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71.
Reis AP Patinha C Ferreira da Silva E Sousa AJ 《Environmental geochemistry and health》2012,34(2):229-241
The Marrancos gold mineralisation has a chemical assemblage of Fe–As–Se–Bi–Au–Ag–Te–(Cu–Pb–Zn–Sn–W). The −200 mesh of 144
topsoil samples was analysed by ICP–MS to determine total contents of 53 elements that include potentially harmful elements
like Cd, As and Pb. The soil geochemistry shows that some trace elements occur in considerably high concentrations. On the
basis of data for total metal concentrations, 10 topsoil samples were selected to carry out a metal fractionation study using
a selective extraction method. A set of four leaches of increasing strength was used sequentially in the soil samples. Across
the study area, there is some evidence of past mining and exploration activity, indicating that these soils may be locally
disturbed. The shallow mineralised quartz veins were exploited for gold by the Romans. Several galleries were constructed
during the 2nd World War, probably for the exploration of quartz–cassiterite–wolframite veins. However, the main mineralised
body in depth was never explored. The results of metal fractionation show different partitions for the three elements. Total
Cd concentrations in these soils are low, with a median value of 0.1 mg/kg. In average, 12% of total Cd is adsorbed by clays
and/or co-precipitated with carbonates, and 19% is bounded to Fe–Mn oxyhydroxides. However, the low concentrations indicate
that the metal does not represent an immediate risk to human health. For Pb, metal fractionation shows that, on average, 22%
of Pb is adsorbed by amorphous Fe and Mn oxides, but the samples from the northern part of the area have the major fractions
of Pb in soluble forms. The low probability of exposure in this part of the study area decreases the risk posed by this heavy
metal. Total As concentrations in the Marrancos soils are extremely high. A large area has As concentrations above 1,000 mg/kg.
For As, metal fractions in the sulphide phase vary between 84 and 98% in the studied samples. But one sample has 20% of total
As in easily reducible forms, corresponding to a partial concentration of 1,800 mg/kg that has a high probability of being
bioavailable. The most labile As forms occur at the southern part of the area, where the probability of exposure is higher
and the risk of human health increases in the same order. From the three studied potentially harmful elements, As is certainly
the element of concern. 相似文献
72.
Concei??o Juana Fortes óscar Ferreira Paulo A. Silva Theo Moura Rui Capit?o Luís Amante Michalis Vousdoukas Maria Bezerra 《Journal of Coastal Conservation》2012,16(4):461-472
In the framework of a research project entitled ??BRISA??BReaking waves and Induced SAnd transport??, a methodology was devised to characterize the waves joining together in-situ measurements and numerical wave propagation models. With this goal in mind, a number of in-situ measurements were made, for selected positions in front of Praia de Faro (South Portugal), during four days (25th to 28th March, 2009) by using different types of equipments (e.g., resistive wave gauges, pressure sensors, currentmeters and a new prototype pore pressure sensor using optical fibre). Wave records were obtained simultaneously offshore (at a water depth of 11.7?m below mean sea level, MSL) and at the surf and swash zones. The data processing and analysis were made by applying classical time domain techniques. Numerical simulations of the wave propagation between offshore and inshore for the measurement period were performed with two numerical models, a 1D model based on linear theory and a nonlinear Boussinesq-type model, COULWAVE, both forced by the measured offshore wave conditions of 27th March 2009. Comparisons between numerical results and field data for the pressure sensors placed in the surf and swash zones were made and discussed. This approach enables to evaluate the performance of those models to simulate those specific conditions, but also to validate the models by gaining confidence on their use in other conditions. 相似文献
73.
Alexandra?ZieritzEmail author Gemma?Clucas Lauren?Axtmann David?C.?Aldridge 《Marine Biology》2012,159(4):863-872
When feeding on blue mussels (Mytilus edulis), oystercatchers (Haematopus ostralegus) either stab into the mollusc’s gaping valves or hammer through its dorsal or ventral shell. Whilst the selectivity of hammering
and stabbing oystercatchers for specific prey morphologies has been well studied, the way in which the effects of environment
on M.
edulis morphology can in turn affect feeding methods of H. ostralegus is very poorly understood. Based on morphological analyses on randomly selected shells from three intertidal zones, this
study failed to detect differences in morphology or distribution of dorsally and ventrally hammered shells but confirms the
finding of previous authors that hammering oystercatchers select thinner mussels than stabbing birds. Additionally, we show
that this difference in optimal prey morphology can lead to spatial patterns in oystercatcher feeding behaviour. Whilst at
the low intertidal and higher mid intertidal zones, characterised by comparatively thick shells, most empty shells had apparently
been stabbed, hammering was the dominant feeding behaviour at the lower mid intertidal zone, where shells were thinner. Preference
of hammering birds for smaller mussels was not ubiquitous. Sagittal shell shape was predominantly influenced by allometric
growth effects and had only minor effect on prey selection. All oystercatchers preferred less inflated mussels, with the degree
of shell inflation gradually increasing with higher intertidal elevation. Our results illustrate the importance of small-scale
patterns in prey ecophenotypes in determining the distribution and feeding dynamics of wading birds. 相似文献
74.
