浅谈安全文化建设的作用和实现条件

安全是石化生产永恒的主题.怎样才能使人们在生产活动中始终绷紧安全弦,牢固树立安全意识,自觉遵守安全操作规程呢?实践证明:积极创建安全文化,是保证安全生产的一条有效途径.     

Health implications of radon distribution in living rooms and bedrooms in U.K. dwellings--a case study in Northamptonshire

Environmental radon exposure of residents of domestic premises in the United Kingdom (UK) and elsewhere in Europe is estimated on the basis of the measured radon concentrations in, and the relative occupancies of, the principal living room and bedroom. While studies on radon concentration variability in the individual units in apartment blocks in various countries have been described, little data has been reported on variability in two-storey single-family dwellings, and the majority of extant studies consolidate living room and bedroom data early in the analysis. To investigate this further, detailed analysis was made of radon concentration data from a set of thirty-four homes situated in areas of Northamptonshire known to exhibit high radon levels. All homes were of typical UK construction of brick/block/stone walls under a pitched tile/slate roof. Approximately 50% of the sample were detached houses, the remainder being semi-detached (duplex) or terraced (row-house). Around 25% of the sample possessed cellars, while 12% were single-storey dwellings (bungalows), reflecting the typical incidence of this type of dwelling in England. In the two-storey homes, all monitored bedrooms were on the upper floor. Distribution of the ratios of bedroom/living room radon concentrations (BR/LR ratio) in individual properties was left-skewed (mean 0.67, median 0.73, range 0.05-1.05) with a tail extending to just above 1.0. The mean is consistent with the outcome of earlier extensive studies in England, while the variability depends principally on the characteristics of the property, and not on seasonal factors. In a small set of homes, the BR/LR ratio was anomalously low, (mean 0.3). BR/LR ratios in single-storey homes clustered around a value of 1.0, indicating that house design, rather than lifestyle, is the dominant factor in determining bedroom radon concentrations. Homes with higher mean annual radon concentrations showed lower BR/LR ratios, supporting our proposal that, in some homes, radon emanation from building materials may comprise a significant component of the overall radon level.     

On the radiocesium carbonate barrier in organics-rich sediments of Lake Juodis, Lithuania

Radiocesium vertical profiles in organics-rich sediments of running shallow eutrophic Lake Juodis (Lithuania) were studied in relation to seasonal variations of vertical profiles (in water column and sediments) of standard variables (pH, redox potential, temperature, oxygen concentrations, conductivity). It is shown that the sedimentation rate, radiocesium mobility and its vertical profiles in sediments are controlled by the vital cycle (processes of the growth, accumulation and decomposition) of green algae covering the main bottom areas of the lake. It is also shown that calcite deposits are formed in the shallow bottom areas that are oxygenated throughout the year because of the photosynthetic activity of the green algae covering the sediment. Formation of the calcite coatings on freshly accumulated organics is remarkable for causing elevated densities of sediment solids in the upper part of the respective vertical profiles. These calcite deposits behave as a barrier for radiocesium backward flux to the bottom water making the respective bottom areas a radionuclide sink. Together with the jelly-structured sediments lying below these deposits, the calcite preserves the shape of the primary radiocesium vertical profiles formed due to free-ion diffusion after the deposition event. It was determined that bottom areas anaerobic in winter are the main radiocesium source in the water column and cause characteristic radiocesium redistribution in surface sediments.     

The transfer of 137Cs and 90Sr from feed to rabbits

Radiological assessment of the impact of nuclear weapons testing on the local population in the Semipalatinsk Test Site (STS) requires comprehensive site-specific information on radionuclide behaviour in the environment. However, information on radionuclide behaviour in the conditions of the STS is rather sparse and, in particular, there are no data in the literature on parameters of radionuclide transfer from feed to rabbit products which have been identified as contributors to internal dose to the inhabitants. The transfer of (137)Cs and (90)Sr to rabbit meat was studied under laboratory conditions in a controlled experiment with 32 locally bred rabbits maintained in the Kazakh Agricultural Research Institute. The equilibrium transfer coefficients for (137)Cs and (90)Sr from feed to rabbit meat were estimated to be 0.4 d kg(-1) and 0.15 d kg(-1), respectively. The biological half-lives were estimated to be 0.1 d for (137)Cs and 0.14 d for (90)Sr. Whereas for (137)Cs the distribution in the body is relatively homogeneous, there are large differences between the organs and tissues for (90)Sr for which, as expected, the highest concentrations were found in bone.     

The transfer of 239/240Pu to cow milk

In summer 1993 we measured the transfer of (239/240)Pu to milk from herbage from a pasture located 5 km from the Chernobyl nuclear power plant. In one treatment cows were allowed to graze freely on the pasture. In a second treatment, cows were fed herbage collected from the pasture in stalls. The milk transfer coefficient; F(m) did not vary significantly between treatments and the mean value of 7.5x10(-6)d l(-1) was higher than previously reported values. Despite many values of F(m) for Pu in the literature we identified few relevant original data sets. Transfer coefficient values for Pu are only appropriate when used in conjunction with a specified time period or an appropriate model which allows for the biological half-life. We recommend for screening purposes an F(m) value of 1x10(-5)d l(-1) for Pu, with an order of magnitude lower value being appropriate for cows which are only exposed for one grazing season.     

