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101.
Kunwar P. Singh Shikha Gupta Priyanka Ojha Premanjali Rai 《Environmental science and pollution research international》2013,20(4):2271-2287
The research aims to develop artificial intelligence (AI)-based model to predict the adsorptive removal of 2-chlorophenol (CP) in aqueous solution by coconut shell carbon (CSC) using four operational variables (pH of solution, adsorbate concentration, temperature, and contact time), and to investigate their effects on the adsorption process. Accordingly, based on a factorial design, 640 batch experiments were conducted. Nonlinearities in experimental data were checked using Brock–Dechert–Scheimkman (BDS) statistics. Five nonlinear models were constructed to predict the adsorptive removal of CP in aqueous solution by CSC using four variables as input. Performances of the constructed models were evaluated and compared using statistical criteria. BDS statistics revealed strong nonlinearity in experimental data. Performance of all the models constructed here was satisfactory. Radial basis function network (RBFN) and multilayer perceptron network (MLPN) models performed better than generalized regression neural network, support vector machines, and gene expression programming models. Sensitivity analysis revealed that the contact time had highest effect on adsorption followed by the solution pH, temperature, and CP concentration. The study concluded that all the models constructed here were capable of capturing the nonlinearity in data. A better generalization and predictive performance of RBFN and MLPN models suggested that these can be used to predict the adsorption of CP in aqueous solution using CSC. 相似文献
102.
从长期受1,2,4-三氯苯(1,2,4-TCB)污染的地下水中筛选出一株低温寡营养降解菌A2,对A2菌进行革兰氏染色鉴定和16S rDNA鉴定,研究了不同pH、温度、盐度等因素对A2菌降解1,2,4-TCB效果以及对邻苯二酚1,2-双加氧酶基因表达的影响,并进行了正交实验。结果表明,A2菌为革兰氏阴性短杆细菌,初步鉴定为假单胞菌;在pH值为7、培养温度30℃、盐度0.8%、培养时间6 d时,A2菌对1,2,4-TCB降解效果最好,降解率达到88.14%,同时该条件下邻苯二酚1,2-双加氧酶基因相对表达水平最高;培养温度为10℃时,A2菌对1,2,4-TCB降解率可达到85.3%,同时邻苯二酚1,2-双加氧酶基因也有较高的相对表达水平。以上结果说明,将A2菌应用于低温寡营养地下水的生物修复是可能的。 相似文献
103.
104.
Background
All employees in health care settings handling needles or other sharps are at risk for needle stick and sharps injuries (NSSIs). Health care workers in under developed countries are at greater risk of infection from blood borne pathogens because of the lack of safety devices and the high prevalence of these pathogens.Objectives
The aim of this study was to assess the prevalence of NSSIs and associated factors among health care workers in government health institutions in Gondar city, Ethiopia.Methods
Institution based cross sectional study was conducted from May-December, 2010. The study included 344 health care workers who were selected from the source population using simple random sampling technique. Data were collected through interviews using structured and pre-tested questionnaire and the collected data were entered and analyzed using SPSS version 16.0.Results
The prevalence of NSSIs among health care workers in the preceding 12 months was 106 (30.8%), of which 58 (54.7%) was reported by females. Lack of training on occupational health and safety, working more than 48 h/week, dissatisfaction with work environment and work culture, greater than 10 years of work experience and having low and moderate perception of risk were found to be significantly associated with NSSIs.Conclusion
The study found high prevalence of NSSIs among health care workers. Effective training, ongoing awareness on the risk of hazards, preventive measures such as engineering control, and post-exposure prophylaxis following NSSIs are essential to reduce the risk of such injuries. 相似文献105.
Present paper provides first-hand information of certain ethnomedicinal plants from an Indo-Burma hotspot region (Mizoram, NE India). Forty ethnomedicinal plants recorded for the first time from this site of particular ecological relevance. Medical applications and conservation status of recorded plants have been described. In light of the fact that biodiversity characterization is now increasingly being recognized as an endangered field, such sort of biodiversity inventorying, monitoring, and assessment works are relevant particularly in relation to plants which are intimately linked with human welfare. Moreover, sustainable use of such components of biodiversity may extend important ecosystem services and also assist in their conservation. 相似文献
106.
