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31.
Solid phase extraction for evaluation of occupational exposure to Pb (II) using XAD-4 sorbent prior to atomic absorption spectroscopy. 总被引:2,自引:0,他引:2
Seyed Jamaleddin Shahtaheri Monireh Khadem Farideh Golbabaei Abbas Rahimi-Froushan Mohammad Reza Ganjali Parviz Norouzi 《International journal of occupational safety and ergonomics》2007,13(2):137-145
Lead is an important constituent widely used in different industrial processes. For evaluation of workers' exposure to trace toxic metal of Pb (II), solid-phase extraction (SPE) was optimized. SPE using mini columns filled with XAD-4 resin was developed with regard to sample pH, ligand concentration, loading flow rate, elution solvent, sample volume, elution volume, the amount of resins, and sample matrix interferences. Lead ions were retained on a solid sorbent and then eluted, followed by a simple determination of analytes with flame atomic absorption spectrometery. The obtained recoveries of metal ions were greater than 92%. This method was validated with 3 different pools of spiked urine samples; it showed a good reproducibility over 6 consecutive days as well as 6 within-day experiments. This optimized method can be considered successful in simplifying sample preparation for a trace residue analysis of lead in different matrices when evaluating occupational and environmental exposures is required. 相似文献
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Jaber?Aazami Abbas?Esmaili Sari Asghar?Abdoli Hormoz?Sohrabi Paul?J.?Van den?BrinkEmail author 《Environmental management》2015,56(1):260-269
The objectives of this study were to assess the biological water of the Iranian Tajan River using different metrics, i.e., a Multimetric Macroinvertebrate Index (MMI) and a traits-based method. Twenty-eight physico-chemical parameters, 10 habitat factors, and abundance of macroinvertebrates were obtained for 17 sites. The Shahid-Rajaie dam divides the Tajan River into an up- and downstream part, with different land uses. Eighteen metrics were used to represent four components of ecosystem quality, including tolerance (Hilsenhoff, SIGNAL), diversity (Margalef, Shannon–Wiener, Simpson, and Evenness), abundance (total number of taxa, individuals, Ephemeroptera, Plecoptera, Trichoptera, EPT, and Insects), and composition of assemblages (% Ephemeroptera, % Plecoptera, % Trichoptera, and % EPT Taxa). The integrated MMI was calculated by averaging the obtained scores of all indices. In the next step, we gathered information on 22 biological traits of macroinvertebrates to evaluate whether (group of) traits could be identified that are indicative for specific or general stress. Result showed a decrease in MMI from upstream (very good water quality) to downstream (bad) due to human activities. Industrial activities like pulping and papermaking operations or sand mining in the downstream part had more effects than agriculture and fish ponds in the upstream part. A redundancy analysis biplot showed the variation between the modalities of trait of macroinvertebrates and their correlation with physico-chemical parameters in Tajan River. The findings show that traits can be indicative for different kind of stress but that more effort has to be put in gathering data sets to disentangle the effect of habitat quality, pollution, and the physico-chemical properties of high- versus lowland rivers. 相似文献
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High-surface-area mesoprous powders of γ-Al2O3 doped with Cu2 +, Cr3 +, and V3 + ions were prepared via a modified sol–gel method and were investigated as catalysts for the oxidation of chlorinated organic compounds. The composites retained high surface areas and pore volumes comparable with those of undoped γ-Al2O3 and the presence of the transition metal ions enhanced their surface acidic properties. The catalytic activity of the prepared catalysts in the oxidation of 1,2-dichloroethane (DCE) was studied in the temperature range of 250–400°C. The catalytic activity and product selectivity were strongly dependent on the presence and the type of dopant ion. While Cu2 +- and Cr3 +-containing catalysts showed 100% conversion at 300°C and 350°C, V3 +-containing catalyst showed considerably lower conversion. Furthermore, while the major products of the reactions over γ-alumina were vinyl chloride (C2H3Cl) and hydrogen chloride (HCl) at all temperatures, Cu- and Cr-doped catalysts showed significantly stronger capability for deep oxidation to CO2. 相似文献
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Parsaie Abbas Haghiabi Amir Hamzeh Latif Sarmad Dashti Tripathi Ravi Prakash 《Environmental science and pollution research international》2021,28(43):60842-60856
Environmental Science and Pollution Research - Predictions of pore pressure and seepage discharge are the most important parameters in the design of earth dams and assessing their safety during the... 相似文献
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Malik Summaira Iqbal Asim Imran Asma Usman Muhammad Nadeem Muhammad Asif Saira Bokhari Awais 《Environmental science and pollution research international》2021,28(26):34017-34026
Environmental Science and Pollution Research - The utilization of economic capabilities to raise production in the economy enhances the industrial activities and use of transportation. These... 相似文献
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Zhang Yaming Abbas Majed Koura Yaya Hamadou Su Yanyuan Iqbal Wasim 《Environmental science and pollution research international》2021,28(6):6913-6928
Environmental Science and Pollution Research - As a major source of pollution and the cause of climate change, greenhouse gas emissions are attracting the attention of scholars, policymakers, and... 相似文献
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Sanaei Fatemeh Amin Mohammad Mehdi Alavijeh Zhaleh Pourjam Esfahani Rana Azaripour Sadeghi Maryam Bandarrig Niayesh Shabankare Fatehizadeh Ali Taheri Ensiyeh Rezakazemi Mashallah 《Environmental science and pollution research international》2021,28(2):1479-1490
Environmental Science and Pollution Research - The aim of this study is to assess the content of heavy metals and their potential health risk in consumed food crops. To this end, the samples from... 相似文献