The Release of Trichlorofluoromethane from Rigid Polyurethane Foams

The use of trichlorofluoromethane (CCl₃F or F-11) in rigid closed cell polyurethane foams has risen dramatically during the past decade and now constitutes one of the major applications of this fluorocarbon, whereas previously aerosol spray cans consumed most of the production of F-11. Our study shows that F-11 remains in the foams for a very long time, perhaps for a hundred years or more, if the foams remain Intact. While in the past F-11 was released relatively soon after it was produced, now polyurethane insulating foams may constitute a growing reservoir from which F-11 will slowly and persistently leak Into the atmosphere for as long as the foams are in use. Although uncertainties remain, we estimate that in the next 50 years it is probable that as much F-11 will be tied up in foams as in the entire atmosphere at present.     

巢湖水体散射和后向散射特性研究

湖泊水体散射特性的研究对湖泊水色要素遥感反演模型的发展具有重要的意义.本研究利用AC-S和ECO-BB9实测了巢湖水体的散射系数和后向散射系数,在分析光谱变化特性的基础上,构建了悬浮颗粒物散射系数和后向散射系数的幂函数光谱模型,获得的光谱指数分别为0.86和3.24.研究发现悬浮颗粒物散射系数与TSM和ISM都存在较好的线性函数关系,进而提出水体中总悬浮颗粒物的比散射系数为0.6364(10-3m2·mg-1),无机悬浮颗粒物的比散射系数为0.9108(10-3m2·mg-1).同时,分析了悬浮颗粒物后向散射率和折射指数的变化,其变化范围分别为0.003～0.026和1.02～1.06.     

国内外冶金行业安全标准对比研究与分析

本文重点介绍了《国内外冶金行业安全标准对比研究》项目开展的基本情况,阐述了我国与欧美国家冶金行业安全标准体系和相关专业安全标准条款的对比内容,分析了我国冶金行业安全标准同欧美发达国家之间存在的差距与不足,有针对性地提出了我国冶金行业安全标准实现与国际发达国家接轨的对策措施和工作方向。     

The prevention of occupational injuries in two industrial plants using an incident reporting scheme

INTRODUCTION: The aim of this study was to examine whether the introduction of an incident reporting scheme with feedback in two industrial plants had an effect on the number of major incidents. METHOD: An intervention design with measurements before the implementation of the incident reporting scheme and two years later was used to examine the relationship between incident rates, safety climate, the willingness to report incidents and perceived management commitment to safety. RESULTS: The results showed that a successful implementation of an incident reporting scheme was followed by a decline in the incidence of major incidents at a Danish metal plant. A key factor in implementing the scheme was top management commitment, which was lacking at another plant, where the implementation of a similar scheme failed. CONCLUSION: Although the study shows some encouraging results concerning the use of incident reporting schemes to prevent occupational accidents, the possibility to draw causal conclusions is limited in the present study, and further studies are needed before the effectiveness of such schemes can be evaluated with certainty.     

Air quality measurements for the aerosol research and inhalation epidemiology study

Measurements of pollutant gases, airborne particulate matter mass and composition, and meteorology have been made at a core site near downtown Atlanta, GA, since August 1998 in support of the Aerosol Research and Inhalation Epidemiology Study (ARIES). This site is one of eight in the Southeastern Aerosol Research and Characterization network. The measurement objective is to provide a long-term, multivariate dataset suitable for investigating statistical associations of respiratory and cardiovascular disease with airborne particulate matter composition, meteorology, and copollutant gases through epidemiologic modeling. Measurements are expected to continue through 2010. Ancillary multiyear measurements at additional sites in the Atlanta metropolitan area and in short-term exposure assessments have been used to estimate the exposure/measurement error associated with using data from a central site to approximate human exposures for the entire area. To date, 13-, 25-, and 53-month air quality datasets have been used in epidemiologic analyses.     

