Assessing potential bioavailability of metals in sediments: A proposed approach

Due to anthropogenic inputs, elevated concentrations of metals frequently occur in aquatic sediments. In order to make defensible estimates of the potential risk of metals in sediments and/or develop sediment quality criteria for metals, it is essential to identify that fraction of the total metal in the sediments that is bioavailable. Studies with a variety of benthic invertebrates indicate that interstitial (pore) water concentrations of metals correspond very well with the bioavailability of metals in test sediments. Many factors may influence pore water concentrations of metals; however, in anaerobic sediments a key phase controlling partitioning of several cationic metals (cadmium, nickel, lead, zinc, copper) into pore water is acid volatile sulfide (AVS). In this paper, we present an overview of the technical basis for predicting bioavailability of cationic metals to benthic organisms based on pore water metal concentrations and metal-AVS relationships. Included are discussions of the advantages and limitations of metal bioavailability predictions based on these parameters, relative both to site-specific assessments and the development of sediment quality criteria.     

The application of spatial‐perceptual wilderness mapping to protected areas management in New Zealand

The paper examines the application of a spatial‐perceptual approach to the wilderness management issue of preserving natural ecological processes while also permitting appropriate wilderness use in protected areas. An approach to delimit the spatial extent of multiple perceptions of wilderness held by backcountry users is used—the wilderness perception mapping (WPM) methodology. The results obtained from employing the WPM.methodology are considered for the North West Nelson region of New Zealand. The map product provides new and useful information that has applicability to protected areas management. The role of WPM is discussed with reference to wilderness management in North West Nelson and New Zealand, and to protected areas management in general. The study demonstrates how a technology can be combined with a critical and sensible analysis of needs and procedures to give useful results, and highlights the value of applied interdisciplinary research.     

DESERT HOUSE: A DEMONSTRATION/EXPERIMENT IN EFFICIENT DOMESTIC WATER AND ENERGY USE1

ABSTRACT: In May 1993, a single-family home and adjoining information center opened to the public at the Desert Botanical Garden in Phoenix, Arizona. Desert House is designed as an example of what can be achieved today using available technology to improve residential water and energy efficiency. The home is expected to reduce water and energy use by 40 percent compared with that for the typical three-bedroom, single-family residence in the Phoenix area. Water-conserving features include: landscape design employing low-water use plants, minimum turf area, mulch around plants to reduce evaporation, and drip irrigation system; spa cover for evaporation reduction; rainwater harvesting; low-flow shower heads, faucets, and toilets; and graywater reuse system. The home will be occupied by a family and monitored for water and energy use by computer. Visitors are able to access real time water and energy use data about the home, as well as tour the information center, technical exhibits, surrounding landscape, and the home when it is open (one afternoon a week).     

UV peroxidation with air stripping for optimized removal of VOCs from groundwater

No one remedial technology is best suited to treat every groundwater contaminant plume. This article describes how pilot testing and analytical evaluation targeted selection of two treatment technologies, UV peroxidation and air stripping, to be used in series to create a synergistic, cost-effective pump-and-treat system for the removal of VOCs from groundwater. Pilot plant size equipment was employed to treat the VOC-contaminated groundwater in order to obtain site-specific reaction rates and to develop full-scale design parameters. It was found that by using the two treatment technologies in combination, the influent concentration of 2,000 ppb total VOCs could be reduced to less than 1 ppb, thus meeting drinking water standards.     

DEVELOPMENT OF A NONDEGRAIATION POLICY FOR HIGH QUALITY WATERS1

ABSTRACT: The development of a nondegradation policy for high quality waters is a complex and often controversial process. This paper discusses the development of a nondegradation policy for two components of the National Wild and Scenic Rivers System. Water quality in these reaches of the Delaware River is threatened by rapid growth and development and the cumulative impacts from numerous wastewater discharges and nonpoint sources of pollution. The Delaware River Basin Commission, with assistance from its member states and the National Park Service, conducted a highly public, six-year planning process to develop a nondegradation policy that protected existing water quality without impinging upon local and state economic development objectives. The resulting non-degradation policy includes such features as numeric definitions of existing water quality and measurable change; stringent point source requirements; nonpoint source requirements including watershed planning requirements; and other water quality management policies.     

FLOW DURATION CURVES II: A REVIEW OF APPLICATIONS IN WATER RESOURCES PLANNING1

ABSTRACT: A streamflow duration curve illustrates the relationship between the frequency and magnitude of streamflow. Flow duration curves have a long history in the field of water-resource engineering and have been used to solve problems in water-quality management, hydropower, instream flow methodologies, water-use planning, flood control, and river and reservoir sedimentation, and for scientific comparisons of streamflow characteristics across watersheds. This paper reviews traditional applications and provides extensions to some new applications, including water allocation, wasteload allocation, river and wetland inundation mapping, and the economic selection of a water-resource project.     

