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21.
This study presents the first systematic information on the degradation patterns of clandestine drug laboratory chemicals in soil. The persistence of five compounds - parent drugs (methamphetamine, 3,4-methylenedioxymethamphetamine (MDMA)), precursor (pseudoephedrine), and synthetic by-products N-formylmethylamphetamine and 1-benzyl-3-methylnaphthalene) - were investigated in laboratory scale for 1 year in three different South Australian soils both under non-sterile and sterile conditions. The results of the degradation study indicated that 1-benzyl-3-methylnaphthalene and methamphetamine persist for a long time in soil compared to MDMA and pseudoephedrine; N-formylmethylamphetamine exhibits intermediate persistence. The role of biotic versus abiotic soil processes on the degradation of target compounds was also varied significantly for different soils as well as with the progress in incubation period. The degradation of methamphetamine and 1-benzyl-3-methylnaphthalene can be considered as predominantly biotic as no measureable changes in concentrations were recorded in the sterile soils within a 1 year period. The results of the present work will help forensic and environmental scientists to precisely determine the environmental impact of chemicals associated with clandestine drug manufacturing laboratories. 相似文献
22.
N. Mithil Kumar K. Varaprasad G. Ramachandra Reddy G. Siva Mohan Reddy Y. Sivabharathi G. Venkata Subba Reddy S. Venkata Naidu 《Journal of Polymers and the Environment》2011,19(1):225-229
Synthesis and characterization of novel biodegradable, water soluble and optically active DL-malic acid (DMA) and citric acid
(CA) copolymers were studied for possible use as antibacterial agents. The copolymers were synthesized by direct bulk melt
condensation in the absence of a catalyst above 150 °C. Characterization of obtained copolymers was carried out with the help
of infrared absorption spectra, differential scanning calorimetry and thermo gravimetric analysis. The antibacterial activity
of copolymers against bacteria was investigated. The results obtained shows the above copolymers possess a broad wound dressing
activity against different types of bacteria and may be useful as antibacterial agents. 相似文献
23.
24.
Zhou YF Haynes RJ Naidu R 《Environmental science and pollution research international》2012,19(4):1260-1270
Purpose
This study aims to examine whether addition of immobilising agents to a sandy, alkaline (pH = 8.1) soil, which had been contaminated with Pb and Zn by airborne particles from a Pb/Zn smelter, would substantially reduce metal bioavailability. 相似文献25.
Li-Na Shi Yan Zhou Zuliang Chen Mallavarapu Megharaj Ravi Naidu 《Environmental science and pollution research international》2013,20(6):3639-3648
Clays such as kaolin, bentonite and zeolite were evaluated as support material for nanoscale zero-valent iron (nZVI) to simultaneously remove Cu2+ and Zn2+ from aqueous solution. Of the three supported nZVIs, bentonite-supported nZVI (B-nZVI) was most effective in the simultaneous removal of Cu2+ and Zn2+ from a aqueous solution containing a 100 mg/l of Cu2+ and Zn2+, where 92.9 % Cu2+ and 58.3 % Zn2+ were removed. Scanning electronic microscope (SEM) revealed that the aggregation of nZVI decreased as the proportion of bentonite increased due to the good dispersion of nZVI, while energy dispersive spectroscopy (EDS) demonstrated the deposition of copper and zinc on B-nZVI after B-nZVI reacted with Cu2+ and Zn2+. A kinetics study indicated that removing Cu2+ and Zn2+ with B-nZVI accorded with the pseudo first-order model. These suggest that simultaneous adsorption of Cu2+and Zn2+ on bentonite and the degradation of Cu2+and Zn2+ by nZVI on the bentonite. However, Cu2+ removal by B-nZVI was reduced rather than adsorption, while Zn2+ removal was main adsorption. Finally, Cu2+, Zn2+, Ni2+, Pb2+ and total Cr from various wastewaters were removed by B-nZVI, and reusability of B-nZVI with different treatment was tested, which demonstrates that B-nZVI is a potential material for the removal of heavy metals from wastewaters. 相似文献
26.
