Water purification by sulfide-containing activated carbon

We investigated a new kind of activated carbon named gaiasafe-Formstoff [1] as an agent for powerful heavy metal reduction. This activated carbon contains highly dispersed sulfide compounds. Our investigations with lead containing wastewaters showed an outstanding metal sulfide precipitation power of the new agent. The lead reduction rates are independent of wastewater parameters like lead concentration and complexing agent concentration. Contacted as powder or as a fixed bed with wastewater gaiasafe-Formstoff showed the best cleaning capacity in comparison to all other agents tested. Investigations with gaiasafe-Formstoff about its ability to reduce the contents of further heavy metals in wastewater are under way. The gaiasafe-Formstoff reaction products with wastewater represent an energy-rich and raw material-rich resource when fed to metallurgical processes.     

Ozone fumigation (twice ambient) reduces leaf infestation following natural and artificial inoculation by the endophytic fungus Apiognomonia errabunda of adult European beech trees

In 2006, a controlled infection study was performed in the ‘Kranzberger Forst’ to address the following questions: (1) Will massive artificial inoculation with Apiognomonia errabunda override the previously observed inhibitory effect of chronic ozone? (2) Can biochemical or molecular markers be detected to account for the action of ozone? To this end six adult beech trees were chosen, three ozone fumigated (2× ozone) and three control trees (ambient = 1× ozone). Spore-sprayed branches of sun and shade crown positions of each of the trees, and uninoculated control branches, were enclosed in 100-L plastic bags for one night to facilitate infection initiation. Samples were taken within a five-week period after inoculation. A. errabunda infestation levels quantified by real-time PCR increased in leaves that were not fumigated with additional ozone. Cell wall components and ACC (ethylene precursor 1-amino cyclopropane-1-carboxylic acid) increased upon ozone fumigation and may in part lead to the repression of fungal infection.     

Suitability of using diffusive gradients in thin films (DGT) to study metal bioavailability in mine tailings: possibilities and constraints

Background, aim, and scope  

Diffusive gradients in thin films (DGT) have been recognized as a suitable tool to assess in situ metal bioavailability in soils. Mine tailings have some singular characteristics such as high heavy-metal concentrations, low pH, or absence of water retention capacity that may compromise the correct application of this technique whose applicability is known to be pH dependent. The goal of this study was to determine the response of DGT devices in heavy-metal-polluted mine tailings with different pH. In addition some experiments were performed in order to determine the effect of acidic pH and dissolved ions on the binding properties of the chelating resin.     

Land Degradation on Barren Hills: A Case Study in Northeast Vietnam

The term "barren hills" has been a keyword for land degradation in the uplands of Vietnam for over a decade. Nevertheless, the "barren" land is still not adequately ecologically characterized. In this work, we analyze land use-induced changes in vegetation and soil properties along a sequence of barren hills types formed on one physiotope. The study is undertaken in the Bac Kan province, one of the poorest upland regions where livestock plays an important role. A transition from an old-growth laurel forest to a sparse manmade grassland is characterized by a total of 177 species, rapid species turnover, and discrete dominants, and an overwhelming effect of disturbance history on both soil and vegetation patterning. Land degradation is most apparent in land use-induced maintenance of arrested successions, and the regeneration course is shifted towards drier formations. We hypothesize a conceptual model as an aid to understanding the process of early fallow differentiation in response to the patterned, fine-scale disturbances. The larger-scale implications of the observed trends in regeneration potentials deviation, and, in particular, the effect of water buffaloes in halting fallow successions, are discussed.     

Testing a Scandinavian Biodiversity Assessment Tool in an African Desert Environment

Life cycle assessment-based environmental product declarations (EPDs) require the inclusion of biodiversity impacts across the entire supply chain. The objective of this study is to test the applicability of a Scandinavian biodiversity assessment tool, developed specifically for use with EPD applications, in an African desert environment, linking the industry types power generation and mining. For this purpose, a GIS-based spatial analysis tool—the biotope method—was adapted to a framework approach which allowed the selection of more suitable, site-specific biodiversity indicators. The biotope method provides a step-by-step process of defining system boundaries, mapping biotopes, categorizing biotopes based on site-specific indicators, and evaluating change in biotope status “before” and “after” the impact. The development of site-specific indicators was piloted in this study and determined by the affected ecosystem and the status of knowledge on biodiversity in this geographic area. Thus plants were used as indicators for biodiversity, and red-list status and endemism constituted the prime criteria for conservation value of plants. This in turn represented the key criterion for classifying biotopes. The tested biodiversity assessment tool has potential for application in different environments and operational settings but leaves room for improvement by including secondary impacts in the assessment and using a wider range of taxa for indicators of biodiversity.     

