Formulation and Characterization of Biodegradable Packaging Film Derived from Potato Starch &; LDPE Grafted with Maleic Anhydride—LDPE Composition

There is a paradigm shift from non renewal resources to renewable resources in view of problems of disposal of plastic products after their life cycle. This paper deals with the approach, preparation and product properties of polymer prepared by using polysaccharide based biodegradable polymer. Basic material has been prepared by mixing LDPE, LDPE-g-mA (LDPE grafted with (0.5%) maleic anhydride (1:1)) containing a polar group in the LDPE backbone. Prepared basic material has been compounded in twin screw extruder with 0, 2.5, 5.0, 7.5, 10.0, 12.5 & 15% of Potato Starch. Thereafter, after conditioning blown film samples were prepared using extrusion film blowing technique, under temperature profile ranging from 120 to 160 °C. Packaging films have been prepared with maximum 15% potato starch contents and have been characterized by FTIR, DSC, TGA, and XRD techniques to ascertain its impact on some structural and thermal properties like thermal stability, flexibility, crystallinity, crystal size etc.     

Altitude distribution of aerosols over Southeast Arabian Sea coast during pre-monsoon season: Elevated layers,long-range transport and atmospheric radiative heating

Every year, during the pre-monsoon period (March–May), a pronounced increase in aerosol optical depth (AOD) is observed over the eastern Arabian Sea, which is attributed to the transport of continental aerosols. This paper presents the altitude distribution of tropospheric aerosols, characteristics of elevated aerosol layers and aerosol radiative heating of the atmosphere during the pre-monsoon season over Trivandrum (8.5°N, 77°E), a station located at the southwest coast of Indian peninsula which is covered by the eastern Arabian Sea plume. Altitude profiles of aerosol backscatter coefficient (β_a) and linear depolarization ratio (LDR) reveal two distinct aerosol layers persisting between 0–2 km and 2–4 km. The layer at 2–4 km, which contributes about 25% of the AOD during polluted conditions, contains significant amount of non-spherical aerosols. This layer is prominent only when the advection of dry airmass occurs from the northern parts of the Indian subcontinent and northern Arabian Sea. Role of long-range transport in the development of this aerosol layer is further confirmed using latitude–altitude cross-section of β_a observed by CALIPSO. Aerosol content in the layer below 2 km is large when advection of air occurs from the north and east Arabian Sea and is significantly small when it occurs from the southwest Arabian Sea or Indian Ocean. During the highly polluted conditions, aerosols tend to increase the diurnal mean atmospheric radiative heating rate by ～0.8 K day^?1 at 500 m and 0.3 K day^?1 at 3 km, which are about 80% and 30% of the respective radiative heating in the aerosol-free atmosphere.     

Short-term wind speed forecasting: Application of linear and non-linear time series models

This study forecasts day-ahead wind speed at 15 minute intervals at the site of a wind turbine located in Maharashtra, India. Wind speed exhibits non-stationarity, seasonality and time-varying volatility clustering. Univariate linear and non-linear time series techniques namely MSARIMA, MSARIMA-GARCH and MSARIMA-EGARCH have been employed for forecasting wind speed using data span ranging from 3 days to 15 days. Study suggests that mean absolute percentage error (MAPE) values first decrease with the increase in data span, reaches its minima and then start increasing. All models provide superior forecasting performances with 5 days data span. It is further evident that ARIMA-GARCH model generates lowest MAPE with 5 days data span. All these models provide superior forecasts with respect to current industry practices. This study establishes that employing various linear and non-linear time series techniques for forecasting day-ahead wind speed can benefit the industry in terms of better operational management of wind turbines and better integration of wind energy into the power system, which have huge financial implications for wind power generators in India.     

Integrated bioleaching of copper metal from waste printed circuit board—a comprehensive review of approaches and challenges

Waste electrical and electronic equipment (e-waste) is the most rapidly growing waste stream in the world, and the majority of the residues are openly disposed of in developing countries. Waste printed circuit boards (WPCBs) make up the major portion of e-waste, and their informal recycling can cause environmental pollution and health risks. Furthermore, the conventional disposal and recycling techniques—mechanical treatments used to recover valuable metals, including copper—are not sustainable in the long term. Chemical leaching is rapid and efficient but causes secondary pollution. Bioleaching is a promising approach, eco-friendly and economically feasible, but it is slower process. This review considers the recycling potential of microbes and suggests an integrated bioleaching approach for Cu extraction and recovery from WPCBs. The proposed recycling system should be more effective, efficient and both technically and economically feasible.     

