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451.
452.
Calculating overpressure from BLEVE explosions 总被引:3,自引:0,他引:3
E. Planas-Cuchi J. M. Salla J. Casal 《Journal of Loss Prevention in the Process Industries》2004,17(6):431-436
Although a certain number of authors have analyzed the prediction of boiling liquid expanding vapour explosion (BLEVE) and fireball effects, only very few of them have proposed methodologies for predicting the overpressure from such explosions. In this paper, the methods previously published are discussed and shown to introduce a significant overestimation due to the erroneous thermodynamic assumptions—ideal gas behaviour and isentropic vapour expansion—on which they are based (in fact, they give the maximum value of overpressure which can be caused by a BLEVE). A new approach is proposed, based on the—more realistic—assumption of an adiabatic and irreversible expansion process; the real properties of the substance involved in the explosion are used. The two methods are compared through the application to a given case. 相似文献
453.
454.
T. D. Blackall M. R. Theobald C. Milford K. J. Hargreaves E. Nemitz L. J. Wilson J. Bull P. J. Bacon K. C. Hamer S. Wanless M. A. Sutton 《Water, Air, & Soil Pollution: Focus》2004,4(6):279-285
Ammonia emissions from two contrasting seabird colonies in Scotland were measured, based on the determination of atmospheric concentrations downwind of the colonies. Atmospheric concentrations of ammonia (NH3) across the downwind plume were compared with the inverse application of a Gaussian dispersion model (ID) to calculate the modelled NH3 emission that would generate the measured cross-wind-integrated plume concentration. In parallel, a tracer gas (sulphur hexafluoride, SF6) was released from the colonies with air samples taken to allow determination of SF6 concentrations. On the basis of the known emission rate of SF6, the magnitude of ammonia emissions was estimated by the cross-wind-integrated tracer ratio (TR) of NH3/SF6 concentrations. Coupled with data on annual bird attendance, the measurements indicate annual emissions from the Isle of May and the Bass Rock of 18 and 132 tonnes NH3-N year–1, respectively. The measured NH3 emissions were compared with estimates of seabird nitrogen excretion to estimate the proportion of excreted N that is volatilised as NH3 (FNr). The emission estimates of the two methods compared favourably, giving 4 and 6 kg NH3-N h–1 (FNr = 15%) for the Isle of May for the ID and TR methods, respectively, and 21 and 25 kg NH3-N h–1 (FNr = 50%) for the Bass Rock for the ID and TR methods, respectively. The results provide the first measurement-based estimates to allow regional up scaling of ammonia emissions from seabirds. 相似文献
455.
Jonn A. Foulk Wayne Y. Chao Danny E. Akin Roy B. Dodd Patricia A. Layton 《Journal of Polymers and the Environment》2004,12(3):165-171
Municipal solid wastes generated each year contain potentially useful and recyclable materials for composites. Simultaneously, interest is high for the use of natural fibers, such as flax (Linum usitatissimum L.), in composites thus providing cost and environmental benefits. To investigate the utility of these materials, composites containing flax fibers with recycled high density polyethylene (HDPE) were created and compared with similar products made with wood pulp, glass, and carbon fibers. Flax was either enzyme- or dew-retted to observe composite property differences between diverse levels of enzyme formulations and retting techniques. Coupling agents would strengthen binding between fibers and HDPE but in this study fibers were not modified in anyway to observe mechanical property differences between natural fiber composites. Composites with flax fibers from various retting methods, i.e., dew- vs. enzyme-retting, behaved differently; dew-retted fiber composites resulted in both lower strength and percent elongation. The lowest level of enzyme-retting and the most economical process produces composites that do not appear to differ from the highest level of enzyme-retting. Flax fibers improved the modulus of elasticity over wood pulp and HDPE alone and were less dense than glass or carbon fiber composites. Likely, differences in surface properties of the various flax fibers, while poorly defined and requiring further research, caused various interactions with the resin that influenced composite properties. 相似文献
456.
Nugraha E. Suyatma Alain Copinet Lan Tighzert Veronique Coma 《Journal of Polymers and the Environment》2004,12(1):1-6
Biodegradable film blends of chitosan with poly(lactic acid) (PLA) were prepared by solution mixing and film casting. The main goal of these blends is to improve the water vapor barrier of chitosan by blending it with a hydrophobic biodegradable polymer from renewable resources. Mechanical properties of obtained films were assessed by tensile test. Thermal properties, water barrier properties, and water sensitivity were studied by differential scanning calorimeter analysis, water vapor permeability measurements, and surface-angle contact tests, respectively. The incorporation of PLA to chitosan improved the water barrier properties and decreased the water sensitivity of chitosan film. However, the tensile strength and elastic modulus of chitosan decreased with the addition of PLA. Mechanical and thermal properties revealed that chitosan and PLA blends are incompatible, consistent with the results of Fourier transform infrared (FTIR) analysis that showed the absence of specific interaction between chitosan and PLA. 相似文献
457.