African river basin development

The international conference on The African Experience with River Basin Development challenged participants to pursue a critical discussion of the record to date on approaches to river basin development and to propose appropriate strategies for the future. During the conference, special focus was given to the institutional requirements for planning, implementing and evaluating those strategies which benefit large numbers of people through increased production, enterprise development and employment generations in an environmentally sound fashion. It was noted that serious negative environmental and socio-economic effects have followed in the wake of African dam construction and the creation of large man-made lakes. The conference produced a short-list of general priorities for improving river basin development in Africa.     

MEASURING THE SITE-SPECIFIC RECREATION BENEFITS RESULTING FROM IMPROVED WATER QUALITY: AN UPPER BOUND APPROACH1

The estimation of the value of recreation benefits resulting from improved water quality is required for many purposes. In particular, the Water Pollution Control Act of 1980 requires the consideration of the reasonableness of costs of reducing water pollution in relation to benefits to be derived from establishing effluent standards (Clean Water Act of 1977). Recreation is often the most important benefit resulting from water quality improvement. Current methods used to calculate recreation benefits are either not site-specific or are expensive and controversial. This paper presents a relatively simple, inexpensive, and less controversial method of calculating site-specific recreation benefits resulting from improved water quality. It does this by producing an upper bound estimate which often is adequate for the relevant decision. The upper bound estimates is based on two assumptions: 1) there are alternative equivalent substitute sites for the newly augmented water quality site, and 2) the new augmented recreation opportunities at the site will be used to their maximum supply capacity. Clearly, if an upper bound benefit estimate in a cost-benefit ratio does not produce a favorable ratio, no other benefit estimate will. In cases where this estimate produces an ambiguous result resort must be had to other more precise methods of estimation.     

Hedgerows and hedgerow networks in landscape ecology

Hedgerows originated and coexist with agriculture. Their internal structure and species diversity vary widely with origin (planted, spontaneous, or remnant), farming practices in adjacent fields, and the refined art of hedgerow management. Most hedgerow species are forest-edge species, and apparently none is limited to hedgerows. Wide hedgerows composed of trees and shrubs appear to function as corridors for movement of many plants and animals across a landscape. The reduction of crop loss, by dampening pest population fluctuations with hedgerow predators, remains a hypothesis for study.Field microclimate downwind of a hedgerow is modified about 16 times the hedgerow height (h) for evaporation, and approximately 28 h for wind speed. A turbulent wind pattern with harsher microclimate is present at 6–8 h if a second hedgerow is nearby downwind. Zones of higher crop productivity at 3- to 6-h downwind, and 2- to 6-h upwind of a second hedgerow may be expected. Overall, we expect little short-term difference in farm-field production with or without hedgerows.Evidence suggests that hedgerow networks, and especially their mesh size (of fields), exert a major control on many major landscape fluxes. Such fluxes include animal populations, wind speed, evapotranspiration and soil desiccation, soil erosion and nutrient runoff, species movement along network lines, and movement of field species across the network. In a relatively short period, the hedgerow ecosystem, with no unique species, has attained a metastable equilibrium, which is regulated by enormous human inputs.More than 20 economic roles of hedgerows are pinpointed. The roles, providing resources and protection of resources, are poorly known quantitatively. We conclude that hedgerows perform diverse functions for society and the farmer that are both economically and ecologically significant.     

Soils Characteristics of The Bassendean and Spearwood Sands of the Gnangara Mound (Western Australia) and their Controls On Recharge, Water Level Patterns and Solutes of The Superficial Aquifer

The flow pathways of water in the soils of the Gnangara Mound are highly irregular and depend upon the moisture content, the repellency and preferential wettability potential of the soils. The occurrence of preferential flow is more evident in dry soils. As the soil wets during the rainy season, the water repellence and differential wettability decreases, the fingering and the preferential flow paths disappear. Most of the agricultural sites in the Spearwood Sands which showed more irregular flow than the Bassendean Sands are under continuous irrigation during cultivation season. As the repellency problems are chemically treated, it is therefore expected that the flow will be more uniform all the year round. Landuse is mainly responsible for variation in recharge rates; however, the hydraulic properties control aquifer response and water level pattern to a greater degree. Water levels in the mid 1970s were in a semi steady state. Since that time, a combination of increasing water use by pine plantations, heavy pumping from private boreholes in market gardens and private homes and intensive pumping from the Gnangara Mound for the metropolitan water supply have caused water levels to continually decline in the Superficial aquifer. Nitrate and phosphate concentrations in the regional Superficial aquifer are generally very low. None of the tested pesticides (atrazine, diazinon, dimethoate, endosulfan, fenamiphos, iprodione, malathion and chlorpyrifos) were detected in the groundwater samples collected from the monitoring bores.