<Emphasis Type="Bold">Tracing lead contamination in foods in the city of Kolkata,India</Emphasis>

Lead isotopic ratios (LIR) of eight common food items, street dust, coal, diesel, sediments, lead ore and rainwater from India have been reported for the first time in this paper. This study characterized the source and extent of lead pollution in the different foodstuff consumed in Kolkata, a major metropolis of eastern India. The atmospheric lead input to the food items, sold openly in busy roadside markets of the city, has been quantified. The mean 207/206 and 208/206 LIRs of the eight food items ranged from 0.8847 to 0.8924 and 2.145 to 2.167, respectively. Diesel had the highest mean 207/206 and 208/206 values of 0.9015 and 2.1869, respectively, apart from the lead ore. The food items had a mean lead concentration between 3.78 and 43.35 mg kg^?1. The two ratio scatter plots of all the different environmental matrices were spread linearly between the uncontaminated Ichapur sediment and diesel. The 207/206 LIRs of the coal with a mean of 0.8777 did not fall in the linear trend, while the street dust and food samples overlapped strongly. The rainwater sample had a 207/206 LIR of 0.9007. Contaminated sediments in Dhapa, the repository of the city’s municipal garbage, had a mean 207/206 LIR of 0.8658. The corresponding value obtained from the sewage-fed vegetable grown there was 0.8058. The present study indicated that diesel was one of the main contributor to Pb pollution. The atmospheric lead contribution to the food items was in the range of 68.48–86.66 %.     

Cell cycle stage specific application of municipal landfill leachates to assess the genotoxicity in root meristem cells of barley (Hordeum vulgare)

Municipal solid wastes (MSW) are unavoidable sources of environmental pollution. Improper disposal of municipal waste results in the leaching of toxic metals and organic chemicals, which can contaminate the surface and ground water leading to serious health hazard. In this study, the toxic effects of the leachate prepared from municipal solid waste samples were examined in root meristem cells of barley (Hordeum vulgare L.) at various stages of cell cycle, i.e., G₁, S, and G₂. Seeds of barley were exposed to 2.5, 5, and 10 % of leachates in soil and aqueous media in 48 h at different cell cycle stages. The physicochemical data of the present study revealed that municipal solid waste leachate contains high amount of heavy metals, which significantly affected growth and physiological activities of barley. Significant inhibition in hypocotyl length, germination, and mitotic index were observed at all concentration of leachate treatment. Induction of chromosomal aberrations (CA’s) and micronuclei (MN) formation were also observed with different concentrations of leachate treatment at 7, 17, and 27 h of presoaking durations, which falls in G₁, S, and G₂ phase of the cell cycle, respectively. Also, exposure of leachate at S phase of the cell cycle had significant effects in barley through chromosomal aberration and micronuclei formation.     

Emissions Variability Processor (EMVAP): Design,evaluation, and application

Emissions of pollutants such as SO₂ and NOx from external combustion sources can vary widely depending on fuel sulfur content, load, and transient conditions such as startup, shutdown, and maintenance/malfunction. While monitoring will automatically reflect variability from both emissions and meteorological influences, dispersion modeling has been typically conducted with a single constant peak emission rate. To respond to the need to account for emissions variability in addressing probabilistic 1-hr ambient air quality standards for SO₂ and NO₂, we have developed a statistical technique, the Emissions Variability Processor (EMVAP), which can account for emissions variability in dispersion modeling through Monte Carlo sampling from a specified frequency distribution of emission rates. Based upon initial AERMOD modeling of from 1 to 5 years of actual meteorological conditions, EMVAP is used as a postprocessor to AERMOD to simulate hundreds or even thousands of years of concentration predictions. This procedure uses emissions varied hourly with a Monte Carlo sampling process that is based upon the user-specified emissions distribution, from which a probabilistic estimate can be obtained of the controlling concentration. EMVAP can also accommodate an advanced Tier 2 NO₂ modeling technique that uses a varying ambient ratio method approach to determine the fraction of total oxides of nitrogen that are in the form of nitrogen dioxide. For the case of the 1-hr National Ambient Air Quality Standards (NAAQS, established for SO₂ and NO₂), a “critical value” can be defined as the highest hourly emission rate that would be simulated to satisfy the standard using air dispersion models assuming constant emissions throughout the simulation. The critical value can be used as the starting point for a procedure like EMVAP that evaluates the impact of emissions variability and uses this information to determine an appropriate value to use for a longer term (e.g., 30-day) average emission rate that would still provide protection for the NAAQS under consideration. This paper reports on the design of EMVAP and its evaluation on several field databases that demonstrate that EMVAP produces a suitably modest overestimation of design concentrations. We also provide an example of an EMVAP application that involves a case in which a new emission limitation needs to be considered for a hypothetical emission unit that has infrequent higher-than-normal SO₂ emissions.