Validation of the digital opacity compliance system under regulatory enforcement conditions

U.S. Environmental Protection Agency (EPA) Emission Measurement Center in conjunction with EPA Regions VI and VIII, the state of Utah, and the U.S. Department of Defense have conducted a series of long-term pilot and field tests to determine the accuracy and reliability of a visible opacity monitoring system consisting of a conventional digital camera and a separate computer software application for plume opacity determination. This technology, known as the Digital Opacity Compliance System (DOCS), has been successfully demonstrated at EPA-sponsored Method-9 "smoke schools", as well as at a number of government and commercially operated industrial facilities. Results from the current DOCS regulatory pilot study demonstrated that, under regulatory enforcement conditions, the average difference in opacity measurement between the DOCS technology and EPA Reference Method 9 (Method 9) was 1.12%. This opacity difference, which was computed from the evaluation of 241 regulated air sources, was found to be statistically significant at the 99% confidence level. In evaluating only those sources for which a nonzero visible opacity level was recorded, the     

PETROLEUM EXPLORATION TRENDS IN THE DEVELOPING COUNTRIES

In 1979, all the non-OPEC less developed countries (LDCs) represented 8.1 per cent of world oil production and more than 10 per cent of the proven reserves. The position of the oil-importing LDCs was more modest, with 2 per cent of world production and only 1.2 per cent of the proved reserves. On the other hand, their reserves of natural gas were slightly larger and relatively little exploited. Considering the low level of exploration in the non-OPEC LDCs, which can at least partially be explained by economic and political conditions, their hydrocarbon potential is considerably higher than present discoveries, as confirmed by results obtained in new zones that have recently been prospected. Up until the last few years, exploration efforts in non-OPEC LDCs, measured in terms of seismic prospecting and drilling, have remained practically stable. On the contrary, since the 1973 crisis and its repercussions on the price of oil, there has been a sharp increase in exploration in the developed countries, especially in North America, due to the greater economic attractiveness of new discoveries. To encourage the same intensification of exploration in the LDCs incentives to promote activities must continue to be proposed. The situation of the some 70 oil-importing LDCs, in which exploration has been highly scattered to date and where petroleum potential exists, is extremely critical. En 1979, tous les pays les moins développés en dehors de I'OPEP représentaient 8.1 pour cent de la production mondiale de pétrole et plus de 10 pour cent des réverses prouvées. La situation des pays les moins développés importateurs de pétrole était plus que défavorable, avec 2 pour cent de la production mondiale et 1.2 pour cent seulement des réverves prouvées. D'autre part, leurs réverves de gaz naturel étaient plus grandes et relativement peu exploitées. Considérant le faible niveau d'exploration dans les pays les moins développés en dehors de I'OPEP, niveau que l'on peut au moins attribue en partie aux conditions économiques et politiques, leur potentiel en hydrocarbures est considérablement plus élevé que les découvertes actuelles, tel que le confirment les résultats obtenus dans de nouvelles zones récemment prospectées. Jusqu'à ces dernières années, les efforts d'exploration dans les pays les moins développés en dehors de I'OPEP en termes de prospection sismique et de forage sont restés pratiquement stables. Par contre, depuis la crise de 1973 et ses répercussions sur le prix du pétrole, il y a eu une augmentation marquante dans l'exploration des pays développés, en particulier en Amérique du nord, à cause des possibilités économiques plus intéressantes de ces nouvelles découvertes. Afin d'arriver à la méme intensification en matière d'exploration dans les pays les moins développés, on doit continuer à fournir des encouragements pour promouvoir les activités. La situation des quelque 70 pays les moins développés importateurs de pétrole dans lesquels l'exploration a été sporadique jusqu'à cette date et où le potentiel en pétrole existe est extrêmement critique. En 1979 todos los países de menor grado de desarrollo, no miembros de la OPEP, representaban 8.1 porciento de la producción mundial de petróleo y más del 10 porciento de las reservas probadas. La situación de esta categoría de países, importadores de petróleo era mas modesta: con 2 porciento de la producción mundial y solo 1.2 porciento de reservas probadas. Por otro lado sus reservas de gas natural eran ligeramente mayores y relativamente poco explotadas. Tomando en consideración el bajo nivel de exploración en los países de menor grado de desarrollo no pertenecientes a la OPEP, el potencial en hidrocarburos de estos países es considerablemente mayor que los descubrimientos presentes tal como se confirma por los resultados obtenidos en zonas nuevas recientemente exploradas. Hasta hace pocos años, los esfuerzos de exploración en estos países han permanecido practicamente estables. Por el contrario desde la crisis de 1973 ha ocurrido un aumento rápido en la exploración en los países desarrollados, especialmente en Norte América, debido al mayor atractivo económico de los nuevos descubrimientos. Para facilitar la misma intensificación de exploración en los países de menor grado de desarrollo se deben proponer incentivos que promuevan mayor actividad. La situación de algo asi como 70 países importadores de petróleo es crítica a pesar de que existe un potencial en hidrocarburos y donde poca exploración se ha realizado hasta ahora.     

