Production and application of anaerobic granular sludge produced by landfill

Sludge granulation is considered to be the most critical parameter governing successful operation of an upflow anaerobic sludge blanket and expanded granular sludge bed(EGSB)reactors.Pre-granulated seeding sludge could greatly reduce the required start- up time.Two lab-scale and a pilot-scale EGSB reactors were operated to treat Shaoxing Wastewater Treatment Plant(SWWTP) containing wastewater from real engineering printing and dyeing with high pH and sulfate concentration.The microbiological structure and the particle size distribution in aerobic excess sludge,sanitary landfill sludge digested for one year,and the granular sludge of EGSB reactor after 400 d of operation were analyzed through scanning electron microscopy (SEM) and sieves.The lab-scale EGSB reactor seeded with anaerobic sludge after digestion for one year in landfill showed obviously better total chemical oxygen demand (TCOD)removal efficiency than one seeded with aerobic excess sludge after cation polyacrylamide flocculation-concentration and dehydration.The TCOD removed was 470.8 mg/L in pilot scale EGSB reactor at short hydraulic retention time of 15 h.SEM of sludge granules showed that the microbiological structure of the sludge from different sources showed some differences.SEM demonstrated that Methanobacterium sp.was present in the granules of pilot-scale EGSB and the granular sludge produced by landfill contained a mixture of anaerobic/anoxic organisms in abundance.The particle size distribution in EGSB demonstrated that using anaerobic granular sludge produced by sanitary landfill as the seeding granular sludge was feasible.     

How to bend down the environmental Kuznets curve: the significance of biomass energy

Sources of renewable energy have received wide attention in the literature because of serious threats to the environment. However, some renewable resources, including biomass energy role is debatable in the energy economics literature. This empirical work focuses to analyze the role of biomass energy in carbon dioxide (CO₂) emissions using the framework of the environmental Kuznets curve (EKC) in Pakistan over the period from 1980 to 2015. The bound testing approach suggests there is cointegration among study variables. The study uses an auto-regressive distributed lag model (ARDL) with a structural break in the series. To summarize the findings of the study, it can be inferred that biomass energy increase CO₂ emissions. In addition, biomass energy helps to form a U-shaped relationship between income and CO₂ emissions that support the EKC hypothesis. Also, the feedback hypothesis is found between biomass energy and CO₂ emissions. The findings would guide policymaker with practical guidelines to formulate policies to utilize a high amount of biomass energy in a sustainable manner.

     

Effect of Oxidized Starch on Morphology,Rheological and Tensile Properties of Low-Density Polyethylene/Linear Low-Density Polyethylene/Thermoplastic Oxidized Starch Blends

In this work, morphology, rheological and tensile properties of low-density polyethylene/linear low-density polyethylene/thermoplastic oxidized starch (LDPE/LLDPE/TPOS) blends are studied. The blends of LDPE/LLDPE (70/30, w/w) containing 0–20 wt% TPOS in the presence of 3 wt% of PE-grafted maleic anhydride (PE-g-MA) as a compatibilizer are prepared by a twin screw extruder and then converted to appropriate thin films using an extrusion film blowing machine. Scanning electron microscopic images show that there is a relative good dispersion of oxidized starch particles in PE matrices. However, as TPOS content in the blends increases, the starch particle size increases too. The rheological analyses indicate that TPOS can decrease the elasticity and viscosity of the blends. The LDPE/LLDPE/TPOS blends show power-law behavior and as the TPOS content increases the power-law exponent (n) and consistency index (K) decrease. The ultimate tensile strength and elongation at break of the final blend films reduce, when TPOS content increases from 5 to 20 wt%. However, the required mechanical properties for packaging applications are achieved when 10 wt% oxidized starch is added, according to ASTM D4635.     

An awareness campaign decreases distracted driving among hospital employees at a rural trauma center

Abstract

Objective: To evaluate whether an educational campaign on distracted driving will have an impact in a given community.

Methods: Investigators were stationed in an employee parking lot of a 256-bed hospital to determine baseline distracted driving followed by a 4-week hospital-wide distracted-driving awareness campaign. The campaign included signs/posters in the hospital, a booth outside of the cafeteria with flyers, a large banner in the employee lot and an opportunity for people to sign a pledge form to drive distraction free. The same employee lot was observed at the same time of the day to re-assess distracted driving immediately following the campaign. The observations were repeated again one year later to evaluate the short and long-term impact of the campaign.

Results: A total of 485 vehicles were observed pre-campaign, identifying 170 (35%) distracted drivers at baseline. The awareness campaign resulted in 525 people pledging to drive distraction free. Following the campaign, 495 vehicles were observed and the number of distracted drivers was 64 (12.9%), showing a significant decrease in the number of distracted drivers by 22.1% (p?<?0.01). One year later, 530 drivers were observed with 150 (28%) displaying one form of distraction.

Conclusions: A local distracted driving educational campaign resulted in a significant decrease in the number of distracted drivers immediately following the campaign. However, one year after the campaign, there was an increase in distracted driving. The proportion of distracted drivers was still significantly lower than the initial rate of distracted-drivers.     