Diana Paula Silva Linhares Patrícia Ventura Garcia Catarina Silva Joana Barroso Nadya Kazachkova Rui Pereira Manuela Lima Ricardo Camarinho Teresa Ferreira Armindo dos Santos Rodrigues 《Environmental geochemistry and health》2018,40(5):1713-1724
Hydrothermal areas are potentially hazardous to humans as volcanic gases such as radon (222Rn) are continuously released from soil diffuse degassing. Exposure to radon is estimated to be the second leading cause of lung cancer, but little is known about radon health-associated risks in hydrothermal regions. This cross-sectional study was designed to evaluate the DNA damage in the buccal epithelial cells of individuals chronically exposed to indoor radon in a volcanic area (Furnas volcano, Azores, Portugal) with a hydrothermal system. Buccal epithelial cells were collected from 33 individuals inhabiting the hydrothermal area (Ribeira Quente village) and from 49 individuals inhabiting a non-hydrothermal area (Ponta Delgada city). Indoor radon was measured with Ramon 2.2 detectors. Chromosome damage was measured by micronucleus cytome assay, and RAPD-PCR was used as a complementary tool to evaluate DNA damage, using three 10-mer primers (D11, F1 and F12). Indoor radon concentration correlated positively with the frequency of micronucleated cells (r s = 0.325, p = 0.003). Exposure to radon is a risk factor for the occurrence micronucleated cells in the inhabitants of the hydrothermal area (RR = 1.71; 95% CI, 1.2–2.4; p = 0.003). One RAPD-PCR primer (F12) produced differences in the banding pattern, a fact that can indicate its potential for detecting radon-induced specific genomic alterations. The observed association between chronic exposure to indoor radon and the occurrence of chromosome damage in human oral epithelial cells evidences the usefulness of biological surveillance to assess mutations involved in pre-carcinogenesis in hydrothermal areas, reinforcing the need for further studies with human populations living in these areas. 相似文献
75.
Ghobashy Mohamed mohamady Sayed Waheed A. A. El-Helaly Alexandra 《Journal of Polymers and the Environment》2021,29(10):3364-3374
Journal of Polymers and the Environment - A Green nanomaterial synthesis could be considered as an alternative bio-controller source of insect pest management as well as saving the environment.... 相似文献
76.
Węgrzyn Magdalena Rudnik Ewa Kamocka-Bronisz Renata Kukfisz Bożena 《Journal of Polymers and the Environment》2021,29(6):1808-1816
Journal of Polymers and the Environment - Biocomposites based on polyethylene from renewable resources derived from sugar cane as raw material were modified with phosphonium ionic liquids.... 相似文献
77.
Lima D Santos MM Ferreira AM Micaelo C Reis-Henriques MA 《Environment international》2008,34(1):94-101
The contamination of aquatic ecosystems by organic contaminants such as polycyclic aromatic hydrocarbons (PAHs) is a matter of great concern. Mussels have been extensively used as sentinel species in a large number of monitoring programs. However, the use of bivalves as the sole species has some limitations, because they are not as responsive as fish to Aryl Hydrocarbon Receptor agonists. Hence, for many marine areas, there is the need to validate new sentinel fish species that can be used in the assessment of pollution by organic contaminants. The shanny Lipophrys pholis is an intertidal fish that combines many characteristics required in a sentinel species: is abundant and easy to catch, has a wide geographical distribution and restrict home range. After larvae recruitment to the intertidal rocky shores, they remain in the same area for the rest of the life-cycle, thus reflecting local pollutants exposure. In order to evaluate the species sensitivity to organic contaminants under field conditions, L. pholis were collected at six sites reflecting different degrees of anthropogenic contamination. The induction of two biomarkers extensively validated in the assessment of PAHs contamination ethoxyresorufin-O-deethylase activity (EROD) and Fluorescent Aromatic Compounds (FACs) was evaluated. In parallel, mussels were collected at the same locations and levels of 16 PAHs and selected heavy metals determined. Overall, the specimens collected in the urban areas showed a significant induction of EROD and FACs (up to a six-fold induction) if compared with the reference sites. Additionally, a positive correlation was observed between the biomarkers and PAHs levels in mussel tissues. Even though further validation is currently in progress, the available data indicate that L. pholis is responsive to organic contaminants such as PAHs, suggesting its future integration in monitoring programmes designed to evaluate the presence of these contaminants in European marine ecosystems. 相似文献
78.