The distribution of triclosan and methyl-triclosan in marine sediments of Barker Inlet, South Australia 总被引:2,自引:0,他引:2
Fernandes M Shareef A Kookana R Gaylard S Hoare S Kildea T 《Journal of environmental monitoring : JEM》2011,13(4):801-806
In this work, we investigated the transport and burial of triclosan and its methylated derivative, in surface sediments near the mouth of Barker Inlet in South Australia. The most likely source of this commonly used bactericide to the area is a wastewater outfall discharging at the confluence of the inlet with marine waters. Triclosan was detected in all samples, at concentrations (5-27 μg kg(-1)) comparable to values found in other surface sediments under the influence of marine wastewater outfalls. Its dispersal was closely associated with fine and organic-rich fractions of the sediments. Methyl-triclosan was detected in approximately half of the samples at concentrations <11 μg kg(-1). The occurrence of this compound was linked to both wastewater discharges and biological methylation of the parent compound. Wastewater-borne methyl-triclosan had a smaller spatial footprint than triclosan and was mostly deposited in close proximity to the outfall. In situ methylation of triclosan likely occurs at deeper depositional sites, whereas the absence of methyl-triclosan from shallower sediments was potentially explained by photodegradation of the parent compound. Based on partition equilibrium, a concentration of triclosan in the order of 1 μg L(-1) was estimated in sediment porewaters, a value lower than the threshold reported for harmful effects to occur in the couple of species of marine phytoplankton investigated to date. Methyl-triclosan presents a greater potential for bioaccumulation than triclosan, but the implications of its occurrence to aquatic ecosystem health are difficult to predict given the lack of ecotoxicological data in the current literature. 相似文献
107.
G. S. Guru P. Prasad H. R. Shivakumar S. K. Rai 《Journal of Polymers and the Environment》2010,18(2):135-140
Miscibility characteristics of Xanthan gum and Poly (vinyl pyrrolidone) (PVP) in common solvent water were studied by viscometry,
ultrasonic velocity and density techniques at 30 and 50 °C. Blend films of Xanthan gum/PVP were prepared by solution casting
method and characterized by scanning electron microscopic (SEM) and differential scanning calorimeter (DSC) techniques. Using
the viscosity data, interaction parameters of Chee’s (μ) and Sun’s (α) were computed to determine their miscibility. The values
obtained revealed that blends were miscible when PVP content is up to 70% in blend at 30 °C. Xanthan gum/poly (vinyl pyrrolidone)
blends showed miscibility in all composition at 50 °C. The results were then confirmed by ultrasonic velocity, density, and
DSC techniques. Compatibility in the above compositions may be due to the formation of hydrogen bonding between the carbonyl
group in PVP and hydroxyl group in Xanthan gum. Further, the results revealed that change in temperature had significant effect
on the miscibility of Xanthan gum/Poly (vinyl pyrrolidone) blends. 相似文献
108.
Yang Wu Mike Williams Lester Smith Donghui Chen Rai Kookana 《Journal of environmental science and health. Part. B》2013,48(4):240-249
In this study, the dissipation of two antibiotics, sulfamethoxazole (SMX) and trimethoprim (TRM), in three soils under both aerobic and anaerobic conditions are evaluated. Under aerobic conditions, SMX dissipated rapidly through biodegradation but TRM was more persistent. Within the first 20 days in biologically active soils, >50% of the SMX was lost from the clay loam and loamy sand soils, and >80% loss was noted in the loam soil. Anaerobic dissipation of both compounds was more rapid than aerobic dissipation. The addition of manure to the soil only slightly increased the initial dissipation rate of the two compounds. Little effect was found on glucose mineralisation in soil following the addition of SMX and TRM, even as mixtures at high concentrations. 相似文献
109.
110.
A high-performance liquid chromatographic method was developed to analyse selected endocrine disrupting chemicals in water by using automated on-line solid-phase extraction with a fluorescence detector. The excitation and emission wavelengths of the fluorescence detector were 230 nm and 290 nm, respectively. The selected endocrine disrupting chemicals include hormone steroids such as estradiol (E2), estriol (E3), ethynylestradiol (EE2), and ethynylestradiol 3-methyl ether (MeEE2) as well as nonylphenols (NP), octylphenols (OP), POE(1-2) nonyl phenol (NPE) and bisphenol A (BP). Three types of on-line cartridges (C18, PLRP-s and PRP-1) were tested to pre-concentrate the endocrine disruptors in deionised water. It was found that the recoveries of these chemicals at 1 microg/L were close to 100% except for 4-octyl phenol and 4-n-nonyl phenol, which had recoveries of about 40% to 80%. The two polymer cartridges (PLRP-s and PRP-1) gave higher recoveries than the C18 cartridges. The addition of methanol at 5% to 10% in water significantly improved the recovery of 4-octyl phenol and 4-n-nonyl phenol. The addition of methanol also led to an improvement in the recovery with C18 cartridges. With the addition of methanol in water samples, these three types of cartridges gave similar recoveries for the chemicals. The detection limits of this method ranged from 20 ng/L to 50 ng/L. A river water sample spiked with these chemicals was analysed using the above method and we found no interference with the peaks of the selected endocrine disrupting chemicals. The recoveries for these chemicals were more than 92% except for 4-NP with a recovery of 61%. This relatively simple method is useful for laboratory studies on the environmental fate of these endocrine disrupting chemicals in water. 相似文献