全文获取类型
收费全文 | 5205篇 |
免费 | 94篇 |
国内免费 | 441篇 |
专业分类
安全科学 | 103篇 |
废物处理 | 345篇 |
环保管理 | 347篇 |
综合类 | 1252篇 |
基础理论 | 1037篇 |
环境理论 | 4篇 |
污染及防治 | 1874篇 |
评价与监测 | 446篇 |
社会与环境 | 285篇 |
灾害及防治 | 47篇 |
出版年
2023年 | 55篇 |
2022年 | 177篇 |
2021年 | 161篇 |
2020年 | 76篇 |
2019年 | 99篇 |
2018年 | 187篇 |
2017年 | 157篇 |
2016年 | 255篇 |
2015年 | 195篇 |
2014年 | 330篇 |
2013年 | 515篇 |
2012年 | 350篇 |
2011年 | 339篇 |
2010年 | 269篇 |
2009年 | 211篇 |
2008年 | 338篇 |
2007年 | 313篇 |
2006年 | 271篇 |
2005年 | 197篇 |
2004年 | 170篇 |
2003年 | 153篇 |
2002年 | 131篇 |
2001年 | 88篇 |
2000年 | 71篇 |
1999年 | 63篇 |
1998年 | 39篇 |
1997年 | 34篇 |
1996年 | 30篇 |
1995年 | 39篇 |
1994年 | 29篇 |
1993年 | 26篇 |
1992年 | 19篇 |
1991年 | 15篇 |
1990年 | 14篇 |
1989年 | 11篇 |
1988年 | 9篇 |
1985年 | 10篇 |
1966年 | 11篇 |
1965年 | 15篇 |
1964年 | 28篇 |
1963年 | 12篇 |
1962年 | 17篇 |
1961年 | 11篇 |
1960年 | 9篇 |
1959年 | 26篇 |
1958年 | 25篇 |
1957年 | 17篇 |
1956年 | 14篇 |
1955年 | 18篇 |
1954年 | 7篇 |
排序方式: 共有5740条查询结果,搜索用时 552 毫秒
11.
Granular acid-activated neutralized red mud (AaN-RM) has been successfully prepared with good chemical stability and physical strength. However, its potential for industrial application remains unknown. Therefore, the performance of granular AaN-RM for phosphate recovery in a fixed-bed column was investigated. The results demonstrated that the phosphate adsorption performance of granular AaN-RM in a fixed-bed column was affected by various operational parameters, such as the bed depth, flow rate, initial solution pH and initial phosphate concentration. With the optimal empty-bed contact time (EBCT) of 24.27 min, the number of processed bed volumes and the phosphate adsorption capacity reached 496.95 and 84.80 mg/g, respectively. Then, the saturated fixed-bed column could be effectively regenerated with a 0.5 mol/L HCl solution. The desorption efficiency remained as high as 83.45% with a low weight loss of 3.57% in the fifth regeneration cycle. In addition, breakthrough curve modelling showed that a 5-9-1 feed-forward artificial neural network (ANN) could be effectively applied for the optimization of the fixed-bed adsorption system; the coefficient of determination (R2) and the root mean square error (RMSE) evaluated on the validation-testing data were 0.9987 and 0.0183, respectively. Therefore, granular AaN-RM fixed-bed adsorption exhibits promising potential for phosphate removal and recovery from polluted water. 相似文献
12.
Yanqin Ren Gehui Wang Jianjun Li Can Wu Cong Cao Jiayuan Wang Lu Zhang Fan Meng Hong Li 《环境科学学报(英文版)》2018,30(9):32-44
Size-resolved biogenic secondary organic aerosols(BSOA) derived from isoprene and monoterpene photooxidation in Qinghai Lake, Tibetan Plateau(a continental background site) and five cities of China were measured using gas chromatography/mass spectrometry(GC/MS). Concentrations of the determined BSOA are higher in the cities than in the background and are also higher in summer than in winter. Moreover, strong positive correlations(R2= 0.44–0.90) between BSOA and sulfate were found at the six sites,suggesting that anthropogenic pollution(i.e., sulfate) could enhance SOA formation,because sulfate provides a surface favorable for acid-catalyzed formation of BSOA. Size distribution measurements showed that most of the determined SOA tracers are enriched in the fine mode( 3.3 μm) except for cis-pinic and cis-pinonic acids, both presented a comparable mass in the fine and coarse( 3.3 μm) modes, respectively. Mass ratio of oxidation products derived from isoprene to those from monoterpene in the five urban regions during summer are much less than those in Qinghai Lake region. In addition, in the five urban regions relative abundances of monoterpene oxidation products to SOA are much higher than those of isoprene. Such phenomena suggest that BSOA derived from monoterpenes are more abundant than those from isoprene in Chinese urban areas. 相似文献
13.
