at each soil depth was significantly higher than by eggplant. The deeper the injection of nitrate the smaller the distance of its downward movement and this corresponded with the movement of soil water during crop growth. Deeper rooting crops with high root length density and high water consumption may therefore be grown to utilize high concentrations of residual nitrate in the subsoil from previous intensive cropping and to protect the environment.     

Organic pollutants in compost and digestate. Part 2. Polychlorinated dibenzo-p-dioxins, and -furans, dioxin-like polychlorinated biphenyls, brominated flame retardants, perfluorinated alkyl substances, pesticides, and other compounds

Compost and digestate are important recycling fertilizers and have beneficial effects on soil parameters. However, they can contain significant amounts of organic pollutants. Here, the first comprehensive data set on dibenzo-p-dioxins and -furans (PCDD/F), dioxin-like polychlorinated biphenyls (DL-PCB), brominated flame retardants, perfluorinated alkyl substances (PFAS), pesticides, phthalates, nonylphenol and chlorinated paraffins (CP) in source-separated compost and digestate from Switzerland is presented (n = 3-18). The median summation 17PCDD/F and summation 12DL-PCB concentrations were at 3.2 ng I-TEQ kg(-1)dry weight (dw) and 3.0 ng WHO-TEQ kg(-1)dw, respectively. Brominated diphenyl ether 209 (BDE 209) accounted for 72% of the total polyBDE content (10 microg kg(-1)dw). Hexabromocyclododecane (HBCD) and tetrabromobisphenol A (TBBPA) levels were at 100 and 0.51 microg kg(-1)dw, respectively. PFAS were identified for the first time in compost and digestate (median concentration 6.3 microg kg(-1)dw, summation 21compounds). Out of 269 pesticides analysed, 30 fungicides, 14 herbicides, eight insecticides and one acaricide were detected. Di-(2-ethylhexyl)phthalate (DEHP) median concentration accounted for 280 microg kg(-1)dw and nonylphenol was below the detection limit of 1 mg kg(-1)dw. The sum of short and medium chain CP was between 90 and 390 microg kg(-1)dw. The concentrations observed were at or above the levels found in background soils, which are the main recipient of compost and digestate. Where actually applied, compost can contribute considerably to the total input of organic pollutants to the soil. However, on a total Swiss agricultural area base, inputs seem to be limited.     

Reduction of mercury emissions from anthropogenic sources including coal combustion

Mercury(Hg)ranks number three,after arsenic(As)and lead(Pb),on the Substance Priority List of the Agency for Toxic Substances and Disease Registry(ATSDR,2019).M...     

Test of APEX for nine forested watersheds in East Texas

Hydrologic/water quality models are increasingly used to explore management and policy alternatives for managing water quality and quantity from intensive silvicultural practices with best management practices (BMPs) in forested watersheds due to the limited number of and cost of conducting watershed monitoring. The Agricultural Policy/Environmental eXtender (APEX) model was field-tested using 6 yr of data for flow, sediment, nutrient, and herbicide losses collected from nine small (2.58 to 2.74 ha) forested watersheds located in southwest Cherokee County in East Texas. Simulated annual average stream flow for each of the nine watersheds was within +/- 7% of the corresponding observed values; simulated annual average sediment losses were within +/- 8% of measured values for eight out of nine watersheds. Nash-Sutcliffe efficiency (EF) values ranged from 0.68 to 0.94 based on annual stream flow comparison and from 0.60 to 0.99 based on annual sediment comparison. Similar to what was observed, simulated flow, sediment, organic N, and P were significantly increased on clear-cut watersheds compared with the control watersheds. APEX reasonably simulated herbicide losses, with an EF of 0.73 and R(2) of 0.74 for imazapyr, and EF of 0.65 and R(2) of 0.68 for hexazinone based on annual values. Overall, the results show that APEX was able to predict the effects of silvicultural practices with BMPs on water quantity and quality and that the model is a useful tool for simulating a variety of responses to forest conditions.     

Modeling riverine nitrate export from an East-Central Illinois watershed using SWAT

Reliable water quality models are needed to forecast the water quality consequences of different agricultural nutrient management scenarios. In this study, the Soil and Water Assessment Tool (SWAT), version 2000, was applied to simulate streamflow, riverine nitrate (NO(3)) export, crop yield, and watershed nitrogen (N) budgets in the upper Embarras River (UER) watershed in east-central Illinois, which has extensive maize-soybean cultivation, large N fertilizer input, and extensive tile drainage. During the calibration (1994-2002) and validation (1985-1993) periods, SWAT simulated monthly and annual stream flows with Nash-Sutcliffe coefficients (E) ranging from 0.67 to 0.94 and R(2) from 0.75 to 0.95. For monthly and annual NO(3) loads, E ranged from -0.16 to 0.45 and R(2) from 0.36 to 0.74. Annual maize and soybean yields were simulated with relative errors ranging from -10 to 6%. The model was then used to predict the changes in NO(3) output with N fertilizer application rates 10 to 50% lower than original application rates in UER. The calibrated SWAT predicted a 10 to 43% decrease in NO(3) export from UER and a 6 to 38% reduction in maize yield in response to the reduction in N fertilizer. The SWAT model markedly overestimated NO(3) export during major wet periods. Moreover, SWAT estimated soybean N fixation rates considerably greater than literature values, and some simulated changes in the N cycle in response to fertilizer reduction seemed to be unrealistic. Improving these aspects of SWAT could lead to more reliable predictions in the water quality outcomes of nutrient management practices in tile-drained watersheds.