Evaluation of relative photonic efficiency in heterogeneous photocatalytic reactors

The evaluation of photonic efficiency in heterogeneous photocatalysis remains elusive because the number of absorbed photons is difficult to assess experimentally. The photonic efficiency of heterogeneous photocatalytic reactors depends on the reactor geometry, irradiation source, and photocatalyst properties. In this work, the relative photonic efficiency of heterogeneous photocatalytic reactors to degrade an azo dye was evaluated using phenol as the standard system. The experimental tests were carried out in a batch reactor under different conditions of pH, catalyst dosage, initial concentration, and ultraviolet (UV) lamps. The kinetics of disappearance of both phenol and azo dye were studied using the initial rate method and were described according to the Langmuir-Hinshelwood (L-H) kinetic model. It was observed that the relative photonic efficiency depends on the adsorption/desorption properties of the photocatalyst.     

Efficient use of Fe metal as an electron transfer agent in a heterogeneous Fenton system based on Fe0/Fe3O4 composites

In this work a novel heterogeneous Fenton system based on Fe(0)/Fe3O4 composites is described. The composites with several Fe(0)/Fe3O4 ratios were prepared by two different methods, i.e. mechanical alloying of Fe(0) and Fe3O4 powders and controlled reduction of Fe3O4 with H2. Reaction studies and detailed Conversion Electron M?ssbauer surface characterization of the composites Fe(0)/Fe3O4, Fe(0), Fe3O4, alpha-Fe2O3 and gamma-Fe2O3 suggested that Fe2+surf species are essential to produce an active Fenton system. Kinetic studies for the oxidation of the dye methylene blue, used as an organic model molecule, and for the peroxide decomposition suggest that the reactions proceed via HO* radicals generated from Fe2+surf species and H2O2 in a Fenton like mechanism. The increase in activity caused by the addition of Fe(0) is discussed in terms of a creation of Fe2+surf species during the preparation of the composite and by an electron transfer mechanism from Fe(0) to Fe3+surf during the Fenton reaction to regenerate the Fe2+surf active species.     

Ammonia emission, deposition and impact assessment at the field scale: a case study of sub-grid spatial variability

A local ammonia (NH3) inventory for a 5x5 km area in central England was developed, to investigate the variability of emissions, deposition and impacts of NH3 at a field scale, as well as to assess the validity of the UK 5-km grid inventory. Input data were available for the study area for 1993 and 1996 on a field by field basis, allowing NH3 emissions to be calculated for each individual field, separately for livestock grazing, livestock housing and manure storage, landspreading of manures and fertiliser N application to crops and grassland. An existing atmospheric transport model was modified and applied to model air concentrations and deposition of NH3 at a fine spatial resolution (50 m grid). From the mapped deposition estimates and land cover information, critical loads and exceedances were derived. to study the implications of local variability for regional NH3 impacts assessments. The results show that the most extreme local variability in NH3 emissions, deposition and impacts is linked to housing and storage losses. However, landspreading of manures and intensive cattle grazing are other important area sources, which vary substantially in the landscape. Overall, the range of predicted emissions from agricultural land within the study area is 0-2000 kg N ha(-1) year(-1) in 1993 and 0-8000 kg N ha(-1) year(-1) in 1996, respectively, with the peak at a poultry farm located in the study area. On average, the estimated field level NH3 emissions over the study area closely match the emission for the equivalent 5-km grid square in the national inventory for 1996. Deposition and expected impacts are highly spatially variable, with the edges of woodland and small "islands" of semi-natural vegetation in intensive agricultural areas being most at risk from enhanced deposition. Conversely the centres of larger nature reserves receive less deposition than average. As a consequence of this local variability it is concluded that national assessments at the 5 km grid level underestimate the occurrence of critical loads exceedances due to NH3 in agricultural landscapes.     

How do animals use substrate-borne vibrations as an information source?