Multivariate statistical characterization of water quality in Lake Lanier, Georgia, USA

Watershed monitoring programs depend on water quality characterization data collected for many parameters, at many times and places, and with limited resources. Our objective is to present a strategy that reduces the measured parameters, locations, and frequency without compromising the quality of the monitoring program. One year of twice-monthly (growing season) and monthly (dormant season) water quality data collected from 17 lake and 10 tributary sites are used in conjunction with multivariate statistical techniques to improve the utility of collected data by identifying key parameters and monitoring locations. Factor analysis shows that tributary water quality data consists of three components-stormwater runoff, municipal and industrial discharges, and ground water-which can be distinguished using total suspended solids, total dissolved solids, and alkalinity plus soluble reactive P, respectively. Lake water quality characterization is more ambiguous than tributary water quality characterization, but factor analysis indicates that anoxia associated with lake stratification is the largest source of lake water quality variation, followed by nutrient abundance, and finally by biomass abundance. Cluster analysis suggests that tributary and lake monitoring stations can be consolidated. Reducing the number of parameters and stations frees up resources for increased monitoring elsewhere.     

水中内分泌干扰物-壬基酚的去除研究进展

壬基酚是一种内分泌干扰物,主要来源于NPEO,能通过生物富集作用进入生物体内并造成危害。当前检测水样中壬基酚的主要方法是采用GC—MS,预处理采用固相萃取。研究表明自来水厂的常规处理工艺对于壬基酚的去除有限;而活性炭、有机蒙脱土吸附等物理方法,超声声化、电化学氧化、光分解等化学方法可有效降解水中的壬基酚。     

Driving under the influence of alcohol and drugs in the eastern part of Denmark in 2015 and 2016: Abuse patterns and trends

Objectives: The objective of this study was to examine the frequency of psychoactive drugs and alcohol in drivers under suspicion of driving under the influence of drugs and alcohol in 2015 and 2016 in the eastern part of Denmark. The trends in the number of traffic cases sent for drug analysis since 2000 and alcohol analysis since 2011 are also discussed.

Methods: Blood samples from drivers suspected of being under the influence of alcohol and/or medication and/or illicit drugs in 2015 and 2016 were investigated as requested by the police. The blood samples were screened for alcohol and/or tetrahydrocannabinol (THC) alone, for other drugs (covering all drugs, except THC, listed in the Danish list of narcotic drugs), or for THC and other drugs. Age and gender were also recorded. The number of drug traffic cases since 2000 and the number of alcohol cases since 2011 were extracted from our Laboratory Information Management System (LIMS).

Results: In total, 11,493 traffic cases were investigated. Alcohol and/or drugs exceeded the legal limit in 9,657 (84%) cases. Men constituted 95% of the drivers investigated for drugs and 88% of the alcohol cases. The drivers investigated for drugs consisted primarily of young men, whereas drivers investigated for alcohol were older.

The frequency was higher for positive alcohol cases above the legal limit (87%) than for drug cases (76%) above the fixed concentration limit. THC (67–69%) was the most frequently detected drug above the legal limit, followed by cocaine (27–28.5%), amphetamine (17%), and clonazepam (6–7%) in both years. Morphine (5.4%), included among the 5 most frequent drugs in 2015, was replaced by methadone (4.6%) in 2016. Few new psychoactive drugs (NPS) were detected.

The number of traffic cases sent for drug analysis has increased more than 30-fold since 2000–2006, and the number of traffic cases submitted in 2016 for drug analysis was higher than the number for alcohol analysis; the latter has decreased since 2011.

Conclusion: Overall, alcohol was the most frequent compound detected above the legal limit in both years, followed by the well-known illicit drugs THC, cocaine, and amphetamine. NPS were seldom seen. One consequence of the increased focus on drugs in traffic has been an immense increase in drug traffic cases sent for analysis since 2006 in the eastern part of Denmark. Although this survey revealed only minimal changes compared to earlier investigations, surveys like this are invaluable for monitoring abuse patterns and trends in drugged and drunken driving.