Cáceres TP Megharaj M Naidu R 《Journal of environmental science and health. Part. B》2008,43(7):605-610
Fenamiphos (0-ethyl-0(3-methyl-4-methylthiophenyl)-isopropylamido-phosphate) is a widely used nematicide and insecticide in bowling greens and agriculture, but information on its sorption including its metabolites is limited. Hence, the sorption of fenamiphos (nematicide) and its major degradation products fenamiphos sulfoxide (FSO) and fenamiphos sulfone (FSO2) were determined in thirteen contrasting soils collected from Australia and Ecuador. The sorption coefficients (Kd) exhibited a wide range of variation from 2.48 to 14.94 L/Kg for fenamiphos; from 0 to 7.42 L/Kg for FSO and from 0 to 9.49 L/Kg for FSO2. The sorption affinity of the three compounds for all soils tested was as follows: fenamiphos > fenamiphos sulfone > fenamiphos sulfoxide. The results showed that the sorption of fenamiphos and its metabolites in some soils is very low, and in one case is nonexistant for the metabolites. This is of particular concern as due to its low sorption coefficient, the compound could easily migrate and contaminate water bodies. Fenamiphos and its oxidation products have been reported to be highly toxic to aquatic invertebrates and therefore, the information generated in this study assumes great importance in the risk assessment of fenamiphos and its metabolites in the environment. 相似文献
27.
Arsenic (As) contamination of soil poses a potential threat to human health, particularly for small children, through the incidental ingestion of soil from hand-to-mouth activity. In this study, we examined the relationship between As bioaccessibility using the simplified bioaccessibility extraction test (SBET) and the soil fractions that contribute to bioaccessible As in 12 long-term contaminated soils. Sequential fractionation of soils prior to As bioaccessibility assessment found that As was primarily associated with the specifically sorbed (3-26%), amorphous and poorly crystalline (12-82%), and the well crystalline (3-25%) oxyhydroxide Fe/Al phases with proportions varying depending on the mode of As input. Arsenic bioaccessibility in these soils ranged from less than 1% in the gossan soil to 48% in railway corridor soils. Soil fractions contributing to As bioaccessibility were found to be from the non-specifically (<1-11%), the specifically (<1-29%) sorbed and the amorphous and poorly-crystalline (30-93%) oxyhydroxide Fe/Al fractions. Significant correlations (p<0.05) were found between the As bioaccessible fraction and the amorphous and poorly-crystalline oxyhydroxide Fe/Al fractions indicating that this fraction is a key factor influencing As bioaccessibility in many anthropogenically contaminated soils. 相似文献
28.
Multivariate analysis of mixed contaminants (PAHs and heavy metals) at manufactured gas plant site soils 总被引:1,自引:0,他引:1
Principal component analysis (PCA) was used to provide an overview of the distribution pattern of polycyclic aromatic hydrocarbons
(PAHs) and heavy metals in former manufactured gas plant (MGP) site soils. PCA is the powerful multivariate method to identify
the patterns in data and expressing their similarities and differences. Ten PAHs (naphthalene, acenapthylene, acenaphthene,
fluorene, phenanthrene, anthracene, fluoranthene, pyrene, chrysene, benzo[a]pyrene) and four toxic heavy metals — lead (Pb), cadmium (Cd), chromium (Cr) and zinc (Zn) — were detected in the site soils.
PAH contamination was contributed equally by both low and high molecular weight PAHs. PCA was performed using the varimax
rotation method in SPSS, 17.0. Two principal components accounting for 91.7% of the total variance was retained using scree
test. Principle component 1 (PC1) substantially explained the dominance of PAH contamination in the MGP site soils. All PAHs,
except anthracene, were positively correlated in PC1. There was a common thread in high molecular weight PAHs loadings, where
the loadings were inversely proportional to the hydrophobicity and molecular weight of individual PAHs. Anthracene, which
was less correlated with other individual PAHs, deviated well from the origin which can be ascribed to its lower toxicity
and different origin than its isomer phenanthrene. Among the four major heavy metals studied in MGP sites, Pb, Cd and Cr were
negatively correlated in PC1 but showed strong positive correlation in principle component 2 (PC2). Although metals may not
have originated directly from gaswork processes, the correlation between PAHs and metals suggests that the materials used
in these sites may have contributed to high concentrations of Pb, Cd, Cr and Zn. Thus, multivariate analysis helped to identify
the sources of PAHs, heavy metals and their association in MGP site, and thereby better characterise the site risk, which
would not be possible if one uses chemical analysis alone. 相似文献
29.
30.
A. V. M. Subba Rao Arun K. Shanker V. U. M. Rao V. Narsimha Rao A. K. Singh Pragyan Kumari C. B. Singh Praveen Kumar Verma P. Vijaya Kumar B. Bapuji Rao Rajkumar Dhakar M. A. Sarath Chandran C. V. Naidu J. L. Chaudhary Ch. Srinivasa Rao B. Venkateshwarlu 《Environmental Modeling and Assessment》2016,21(1):17-30