Animal communication is a dynamic field that promotes cross-disciplinary study of the complex mechanisms of sending and receiving signals, the neurobiology of signal detection and processing, and the behaviors of animals creating and responding to encoded messages. Alongside visual signals, songs, or pheromones exists another major communication channel that has been rather neglected until recent decades: substrate-borne vibration. Vibrations carried in the substrate are considered to provide a very old and apparently ubiquitous communication channel that is used alone or in combination with other information channels in multimodal signaling. The substrate could be ‘the ground’, or a plant leaf or stem, or the surface of water, or a spider’s web, or a honeybee’s honeycomb. Animals moving on these substrates typically create incidental vibrations that can alert others to their presence. They also may use behaviors to create vibrational waves that are employed in the contexts of mate location and identification, courtship and mating, maternal care and sibling interactions, predation, predator avoidance, foraging, and general recruitment of family members to work. In fact, animals use substrate-borne vibrations to signal in the same contexts that they use vision, hearing, touch, taste, or smell. Study of vibrational communication across animal taxa provides more than just a more complete story. Communication through substrate-borne vibration has its own constraints and opportunities not found in other signaling modalities. Here, I review the state of our understanding of information acquisition via substrate-borne vibrations with special attention to the most recent literature.     

Assessment of soil erosion under rainfed sugarcane in KwaZulu‐Natal,South Africa

Soil erosion from agricultural land use runoff is a major threat to the sustainability of soil composition and water resource integrity. Sugarcane is an important cash and food security crop in South Africa, subjected to an intensive soil erosion, and consequently, severe land degradation. This study aimed to investigate soil erosion and associated soil and cover factors under rainfed sugarcane, in a small catchment, KwaZulu‐Natal, South Africa. Three replicated runoff plots were installed at different slope positions (down, mid and upslope) within cultivated sugarcane fields to monitor soil erosion during the 2016–2017 rainy season. On average, annual runoff (RF) was significantly greater from 10 m² plots with 1163.77 ± 2.63 l/m/year compared to 1 m² plots. However, sediment concentration (SC) was significantly lower in 10 m² (0.34 ± 0.04 g/l) compared to 1 m² (6.94 ± 0.24 g/l) plots. The annual soil losses (SL) calculated from 12 rainfall events was 58.36 ± 0.77 and 8.84 ± 0.20 t/ha from 1 m² and 10 m² plots, respectively. The 1 m² plot, SL (2.4 ± 1.41 ton/ha/year) in the upslope experienced 33% more loss than the midslope and 50% more loss than the downslope position. SL was relatively lower from the 10 m² plots than the 1 m² plots, which is explained by high sediment deposition at the greater plot scale. SL was negatively correlated with the soil organic carbon stocks (r = ?0.82) and soil surface cover (r = ?0.55). RF decreased with the increase of slope gradient (r = ?0.88) and soil infiltration rate (r = ?0.87). There were considerable soil losses from cultivated sugarcane fields with low organic matter. These findings suggest that to mitigate soil erosion, soil organic carbon stocks and vegetation cover needs to be increased through appropriate land management practices, particularly in cultivated areas with steep gradients.     

Using activated biochar for greenhouse gas mitigation and industrial water treatment

This study explored the feasibility of using residual biomass to both mitigate greenhouse gas (GHG) emissions and remediate water contaminated by hydrocarbons. Using produced (process-affected) water from Canada’s oil sands operations as a case study, activated biochar (ACB) was found to have a higher affinity to organics than activated coal and removed 75 % of total organic carbon (TOC) from produced water in steam-assisted gravity drainage (SAGD) operations or 90 % of the TOC from synthetic tailings (ST) water sample. Up to 6 Tg dry biomass year^?1 would be required to treat the waters associated with the 93?×?10⁶-m³ of bitumen recovered per year. Landfilling the spent ACB and flaring any biogas produced were estimated to provide a greater GHG benefit than the combustion of the biochar + organics for heat to offset natural gas demand. Net costs for the ACB were about 13.84?$?m^?3 bitumen for SAGD operations and 1.76?$?m^?3 bitumen for mining operations. The values for mining operations justify further work to create a value chain that will integrate bioprocesses into the fossil fuel industry.     