Marine Protected Dramas: The Flaws of the Brazilian National System of Marine Protected Areas 总被引:1,自引:0,他引:1
Leopoldo C. Gerhardinger Eduardo A. S. Godoy Peter J. S. Jones Gilberto Sales Beatrice P. Ferreira 《Environmental management》2011,47(4):630-643
This article discusses the current problems and issues associated with the implementation of a National System of Marine Protected
Areas in Brazil. MPA managers and higher governmental level authorities were interviewed about their perceptions of the implementation
of a national MPA strategy and the recent changes in the institutional arrangement of government marine conservation agencies.
Interviewees’ narratives were generally pessimistic and the National System was perceived as weak, with few recognizable marine
conservation outcomes on the ground. The following major flaws were identified: poor inter-institutional coordination of coastal
and ocean governance; institutional crisis faced by the national government marine conservation agency; poor management within
individual MPAs; problems with regional networks of marine protected areas; an overly bureaucratic management and administrative
system; financial shortages creating structural problems and a disconnect between MPA policy and its delivery. Furthermore,
a lack of professional motivation and a pessimistic atmosphere was encountered during many interviews, a malaise which we
believe affects how the entire system is able to respond to crises. Our findings highlight the need for a better understanding
of the role of ‘leadership’ in the performance of socio-ecological systems (such as MPA networks), more effective official
evaluation mechanisms, more localized audits of (and reforms if necessary to) Brazil’s federal biodiversity conservation agency
(ICMBio), and the need for political measures to promote state leadership and support. Continuing to focus on the designation
of more MPAs whilst not fully addressing these issues will achieve little beyond fulfilling, on paper, Brazil’s international
marine biodiversity commitments. 相似文献
79.
Galante-Oliveira S Oliveira I Ferreira N Santos JA Pacheco M Barroso C 《Journal of environmental monitoring : JEM》2011,13(2):304-312
Nucella lapillus (dog whelk) imposex levels were assessed along the mainland Portuguese coast in 2006 and 2008 and were compared with available data from 2003 for the same area. Given that specimen size has been described as a factor inducing variation in some of the imposex assessment indices, and thus resulting in less reliable results, new monitoring and data analysis procedures are described and applied to study change of imposex levels from 2003 to 2008. A significant decline in imposex intensity was observed in the study area during the study period, and the Portuguese coast ecological status (under the terms defined by the OSPAR Commission) notably improved after 2003, confirming the effectiveness of the Regulation (EC) No. 782/2003 in reducing TBT pollution. Nevertheless, N. lapillus populations are still extensively affected by imposex, and fresh TBT inputs were detected in seawater throughout the coast in 2006. These recent inputs are attributed to vessels still carrying TBT antifoulants applied before 2003, as their presence in vessels was only forbidden in 2008. Considering that Regulation (EC) No. 782/2003 is an anticipation of the IMO global ban entered into force in September 2008, a worldwide-scale decrease in TBT pollution can be expected in the near future. 相似文献
80.
Almeida C Pereira C Gomes T Bebianno MJ Cravo A 《Journal of environmental monitoring : JEM》2011,13(9):2559-2567
DNA damage was evaluated in the haemolymph of Mytilus galloprovincialis from nine sites along the south coast of Portugal using the comet assay. DNA damage was low, in the same range of sites considered to suffer low impact from genotoxic contaminants. Even so, differences between sites, seasons and genders were found. Highest values were in mussels from the main estuaries and the fishery harbour, reflecting higher genotoxin levels, whereas the lowest values can be used as a baseline for future work. Non-contaminant related factors (e.g. temperature and oxygen) were also shown to influence DNA damage. Between seasons, highest values were in summer related not only to the increase of tourism in this region (~10-fold), but also to temperature. Between genders, males were found to be more sensitive. The condition index was also generally higher in summer. Lipid peroxidation, another damage biomarker, was measured in gills to assess if there is any association between the responses of both biomarkers and if they are similarly affected by the same environmental conditions. LPO like DNA damage was higher in summer. This work confirms that DNA damage is a sensitive biomarker to discriminate genotoxic contamination, even in areas considered to suffer low impact from genotoxins. 相似文献