Distribution of organotin compounds in the bivalves of the Aegean Sea, Greece

Five bivalve species--Mytilus galloprovinciallis (Mediterranean mussels), Venus gallina (stripped venus), Modiola barbatus L. (bearded horse mussels), Pecten jacobeus (scallops) and Callista chione (hard clams)--were collected from seven areas in Aegean Sea, Greece, between August 2001 and January 2003 and analyzed for organotins (OTs). The concentrations (as geometric means) found were 17.1 ng g-1 for tributyltin (TBT), 18.8 ng g-1 for dibutytltin (DBT), 7.8 ng g-1 for monobutyltin (MBT) and 13.0 ng g-1 for triphenyltin (TPhT) (wet weight), which are at similar or lower levels than those reported worldwide. Studying OTs distribution between different bivalve species, lower concentrations were observed in mediterranean mussels, possibly due to their growth in water column (grown on sea net pens in mussel farms), in contrast to the free-ranging species, collected from fishing grounds. Concentrations of the OTs in the examined bivalves varied seasonally.     

呼和浩特城区冬季近地面挥发性有机物污染特征初步研究

挥发性有机物(VOCs)是环境空气监测的主要目标污染物。本文运用罐采样-三级冷阱预浓缩-中心切割-气相色谱(FID)/气质联用法对人群主要活动的近地面不同高度、不同时间段及不同区域的呼和浩特冬季大气环境中挥发性有机物进行定性定量分析。发现典型天气情况下,呼和浩特城区冬季近地面挥发性有机物组分中烷烃和芳香烃占比较高,城区西侧所监测点位挥发性有机物总量(TVOCs)浓度高于其他区域,且其浓度在高度和时段上存在明显差异。     

Little Egrets (Egretta Garzetta) and Trace-Metal Contamination in Wetlands of China

The rapidly developing Asian countries may face threatening environmental contamination, that however remains largely unassessed. We studied persistent trace elements in three wetlands, Poyang Lake, relatively unpolluted, and Tai Lake, and Pearl River Delta, selected as hotspots of pollution in Central China. We adopted as indicator the Little Egret, a widespread colonial waterbird, and during 1999 and 2000 we collected and analysed the same samples as for a parallel study we conducted in Pakistan, e.g. eggs, body feathers of chicks, prey spontaneously regurgitated by the chicks, and sediments at the areas most used by foraging egrets. The levels of trace-metals at our three study areas were similar, or within the range, of those found in the few other studies for East Asia, with few exceptions. The concentrations of the various elements were below the threshold that may affect the survival or reproduction of the birds, and even the highest concentrations relative to background, i.e. Se in eggs, and Hg in feathers at Pearl Delta, do not pose toxic hazards. In sediments, the levels of trace elements were lower than the critical levels assumed for contaminated soil, except for alarming high levels of As at Poyang. These results do not confirm our expectation, that Poyang was relatively uncontaminated, while Tai and Pearl were polluted. Although trace metal concentration differed significantly among the three study areas, these differences were minor and were not consistent among elements and samples. The bioaccumulation ratios from sediments through prey, feather and egg, were consistent with our previous findings for Pakistan. Only Hg exhibited high bioaccumulation, while Se and Zn had low accumulation, and the other elements no accumulation. This reasserts that feathers of predators such as egrets, may be more sensitive indicators of environmental contamination for the elements subject to bioaccumulation, whereas the sediments or the organisms low in the food chain are better indicators for the other elements.     

Fruit Stones from Industrial Waste for the Removal of Lead Ions from Polluted Water

Lead, one of the earliest metals recognized and used by humans, has a long history of beneficial use. However, it is now recognized as toxic and as posing a widespread threat to humans and wildlife. Treatment of lead from polluted water and wastewater has received a great deal of attention. Adsorption is one of the most common technologies for the treatment of lead-polluted water. This technique was evaluated here, with the goal of identifying innovative, low-cost adsorbent. This study presents experiments undertaken to determine the suitable conditions for the use of peach and apricot stones, produced from food industries as solid waste, as adsorbents for the removal of lead from aqueous solution. Chemical stability of adsorbents, effect of pH, adsorbents dose, adsorption time and equilibrium concentration were studied. The results reveal that adsorption of lead ions onto peach stone was stronger than onto apricot stone up to 3.36% at 3 h adsorption time. Suitable equilibrium time for the adsorption was 3–5 h (% Pb adsorption 93% for apricot and 97.64% for peach). The effective adsorption range for pH in the range was 7–8. Application of Langmuir and Freundlich isotherm models show high adsorption maximum and binding energies for using these adsorbents for the removal of lead ions from contaminated water and wastewater.     

Greenhouse gas emissions from conventional, agri-environmental scheme, and organic Irish suckler-beef units

The problems of overproduction within the European Union countries and the environmental impact of agriculture have lead to the introduction of schemes that aim to reduce both. Beef (Bos taurus) production forms a large component of the Irish agricultural industry and accounts for more than one quarter of agricultural economic output. Recently, the European CAP (Common Agricultural Policy) has been re-evaluated to include supplementary measures that encompass the environmental role of agriculture rather than just the production role. A life cycle assessment (LCA) method was adopted to estimate emissions per kilogram of CO2 equivalent per kilogram of live weight (LW) leaving the farm gate per annum (kg CO2 kg(-1) LW yr(-1)) and per hectare (kg CO2 ha(-1) yr(-1)). Fifteen units engaged in suckler-beef production (five conventional, five in an Irish agri-environmental scheme, and five organic units) were evaluated for emissions per unit product and area. The average emissions from the conventional units were 13.0 kg CO2 kg(-1) LW yr(-1), from the agri-environmental scheme units 12.2 kg CO2 kg(-1) LW yr(-1), and from the organic units 11.1 kg CO2 kg LW yr(-1). The average emissions per unit area from the conventional units was 5346 kg CO2 ha(-1) yr(-1), from the agri-environmental scheme units 4372 kg CO2 ha(-1) yr(-1), and from the organic units 2302 kg CO2 ha(-1) yr(-1). Results indicated that moving toward extensive production could reduce emissions per unit product and area but live weight production per hectare would be reduced.