14.
Examination of car fleet records in Accra demonstrates an increasing proportion of catalytic converter-equipped cars in the relatively old car fleet (average age 13 years) due to their import from developed countries. However, only leaded petrol is sold in Ghana. Lead anti-knocking additives, which are known to affect catalyst activity and promote thermal sintering and mechanical abrasion, may increase Pt emissions. This possible synergism prompted the concomitant determination of Pb and Pt levels in road dust and roadside soils in Ghana. Both metals followed traffic density with higher concentrations in urban areas compared to remote sites. In urban areas, the range for Pb (365 +/- 93 microg g(-1) for dust and 291 +/- 76 microg g(-1) for soil) reflects precatalyst levels in Europe and the US, while the range for Pt (39 +/- 24 ng g(-1) for dust and 15 +/- 5.3 ng g(-1) for soil) is typical for the same countries. The elevated Pt concentrations were unexpected due to recent introduction of catalysts to Ghana compared to the prolonged use of catalysts in Europe and the US. 相似文献
15.
Yáñez J Fierro V Mansilla H Figueroa L Cornejo L Barnes RM 《Journal of environmental monitoring : JEM》2005,7(12):1335-1341
The analysis for arsenic in hair is commonly used in epidemiological studies to assess exposure to this toxic element. However, poor correlation between total arsenic concentration in hair and water sources have been found in previous studies. Exclusive determination of endogenous arsenic in the hair, excluding external contamination has become an analytical challenge. Arsenic speciation in hair appears as a new possibility for analytical assessing in As-exposure studies. This study applied a relative simple method for arsenic speciation in human hair based on water extraction and HPLC-HG-ICP-MS. The concentration of arsenic species in human hair was assessed in chronically As(V)-exposed populations from two villages (Esqui?a and Illapata) of the Atacama Desert, Chile. The arsenic concentrations in drinking water are 0.075 and 1.25 mg L(-1), respectively, where As(V) represented between 92 and 99.5% of the total arsenic of the consumed waters. On average, the total arsenic concentrations in hair from individuals of Esqui?a and Illapata were 0.7 and 6.1 microg g(-1), respectively. Four arsenic species, As(III), DMA(V), MMA(V) and As(V), were detected and quantified in the hair extracts. Assuming the found species in extracts represent the species in hair, more than 98% of the total arsenic in hair corresponded to inorganic As. On average, As(III) concentrations in hair were 0.25 and 3.75 microg g(-1) in Esqui?a and Illapata, respectively; while, the As(V) average concentrations were 0.15 and 0.45 microg g(-1) in Esqui?a and Illapata, respectively. Methylated species represent less than 2% of the extracted As (DMA(V)+ MMA(V)) in both populations. As(III) in hair shows the best correlation with chronic exposure to As(V) in comparison to other species and total arsenic. In fact, concentrations of As(total), As(III) and As(V) in hair samples are correlated with the age of the exposed individuals from Illapata (R= 0.65, 0.69, 0.57, respectively) and with the time of residence in this village (R= 0.54, 0.71 and 0.58, respectively). 相似文献
16.
Cariñanos P Sánchez-Mesa JA Prieto-Baena JC Lopez A Guerra F Moreno C Dominguez E Galan C 《Journal of environmental monitoring : JEM》2002,4(5):734-738
The aim of this study was to analyse the relationship between the distribution of hay-fever patients in the city of Córdoba, south-western Iberian Peninsula, and the specific atmospheric biological content originating from local sources. Four different districts were established in the metropolitan area of the city, according to vegetational and urbanistic characteristics. Air samples were taken in each area using portable Hirst-type samplers (Lanzoni VPPS 1000) and the spectrum of biological content was defined. Patients attending the Allergy Unit at Córdoba Teaching Hospital in 2000 with allergic rhinitis and/or asthma, and displaying a positive reaction to aeroallergen extracts, were distributed within the areas as a function of their district of residence. Aerobiological results revealed differences in pollen content between areas, in terms of both quantity and number of pollen types recorded. These differences were largely due to proximity to rural areas, prevalence of pollen from typically urban species and the possible effect of urban architecture as a barrier to the dispersal/ concentration of particles and other pollutants. Patients were not uniformly distributed within the city. The majority lived in districts in which pollen from rural species was mixed with pollen from ornamentals. Patients living in typically urban districts displayed a higher prevalence of allergy to pollen from ornamentals. It is concluded that a high degree of exposure to the same environment may influence the development of sensitisation to the particular pollen load associated with that area. 相似文献
17.