Diesel reformulation using bio-derived propanol to control toxic emissions from a light-duty agricultural diesel engine

In the Indian agricultural sector, millions of diesel-driven pump-sets were used for irrigation purposes. These engines produce carcinogenic diesel particulates, toxic nitrogen oxides (NOx), and carbon monoxide (CO) emissions which threaten the livelihood of large population of farmers in India. The present study investigates the use of n-propanol, a less-explored high carbon bio-alcohol that can be produced by sustainable pathways from industrial and crop wastes that has an attractive opportunity for powering stationary diesel engines meant for irrigation and rural electrification. This study evaluates the use of n-propanol addition in fossil diesel by up to 30% by vol. and concurrently reports the effects of exhaust gas recirculation (EGR) on emissions of an agricultural DI diesel engine. Three blends PR10, PR20, and PR30 were prepared by mixing 10, 20, and 30% by vol. of n-propanol with fossil diesel. Results when compared to baseline diesel case indicated that smoke density reduced with increasing n-propanol fraction in the blends. PR10, PR20, and PR30 reduced smoke density by 13.33, 33.33, and 60%, respectively. NOx emissions increased with increasing n-propanol fraction in the blends. Later, three EGR rates (10, 20, and 30%) were employed. At any particular EGR rate, smoke density remained lower with increasing n-propanol content in the blends under increasing EGR rates. NOx reduced gradually with EGR. At 30% EGR, the blends PR10, PR20, and PR30 reduced NOx emissions by 43.04, 37.98, and 34.86%, respectively when compared to baseline diesel. CO emissions remained low but hydrocarbon (HC) emissions were high for n-propanol/diesel blends under EGR. Study confirmed that n-propanol could be used by up to 30% by vol. with diesel and the blends delivered lower soot density, NOx, and CO emissions under EGR.     

Fabrication and Characterization of Polyaniline Based Nano-Composite with Their Physico-Chemical and Environmental Applications

A series of organic–inorganic conducting nano polymer-matrix composite cation-exchanger have been synthesized via sol–gel method and characterized through FTIR, XRD, TGA-DTA, SEM, and TEM studies. The structural studies confirm the semi-crystalline nature of the material but the morphology of the exchanger gets changed after incorporation of inorganic moiety. The particle size of the nano-composite was found to be 19.2 nm. The observed band gap for the different samples was found to be in the range of 3.70–4.61 eV which shows that nano-composite material covers semiconducting range but the resistivity of samples is highly dependent on the percentage of inorganic part in the composite. Further the oxidative degradation of the polymer backbone begins after the removal of trapped water successively followed by dopant and low molecular weight oligomers. During the antimicrobial screening, the nano-composite was found to be active against different strains of bacteria and fungi. Gel electrophoresis and molecular docking studies were carried out to check the interaction and mechanism of inhibition of microbial growth, respectively by studying the effect of the nano-composite with DNA-Topoisomerase-1.     

Medium-scale gasification of oil palm empty fruit bunch for power generation

Journal of Material Cycles and Waste Management - This paper focuses on the performance of oil palm empty fruit bunch (EFB) gasification using a medium-scale downdraft gasifier for power...     

DDT residue in soil and water in and around abandoned DDT manufacturing factory

Dichlorodiphenyltrichloroethane (DDT) belongs to one of the most hazardous groups of chemicals called persistent organic pollutants. Many organochlorine pesticides including p,p(')-DDT are long lasting due to their non-degradability can travel to distant places and being fat soluble can accumulate in animals and human bodies. Due to the persistent nature of p,p(')-DDT, its adverse environmental and health impacts, the present study was undertaken to examine the residual p,p(')-DDT in and around abandoned p,p(')-DDT manufacturing factory in Amman Gharh, Nowshera, NWFP. Samples of soil, sediments and water were collected in and around the factory area, nearby p,p(')-DDT stores, main factory drain leading to river Kabul and nearby villages. Standard procedures were used for the collection, transportation and storage of samples for analyses. Extraction of each sample for p,p(')-DDT analyses was carried out in triplicates using Soxhelt extraction. p,p(')-DDT contents in the samples were analyzed by capillary GC with electron capture detector. Most of the samples collected up to half kilometer distance from the site of the DDT factory were found contaminated. Further the level of p,p(')-DDT decreased with increasing depth from top to bottom and with distance from the site. The results indicate that there is no immediate threat to underground water reservoirs.     

Exposure assessment of endocrine disruptors in bottled drinking water of Lebanon

Bisphenol A (BPA) is a commonly used monomer in various products including bottled water. Numerous studies have reported endocrine adverse effects and neoplasia associated with BPA exposure in animals. However, considerable discrepancies exist among these studies with respect to both the nature of the toxic effects and the threshold dose. In Lebanon, 19-L polycarbonate (PC) bottles of drinking water are widely used in urban areas. The present study aims at assessing BPA human exposure and associated health risks from drinking water in Lebanese. A total of 22 bottled water sources, packaged in PC, were identified from licensed and non-licensed sources. Water samples were analyzed following exposure to sunlight for 72 h. BPA in water was quantified by HPLC, and other potential organic pollutants were screened by GC/MS. Fifty-nine percent of samples showed BPA levels above detection limits (>0.05 ng/mL). The median BPA level was 0.1 ng/mL (range 0.05 to 1.37 ng/mL). The mean BPA level for the total number of samples was 0.169 ng/mL (±0.280). A higher mean BPA level was found in water from licensed companies compared to non-licensed sources, however, not statistically significant. Screening showed the presence of dibutyl-phthalate and dioctyl-phthalate in only two samples. Endocrine disruptors (EDR) are ubiquitous contaminants in bottled water in Lebanon with potential health risk implications. Although estimated exposure levels are below the reference dose (RfD), further studies are needed to quantitate exposure from various sources and to investigate EDR contribution to existing epidemics in the country.