Framing natural assets for advancing sustainability research: translating different perspectives into actions

Sustainability is a key challenge for humanity in the context of complex and unprecedented global changes. Future Earth, an international research initiative aiming to advance global sustainability science, has recently launched knowledge–action networks (KANs) as mechanisms for delivering its research strategy. The research initiative is currently developing a KAN on “natural assets” to facilitate and enable action-oriented research and synthesis towards natural assets sustainability. ‘Natural assets’ has been adopted by Future Earth as an umbrella term aiming to translate and bridge across different knowledge systems and different perspectives on peoples’ relationships with nature. In this paper, we clarify the framing of Future Earth around natural assets emphasizing the recognition on pluralism and identifying the challenges of translating different visions about the role of natural assets, including via policy formulation, for local to global sustainability challenges. This understanding will be useful to develop inter-and transdisciplinary solutions for human–environmental problems by (i) embracing richer collaborative decision processes and building bridges across different perspectives; (ii) giving emphasis on the interactions between biophysical and socioeconomic drivers affecting the future trends of investments and disinvestments in natural assets; and (iii) focusing on social equity, power relationships for effective application of the natural assets approach. This understanding also intends to inform the scope of the natural asset KAN’s research agenda to mobilize the translation of research into co-designed action for sustainability.     

Assessment of heavy metal releases from the use phase of road transport in Europe

An emission inventory was compiled for heavy metal air emissions from road transport in Europe (EU-40). For the database, country-specific data was taken such as the diesel and gasoline fuel consumption per country, the content of Pb in gasoline and diesel fuel and the share of different vehicle types. For tyre and brake wear emissions, average wear rates and heavy metal contents of different materials were used to develop emission factors for tyre and brake wear. It covers exhaust emissions (Pb from gasoline and diesel) as well as non-exhaust emissions (As, Cd, Cr, Ni and Pb from the wear of brake linings and vehicle tyres). The base year is 2000, and two scenarios were developed for 2010, a business as usual (BAU) scenario and a maximum feasible technical reduction (MFTR) scenario. Both result in a remarkable decrease in Pb exhaust emissions and a rising share of non-exhaust emissions. To assess the results, the inventory is (a) compared to an inventory compiled with a top-down approach that covers the same area and years but only emissions from combustion processes and (b) added to an inventory covering all sectors for heavy metal air emissions.     

Assessing the spatial distribution of grassland age in a marginal European landscape

Grassland age is increasingly recognised to be an indicator for present-day biodiversity, e.g. plant species richness, and is also important for other landscape functions. We developed a methodological approach to systematically assess the spatial distribution of grassland age in marginal European landscapes. This approach - applied to the Lahn-Dill Highlands (1270 km(2)), a marginal landscape in Hesse, Germany - comprises three steps: (1) in a two-stage stratification process, we pre-stratified the study area according to recent land-cover patterns and their changes between 1955 and 1995 (stratification I) and classified grassland types by combining data on soil moisture, base-richness, and elevation (stratification II). From 50 grassland types, we randomly selected 1000 representative grassland patches. (2) We determined the age of these patches by means of aerial photograph interpretation of a chronosequence dating back to 1953 and classified each patch with respect to the age classes young (<18 years), mid-aged (18-47 years), and old (>47 years). (3) Based on this information, we calculated grassland type-specific probabilities for grassland patches to belong to the respective age classes. These probabilities were projected to districts by direct extrapolation. An exemplary validation of extrapolation results for two test areas was performed. The results revealed that 49% of the investigated patches were old grassland. The remaining patches were mid-aged (36%) or young grassland (15%). The extrapolation results indicated accordingly a predominance of old grassland at the district scale. Occurrences of mid-aged grassland were concentrated in districts with a pronounced land-cover change, whereas young grassland is apparently evenly distributed across the study area. Validation results suggest that our approach is suitable for a realistic estimation of grassland age in marginal European landscapes. The method may be applied in landscape models of various disciplines that rely on large-scale information on grassland age.     

Cu and Zn mobilization in soil columns percolated by different irrigation solutions

We investigated the effects of different concentrations of nitrate and ammonium in irrigation water on the mobilization of Zn and Cu in repacked soil columns with a metal-polluted topsoil and unpolluted subsoils over two and a half years. Soil solution samples were collected by suction cups installed at vertical distances of a few centimeters and analyzed for dissolved organic carbon (DOC), Cu, and Zn (total and labile). During high N treatments the pH decreased and the presence of exchangeable cations resulted in Zn mobilization from the surface soil. The nitrogen input stimulated the biological activity, which affected both concentration and characteristics of DOC and consequently Cu speciation. Metal leaching through the boundary between the polluted topsoil and the unpolluted subsoils increased soil-bound and dissolved metals within the uppermost 2 cm in the subsoils. Our study shows that agricultural activities involving nitrogen fertilization can have a strong influence on metal leaching and speciation.