Santamaría-Fernández R Moreda-Piñeiro A Hill SJ 《Journal of environmental monitoring : JEM》2002,4(2):330-336
The optimisation of a simple multielement extraction method employing an experimental design approach is described. The method uses centrifugation to pass one extractant solution at varying pH through a contaminated soil sample. The nature and concentration of the acid, rate of centrifugation and time, number of sequential leachates and the ratio of extractant volume: sample weight have been studied in order to obtain the optimum conditions for extraction. A fractional factorial experimental design was performed, and the results were used to identify significance which was then evaluated by carrying out a central composite experimental approach. Once optimum conditions had been obtained, sequential leaches were analysed by ICP-AES and chemometrics were employed to identify the composition of each component. Comparisons have been made with previous studies and tentative assignments, based on well defined separated fractions and percentage compositions for individual elements, used to identify the different physico-chemical components in the sample. 相似文献
18.
Fagundez LA Fernández VL Marino TH Martín I Persano DA Rivarola Y Benítez M Sadañiowski IV Codnia J Zalts A 《Environmental monitoring and assessment》2001,71(1):61-70
Passive diffusion samplers were employed in San Miguel(Buenos Aires Metropolitan Area) for a preliminary airpollution monitoring. The highest loads were observedin downtown, compared with an urban background site.Total suspended particulate matter (TSPM) varied from0.257 to 0.033 mg cm-2 month-1; dust was examinedfor particle nature and size distribution. A similartrend was observed for nitrogen dioxide (NO2) andTSPM spatial distribution, suggesting that traffic isthe major pollution source. Sulphur dioxide (SO2)values were low and rather homogeneous. Levels for theinvestigated pollutants are below EPA's guide linevalues. Geographic (flat area, near to Rio de LaPlata) and climatologic factors (rainfalls andvariable wind directions) contribute to disperse pollutants. 相似文献
19.
Gustavo Ratto Fabián Videla J. Reyna Almandos Ricardo Maronna Daniel Schinca 《Environmental monitoring and assessment》2006,121(1-3):325-340
This article presents and discusses SO2 (ppbv) concentration measurements combined with meteorological data (mainly wind speed and direction) for a five-year campaign (1996 to 2000), in a site near an oil refinery plant close to the city of La Plata and surroundings (aprox. 740.000 inh.), considered one of the six most affected cities by air pollution in the country. Since there is no monitoring network in the area, the obtained results should be considered as medium term accumulated data that enables to determine trends by analyzing together gas concentrations and meteorological parameters. Preliminary characterization of the behaviour of the predominant winds of the region in relation with potential atmospheric gas pollutants from seasonal wind roses is possible to carry out from the data. These results are complemented with monthly averaged SO2 measurements. In particular, for year 2000, pollutant roses were determined which enable predictions about contamination emission sources. As a general result we can state that there is a clear increase in annual SO2 concentration and that the selected site should be considered as a key site for future survey monitoring network deployment. Annual SO2 average concentration and prevailing seasonal winds determined in this work, together with the potential health impact of SO2 reveals the need for a comprehensive and systematic study involving particulate matter an other basic pollutant gases. 相似文献
20.
Pacáková V Pockeviciute D Armalis S Stulík K Li J Veselý J 《Journal of environmental monitoring : JEM》2000,2(2):187-191
Experiments were carried out to monitor the equilibrium distribution of lead, cadmium and copper between an aqueous phase modelling natural water and a solid phase modelling natural sediment, under varying conditions. The aqueous phase was analysed using ETAAS and differential pulse anodic stripping voltammetry (DPASV), whereas XRD and FTIR were used to study the solid phase. Sorption isotherms at constant pH were measured. Conditional distribution constants were calculated as functions of the pH, the time of equilibration and the amount of solid material. The results obtained stress the need for standardization of the approaches to the study of water-sediment interactions in order to be able to evaluate and compare the extensive data from field measurements and to predict these interactions. 相似文献