Wetland Flowpaths Mediate Nitrogen and Phosphorus Concentrations across the Upper Mississippi River Basin

Eutrophication, harmful algal blooms, and human health impacts are critical environmental challenges resulting from excess nitrogen and phosphorus in surface waters. Yet we have limited information regarding how wetland characteristics mediate water quality across watershed scales. We developed a large, novel set of spatial variables characterizing hydrological flowpaths from wetlands to streams, that is, “wetland hydrological transport variables,” to explore how wetlands statistically explain the variability in total nitrogen (TN) and total phosphorus (TP) concentrations across the Upper Mississippi River Basin (UMRB) in the United States. We found that wetland flowpath variables improved landscape-to-aquatic nutrient multilinear regression models (from R² = 0.89 to 0.91 for TN; R² = 0.53 to 0.84 for TP) and provided insights into potential processes governing how wetlands influence watershed-scale TN and TP concentrations. Specifically, flowpath variables describing flow-attenuating environments, for example, subsurface transport compared to overland flowpaths, were related to lower TN and TP concentrations. Frequent hydrological connections from wetlands to streams were also linked to low TP concentrations, which likely suggests a nutrient source limitation in some areas of the UMRB. Consideration of wetland flowpaths could inform management and conservation activities designed to reduce nutrient export to downstream waters.     

Mercury exposure through diet in pregnant women and women of childbearing age

The study examined the stage of clean-up of the Port Lavaca bay sites in Texas, which were polluted during the early 1990's by effluent containing mercury (Hg) from a chloralkali plant. In addition to Hg intoxication through environmental contaminations, human exposure through dietary fish and other seafoods occurred. Bacteria converts inorganic Hg to alkyl organic compounds and subsequently the metal crosses the blood brain barrier thus exerting adverse effects on the fetal developing nervous system. In order to conduct a survey of dietary Hg exposure, blood was collected from pregnant women and those of childbearing age at routine clinic visits at each of three centers in South Texas cities (Galveston, Texas City, Port Lavaca/Victoria, TX). A questionnaire sought dietary and lifestyle information including consumption, sources of fish and other seafoods. A significant number of subjects (119 out of 175, 68%) ate fish caught locally. The blood Hg concentrations (µg?L^?1) range varied with the location of the study centers: City of Galveston 2.6–62; Texas City 2.8–111.8; and the Port Lavaca areas 3.02–126.7. The concentrations of blood Hg was directly proportional to the number of fish meals consumed for each species considered. Mean blood Hg concentrations for no fish meals per week were: Port Lavaca 4.5 (N?=?3), Galveston 4.3 (N?=?3), Texas City 3.5 (N?=?10). For >3 fish meals per week, the mean blood Hg concentrations were: Port Lavaca, 48.0 (N?=?53), Galveston 29.1 (N?=?35), Texas City, 36.1 (N?=?31). Data show that residues of Hg were still present in 1994 despite the clean-up efforts.     

Uptake and genotoxicity of micromolar concentrations of cobalt chloride in mammalian cells

Literature data concerning the genotoxicity of cobalt salts have been conflicting. To establish appropriate incubation conditions, we conducted a series of uptake studies, before genotoxicity was determined by DNA strand break induction in HeLa cells and mutagenicity in V79 Chinese hamster cells. Co(II) is taken up by HeLa cells in a concentration‐dependent manner and is accumulated inside the cell. The uptake is preceded by a fast association step to the outer membrane, with no saturation up to 24 h. DNA strand breaks as determined by nucleoid sedimentation are induced at concentrations as low as 50μMCoCl₂. The induction is time‐dependent, showing the highest number of breaks after 4h incubation with no further increase up to 24h. CoCl₂ is mutagenic at the HPRT‐locus, enhancing the spontaneous mutation frequency 4.2‐fold at 100μ?. Besides direct interactions with DNA, the mutagenicity of CoCl₂ could also be due to a decrease in the Fidelity of DNA polymerisation.     

Quantitative assessment of post‐disaster housing recovery: a case study of Punta Gorda,Florida, after Hurricane Charley

Quantitative assessment of post‐disaster housing recovery is critical to enhancing understanding of the process and improving the decisions that shape it. Nevertheless, few comprehensive empirical evaluations of post‐disaster housing recovery have been conducted, and no standard measurement methods exist. This paper presents a quantitative assessment of housing recovery in Punta Gorda, Florida, United States, following Hurricane Charley of August 2004, including an overview of the phases of housing recovery, progression of recovery over time, alternative trajectories of recovery, differential recovery, incorporation of mitigation, and effect on property sales. The assessment is grounded in a conceptual framework that considers the recovery of both people and place, and that emphasises recovery as a process, not as an endpoint. Several data sources are integrated into the assessment—including building permits, remotely sensed imagery, and property appraiser data—and their strengths and limitations are discussed with a view to developing a standardised method for measuring and monitoring housing recovery.