Recording the Response of Plants to Various Air Pollutants

A discussion of the methods used to determine the most economic design of chimney for a new thermal power station or large industrial plant is presented, with the objective that ground level concentration of pollutants will be kept at a minimum. Attention is paid to the geography and climatology of the site, with special reference to the frequency and height of inversions and the prevailing wind direction and speed.

A method is illustrated in using a large thermal power station as an example. The maximum sulfur dioxide concentrations at ground level are computed for several chimney heights and gas exit velocities. The values of these sulfur dioxide concentrations, the capital cost of the chimney, the pumping costs, and the gas pressures within the chimney are considered in selecting a suitable chimney height and a gas exit velocity which will meet most economically the stated objective.

The paper deals primarily with chimneys for industrial or power boiler plant of maximum continuous rating greater than 450 million Btu/hr (about 450,000 lbs of steam/hr), or to chimneys serving furnaces burning fuel at a maximum rate greater than 50,000 lbs/hr of coal, or 80,000 lbs/hr of oil. For chimneys serving plant with smaller heat inputs, chimney selection by reference to Clean Air Act 1956, Memorandum on Chimney Heights is suggested.     

Kinetic assessment of the potassium ferrate(VI) oxidation of antibacterial drug sulfamethoxazole

Sulfamethoxazole (SMX), a worldwide-applied antibacterial drug, was recently found in surface waters and in secondary wastewater effluents, which may result in ecotoxical effects in the environment. Herein, removal of SMX by environmentally-friendly oxidant, potassium ferrate(VI) (K(2)FeO(4)), is sought by studying the kinetics of the reaction between Fe(VI) and SMX as a function of pH (6.93-9.50) and temperature (15-45 degrees C). The rate law for the oxidation of SMX by Fe(VI) is first-order with respect to each reactant. The observed second-order rate constant decreased non-linearly from 1.33+/-0.08 x 10(3) M(-1)s(-1) to 1.33+/-0.10 x 10(0) M(-1)s(-1) with an increase of pH from 7.00 to 9.50. This is related to protonation of Fe(VI) (HFeO(4)(-) <==> H(+) + FeO(4)(2-); pK(a,HFeO(4)) = 7.23) and sulfamethoxazole (SH <==> H(+) + S(-); pK(a,SH)=5.7). The estimated rate constants were k(11)(HFeO(4)(-) + SH) = 3.0 x 10(4) M(-1)s(-1), k(12)(HFeO(4)(-) + S(-)) = 1.7 x 10(2) M(-1)s(-1), and k(13) (FeO(4)(2-) + SH) = 1.2 x 10(0) M(-1)s(-1). The energy of activation at pH 7.0 was found to be 1.86+/-0.04 kJ mol(-1). If excess potassium ferrate(VI) concentration (10 microM) is used than the SMX in water, the half-life of the reaction using a rate constant obtained in our study would be approximately 2 min at pH 7. The reaction rates are pH dependent; thus, so are the half-lives of the reactions. The results suggest that K(2)FeO(4) has the potential to serve as an oxidative treatment chemical for removing SMX in water.     

Modelling nitrogen saturation and carbon accumulation in heathland soils under elevated nitrogen deposition

A simple model of nitrogen (N) saturation, based on an extension of the biogeochemical model MAGIC, has been tested at two long-running heathland N manipulation experiments. The model simulates N immobilisation as a function of organic soil C/N ratio, but permits a proportion of immobilised N to be accompanied by accumulation of soil carbon (C), slowing the rate of C/N ratio change and subsequent N saturation. The model successfully reproduced observed treatment effects on soil C and N, and inorganic N leaching, for both sites. At the C-rich upland site, N addition led to relatively small reductions in soil C/N, low inorganic N leaching, and a substantial increase in organic soil C. At the C-poor lowland site, soil C/N ratio decreases and N leaching increases were much more dramatic, and soil C accumulation predicted to be smaller. The study suggests that (i) a simple model can effectively simulate observed changes in soil and leachate N; (ii) previous model predictions based on a constant soil C pool may overpredict future N leaching; (iii) N saturation may develop most rapidly in dry, organic-poor, high-decomposition systems; and (iv) N deposition may lead to significantly enhanced soil C sequestration, particularly in wet, nutrient-poor, organic-rich systems.     

Case study analysis of the financial impact of catastrophic safety events

Several catastrophic events in the process industry have caused extensive damage to life and property and have forever changed the process safety landscape. Despite the commitment from the industry, incidents still occur with similar root causes, impacting major companies in various ways. This work examines the financial impact of such incidents on the stability and future of affected companies in different industries. Several devastating incidents were analyzed to evaluate the direct impact in the short- and long-term and to discuss factors influencing the ability of affected companies to withstand the consequence of catastrophic events.     

WATER COLUMN LIGHT ATTENUATION IN DANSHUEI RIVER ESTUARY,TAIWAN1

ABSTRACT: The penetration of sunlight into the water column plays a critical role in the aquatic ecosystem. This study investigates light attenuation through the water column of the Danshuei River estuary and explores the models for quantifying it. The measurement of photosynthetically active radiation (PAR) indicates that the conventional exponential attenuation of light with depth is a very good model. A light attenuation coefficient may be derived from the PAR measurements at each location. The simpler measurements of Secchi depth (SD) provide an approximate estimate of the attenuation coefficients through an inverse linear relationship. The results also reveal that the amount and kinds of materials, which are either dissolved or suspended in the water, control light attenuation through the water column. However, the linear regression with such a model results in very poor correlation, and a relatively large constant term for the Danshuei River estuary. The regression with salinity yields a good correlation, indicating that the fraction of sea water might be a good parameter for estimating light attenuation coefficient for practical application in the Danshuei River estuary.     

A low cost instrument based on a solid state sensor for balloon-borne atmospheric O(3) profile sounding

The design of an instrument based on a solid state tungsten oxide sensor for making profile measurements of atmospheric ozone from balloon platforms is described. The sensor is operated at a constant temperature, typically 530 [degree]C. The importance of a detailed consideration of the electronic design is demonstrated, with particular reference to the circuit to control the sensor heater. Calibration methods which are straightforward to implement are illustrated, and the results of a test flight alongside an electrochemical ozonesonde are shown. Quantitative agreement within 25% for most of the profile demonstrates the potential of this type of sensor for ozone sounding. Future improvements from manufacture to analysis are expected to improve on this.     

Identification of new photoreduction products of pentachlorophenol

Pentachlorophenol (PCP), a fungicide and insecticide, leaves behind considerable residue in the environment in the form of unreacted molecule, metabolites and photoreduction products. Most of the previously reported photoproducts have resulted from dechlorination of the parent molecule. We have shown that photoreduction of PCP also proceeds by photoreduction of the parent molecule at carbons 2 and 4. These products were identified and characterized as 2-dehydro-2,3,4,5,6-pentachlorocyclohexanone (II) and 2,3,4,5,6-pentachlorocyclohexanone (IV). Both of them display keto-enol tautomerism. Identification and characterization of new photoproducts of PCP is significant for determining its overall environmental impact in the ecosystem.