Temperature and microbial activity effects on trace element leaching from metalliferous peats

Due to geochemical processes, peat soils often have elevated concentrations of trace elements, which are gradually released following drainage for agriculture. Our objectives were to use incubation temperatures to vary microbial activity in two metalliferous peats (M7 acidic peat and M3 neutral peat) from the Elba, New York region, and to use periodic leaching to assess the extent of trace element release from these soils. Dried soils were mixed with glass beads to maintain aeration, moistened, and incubated at 4, 16, 28, and 37 degrees C in 10-cm-diameter x 8-cm-tall columns. Five incubation-leaching cycles were performed, each consisting of 7.3 d of incubation (28 d for the final cycle) followed by 16 h of leaching with synthetic acid rain at 2.5 mm h(-1). Microbial activity was determined initially and after the final leaching by measuring C mineralization following glucose stimulation. Cumulative respiration results were ranked 28 > 16 > 4 > 37 degrees C, with M7 acidic peat respiration values greater than M3 neutral peat at each temperature. Initial leachate pH levels were between 2 and 4, with acidification less pronounced and shorter-lived for the M3 peat. Leachate S, dissolved organic carbon (DOC), NO3-N, and trace elements declined with successive leachings (rebounding slightly in the final M3 leachate), with concentrations typically greater in the M7 leachate. Elemental losses followed the same general ranking (28 > 16 > 4 > 37 degrees C); losses at 28 degrees C were 15 to 22% for As, Cd, Ni, and Zn from the M7 peat; losses from M3 were comparable only for Cu (1%) and Ni (19%). The correlation of respiration with S, DOC, and trace elements losses indicates that microbial processes mediated the release of trace elements in both peat soils. Neutral M3 peat pH levels limited losses of most analytes.     

SURFACE WATER RESOURCES OF NORTHWEST FLORIDA1

ABSTRACT: Of the 1,700 streams located in the state of Florida, the northwest area contains approximately 1,000 streams and three of the five largest rivers, namely the Apalachicola, the Choctawhatchee, and the Escambia. This 11,200 square-mile area contains 11 drainage basins and receives an average annual rainfall which ranges from 53 inches in the east to 67 inches in the west. Basin water yields range from a high of 3,376 cfs (2,180 mgd) to a low of 672 cfs (434 mgd). Individual basin outflows range from a high of 25,743 cfs (16,630 mgd) to a low of 844 cfs (545 mgd). Approximately 67 percent of the total northwest Florida basin outflows to the Gulf of Mexico, or 36,805 cfs (23,766 mgd), are received in the form of surface water inflows from Alabama and Georgia. In the absence of any interstate mechanism for water management between Alabama, Florida, and Georgia, the basin outflow estimates presented in this paper depend greatly on the upstream usage in the neighboring states. The establishment of a tri-state water management program could eliminate the uncertainty involved in predicting water availability in northwest Florida and ensure sufficient quantities of flows in the streams.     

Irrigation development and its environmental consequences in arid regions of India

The present paper examines the nature and dimensions of environmental transformation induced by canal irrigation in the arid region of India. The case study pertains to the Indira Gandhi Canal comand area in Rajasthan where the density and area of vegetation cover have increased due to afforestation, and the cultivated area has expanded due to irrigation. Consequently, there has been a perceptible improvement in the structure and fertility of sandy soils, but it would require a herculean effort on the part of the canal authority and local people to reduce soil erosion and siltation in the lower parts of stage I and the entire command area of stage II. Moreover, the water table has been rising rapidly throughout the command area of stage I. About half of the command area and adjoining Ghaggar basin in Ganganagar District will be facing the danger of waterlogging by the turn of the century. The incidence of irrigation-induced alkalization is higher in the lower parts of stage I. Soil alkalinity has appeared within five years of the introduction of irrigation in the interdunal basins and is manifested as a strong salt regime or calcareous pans near surface. This calls for immediate reclamation of the affected area and prevention of its expansion by altering the strategy of irrigation development, by changing cropping patterns, and by providing soil drainage.     

Prenatal diagnosis of dilated coronary sinus with persistent left superior vena cava in a fetus with trisomy 18

A case of dilated coronary sinus with persistent left superior vena cava diagnosed at 33 weeks in a fetus with trisomy 18 is reported. The features of this cardiac anomaly on prenatal ultrasonography and its association with trisomy 18 are discussed. Published in 2003 John Wiley & Sons, Ltd.     

Microwave treatment and struvite recovery potential of dairy manure

Microwave digestion of liquid dairy manure was tested for the release of nutrients, such as orthophosphates, ammonia-nitrogen, magnesium, calcium and potassium, both with and without the aid of an oxidizing agent (hydrogen peroxide). The orthophosphate to total phosphorus ratio of the manure increased from 21% to greater than 80% with 5 minutes of microwave treatment. More than 36% of total chemical oxygen demand (t-COD) of the manure was reduced when microwave digestion was assisted with peroxide addition. In addition, the volatile fatty acids (VFAs) distribution shifted to simpler chain acids (acetic acid in particular) with an increase in operating temperature. In the second part of the study, digested manure with increased soluble phosphate was tested for the recovery of struvite (magnesium ammonium phosphate) at different pH. It was found that up to 90% of orthophosphate can be removed from the solution. Overall, it was concluded that the oxidizing agent-assisted microwave digestion process can be used upstream of anaerobic digestion, following which the anaerobically digested manure can be used for struvite recovery. Thus, this microwave digestion process presents the potential for enhanced efficiencies in both manure digestion and struvite recovery.     

Non-linear relationship between tourism,economic growth,urbanization, and environmental degradation: evidence from smooth transition models

Environmental Science and Pollution Research - The study aims to analyze two objectives: first is to explore the non-linear relationship between tourism development, economic growth, urbanization,...     

Proteomics of mercury-induced responses and resilience in plants: a review

Environmental Chemistry Letters - Excessive levels of heavy metals in the environment induce toxic effects on food crops and human health. For instance, mercury (Hg) disrupts global plant...