Steven N. Chillrud Richard F. Bopp James M. Ross Damon A. Chaky Sidney Hemming Edward L. Shuster H. James Simpson Frank Estabrooks 《Water, Air, & Soil Pollution: Focus》2004,4(2-3):469-482
Radionuclide, radiogenic lead isotope and trace metal analyses on fine-grained sediment cores collected along 160 km of the upper and tidal Hudson River were used to examine temporal trends of contaminant loadings and to develop radiogenic lead isotopes both as a stratigraphic tool and as tracers for resolving decadal particle transport fluxes. Very large inputs of Cd, Sb, Pb, and Cr are evident in the sediment record, potentially from a single manufacturing facility. The total range in radiogenic lead isotope ratios observed in well-dated cores collected about 24 km downstream of the plant is large (e.g., maximum difference in 206Pb/207Pb is 10%), characterized by four major shifts occurring in the 1950s, 1960s, 1970s and 1980s. The upper Hudson signals in Cd and radiogenic lead isotopes were still evident in sediments collected 160 km downstream in the tidal Hudson. The large magnitude and abrupt shifts in radiogenic lead isotope ratios as a function of depth provide sensitive temporal constraints that complement information derived from radionuclide analyses to significantly improve the precision of dating assignments. Application of a simple dilution model to data from paired cores suggests much larger sediment inputs in one section of the river than previously reported, suggesting particle influxes to the Hudson have been underestimated. 相似文献
458.
A solution containing 35SO4 2- and 3H2O was applied to four plots (5 × 5 m) in a boreal coniferous forest in the Laflamme Lake watershed, Québec, under two contrasting conditions: in summer (plots 1 and 2), and on the snowpack before snowmelt (plots 3 and 4). The transit of both these tracers in the soil solution was then followed through a network of soil lysimeters located at different depths. Four months after the summer application, 3H2O had infiltrated the whole soil profile at plot 1, while 35SO4 2- was only observed in the LFH and Bhf horizons. A 35SO4 2- budget calculated from mid-August to November indicated that 89 and 10.6% of the added 35SO4 2- was retained within the LFH and the Bhf layers, respectively. Fifteen months later, the added 35SO4 2- was distributed in the following proportions within the soil horizons: LFH (73.7%), Bhf (11.8%) and Bf (12.8%), for a total retention rate of 98.3%. The superficial penetration of 3H2O at plot 2 was indicative of a major lateral water movement that prevented the calculation of a 35SO4 2- budget. This situation also was observed at plot 4 during snowmelt. At plot 3, 3H2O moved freely through the soil profile and a significant fraction of the added 35SO4 2- reached the B horizons, where it was presumably adsorbed on aluminum (Al) and ferric (Fe) oxides. The 35SO4 2- budget for plot 3 from March to November indicated that 87% of the added 35SO4 2- was retained within the soil profile, with most being retained in the B horizons (LFH = 33.1%, Bhf = 33.1%, Bf = 20.8%). The contrasting retention patterns of 35SO4 2- within the soil profile following the summer addition and snowmelt likely was caused by the contrastingsoil temperatures and soil solution residence times within the differentsoil layers. The persistence of 35SO4 2- in the soil solution of the entire profile long after the initial tracer infiltration, and the relative temporal stability of specific activity of SO4 2-, point to the establishment of an isotopic equilibrium between the added 35SO4 and the active S-containing reservoirs within a given soil horizon. Overall, the results clearly illustrate the very strong potential for 35SO4 2- retention and recycling in forest soils. 相似文献
459.
Ali M Alhemood Ashraf M Genaidy Richard Shell Michael Gunn Christin Shoaf 《International journal of occupational safety and ergonomics》2004,10(4):303-318
In this study, a survey instrument was developed to measure safety climate. A review of the scientific literature as well as consultation with an expert panel was used to determine the survey's dimensions. Next, the survey was administered, first as a pilot study (n = 15) and then as a full scale study (n = 229), to employees of the City of Cincinnati Department of Public Works. The psychometric integrity of the survey was assessed according to validity, reliability and utility criteria. Results are presented and discussed. 相似文献
460.
This study addresses the behaviors of project managers under various conditions of cognitive and affective trust, and the implications for obtaining client loyalty. Theoretical foundations were drawn from interpersonal and interorganizational trust literature. A test of the proposed theoretical framework was conducted in a field setting utilizing a matched design of both project managers and their clients. The results show that reliable project performance positively impacted client loyalty intentions and service‐oriented OCBs positively impacted client secondary retention. An interaction showed that in low cognitive trust situations the project manager behavior of reliable project performance facilitated the obtainment of client loyalty intentions. Implications for research and practice are discussed. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献