ImplicationsEmissions of pollutants from combustion sources can vary widely depending on fuel sulfur content, load, and transient conditions such as startup and shutdown. While monitoring will automatically reflect this variability on measured concentrations, dispersion modeling is typically conducted with a single peak emission rate assumed to occur continuously. To realistically account for emissions variability in addressing probabilistic 1-hr ambient air quality standards for SO₂ and NO₂, the authors have developed a statistical technique, the Emissions Variability Processor (EMVAP), which can account for emissions variability in dispersion modeling through Monte Carlo sampling from a specified frequency distribution of emission rates.     

Fish diversity,habitat ecology and their conservation and management issues of a tropical River in Ganga basin,India

In the present communication habitat ecology, species diversity; distribution and different indices of fish biodiversity management were studied in a Central India river (River Betwa, a tributary of River Ganga basin approved under India’s first river linking plan). Correlation between fish species richness with the hydrological attributes showed good relationship and water depth, dissolved oxygen and pH were found the most important variables in shaping fish assemblage. Altogether, sixty-three fish species belonging to 20 families and 45 genera were collected from five sampling stations spread along the upstream, mid stream and lower streams. Cyprinids were the most dominated group represented by 26 species belonging to 15 genera, followed by Bagridae (6 species from 3 genera), and Schilbeidae (4 species from 4 genera). The distribution of fish showed interesting pattern and about 10% species were common to all the sites showing long migration range. Shannon-Weiner diversity index showed considerable variation and ranged from 1.89 to 3.51. Out of 63 species status of 10 species were not known due to data deficit, 29 categorized as lower risk, 14 as vulnerable, 8 as endangered, while the remaining two species were introduced. Our study shows that the River supports considerable diversity of the fishes and is important for conservation and about 34% fish fauna is threatened being either vulnerable or endangered. We assessed that the river supports considerable percentage of food fish (89.47), ornamental fish (49.12%) and sport fish (5.26%). Among the eight major types of fish habitats identified along the entire stretch of river, open river, shallow water and deep pools were habitats contributing maximum diversity. Fish species richness (FSR) were significantly different (P < 0.05) in all the habitats except channel confluence and scour pool. Trophic niche model may be useful for assessing altered as well as less altered fish habitat of the tropical rivers. Since this river will be interlinked in near future, this study would be useful for conservation planning and management and also for future assessment after interlinking. Issues related to various threats to aquatic environment and conservation management strategies have been discussed.     

Post-tsunami changes in the littoral environment along the southeast coast of India

The 26th December 2004 Indian Ocean tsunami devastated coastal regions of the Indian subcontinent. Andaman and Nicobar Islands, coastal stretches of Tamil Nadu, Andhra Pradesh and Kerala were the most affected regions of India. Changes in the beach profiles, long shore currents, breaking wave characteristics in the surf zone at selected locations along the Tamil Nadu coast were studied during January, April, October 2005 and January 2006. Long shore sediment transport rates were estimated from the observed parameters. Studies were carried out earlier (1995-1996 and 1998) to understand the coastal environment over a one-year cycle in the study region. The post-tsunami observations were compared with the earlier studies to establish the variations in the littoral environment and to ascertain the normalcy of the littoral environment in the post-tsunami scenario. From the changes in the beach profiles, the shoreline was observed to recede by about 20m and built-up of backshore by about 0.5m at most locations. Observations from the field investigations and comparisons with earlier studies along this stretch of the coastline indicate that the coastline is yet to return completely to normalcy.